Diphenyl ditelluride

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Diphenyl ditelluride
Chemical structure of diphenyl ditelluride
Space-filling model of the diphenyl ditelluride molecule
Names
Preferred IUPAC name
1,1′-Ditellanediyldibenzene
Other names
Phenylditelluride
Diphenylditelluride
Identifiers
3D model (
JSmol
)
ChEMBL
ChemSpider
ECHA InfoCard
100.046.332 Edit this at Wikidata
EC Number
  • 250-982-1
  • InChI=1S/C12H10Te2/c1-3-7-11(8-4-1)13-14-12-9-5-2-6-10-12/h1-10H checkY
    Key: VRLFOXMNTSYGMX-UHFFFAOYSA-N checkY
  • InChI=1/C12H10Te2/c1-3-7-11(8-4-1)13-14-12-9-5-2-6-10-12/h1-10H
    Key: VRLFOXMNTSYGMX-UHFFFAOYAJ
  • C1([Te][Te]C2=CC=CC=C2)=CC=CC=C1
  • [Te]([Te]c1ccccc1)c2ccccc2
Properties
C12H10Te2
Molar mass 409.42 g/mol
Appearance Orange powder
Density 2.23 g/cm3
Melting point 66 to 67 °C (151 to 153 °F; 339 to 340 K)
Boiling point decomposes
Insoluble
Solubility in other solvents Dichloromethane
Structure
90° at Se
C2 symmetry
0 D
Hazards
Occupational safety and health (OHS/OSH):
Main hazards
Toxic
GHS labelling:[1]
GHS07: Exclamation mark
Warning
H302, H312, H315, H319, H332, H335
P261, P264, P270, P271, P280, P301+P312, P302+P352, P304+P312, P304+P340, P305+P351+P338, P312, P321, P322, P330, P332+P313, P337+P313, P362, P363, P403+P233, P405, P501
Related compounds
Related compounds
Ph2S2,
Ph2Se2
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
checkY verify (what is checkY☒N ?)

Diphenylditelluride is the

catalyst for redox reactions.[3]

Preparation

Ph2Te2 is prepared by the oxidation of tellurophenolate, which is generated via the Grignard reagent:[4]

PhMgBr + Te → PhTeMgBr
2PhTeMgBr + 0.5 O2 + H2O → Ph2Te2 + 2 MgBr(OH)

The molecule has C2 symmetry.

References

  1. ^ "Diphenyl ditelluride". pubchem.ncbi.nlm.nih.gov. Retrieved 23 December 2021.
  2. S2CID 97000699
    .
  3. .
  4. .