Natural hydrogen
Natural hydrogen (known as white hydrogen, geologic hydrogen
Origins
Sources of natural hydrogen include:[8]
- degassing of deep hydrogen from Earth's crust and mantle;[9]
- reaction of water with serpentinisation);
- water in contact with reducing agents in Earth's mantle;
- weathering - water in contact with freshly exposed rock surfaces;
- decomposition of hydroxyl ionsin the structure of minerals;
- natural water radiolysis;
- decomposition of organic matter;
- biological activity
Reserves
According to the Financial Times, there are 5 trillion tons of natural hydrogen reserves worldwide.[10] A discovery in Russia in 2008 suggests the possibility of extracting native hydrogen in geological environments.[citation needed] Reserves have been identified in France,[11] Mali, the United States and approximately a dozen other countries.[12]
An accumulation of natural hydrogen was discovered in a water well in Bourakébougou, Mali, that was exploited to power the nearby village.[13] In 2023 Pironon and de Donato announced the discovery of a deposit they estimated to be some 46 million to 260 million metric tons (several years worth of 2020s production).[13] In 2024, a natural deposit of helium and hydrogen was discovered in Rukwa, Tanzania.[14]
Mid-continent Rift System
White hydrogen could be found or produced in the Mid-continental Rift System at scale. Water could be pumped down to hot iron-rich rock to produce hydrogen for extraction.[15]
Geology
Natural hydrogen is generated from various sources. Many hydrogen emergences have been identified on mid-ocean ridges.[16] Serpentinisation occurs in the oceanic crust.
Diagenetic origin (iron oxidation) in the sedimentary basins of cratons, notably are found in Russia.
Mantle hydrogen and hydrogen from
Hydrogen is soluble in fresh water, especially at moderate depths as solubility generally increases with pressure. However, at greater depths and pressures, such as within the mantle,[19] the solubility decreases due to the highly assymetric nature of mixtures of hydrogen and water.
Literature
Vladimir Vernadsky originated the concept of natural hydrogen captured by the Earth in the process of formation from the post-nebula cloud. Cosmogonical aspects were anticipated by Fred Hoyle. From 1960-2010, V.N. Larin developed the Primordially Hydridic Earth concept[20][dubious ] that described deep-seated natural hydrogen prominence[21] and migration paths.
See also
- Pure-play helium
- Electrofuel
- Hydrogen economy
- Hydrogen production
- Combined cycle hydrogen power plant
- Hydrogen fuel cell power plant
References
- ^ "Geologists signal start of hydrogen energy 'gold rush'".
- ^ Larin V.N. 1975 Hydridic Earth: The New Geology of Our Primordially Hydrogen-Rich Planet (Moscow: Izd. IMGRE). (in Russian)
- S2CID 195544603.
- ^ "Hydrogen color code". H2B.
- ^ La rédaction: Hydrogène naturel : une source potentielle d'énergie renouvelable. In: La Revue des Transitions. 7 November 2019, retrieved 17 January 2022 (in French).
- .
- ^ Gregory Paita, Master Thesis, Engie & Université de Montpellier.
- ^ Zgonnik, P. Malbrunot: L'Hydrogene Naturel. Hrsg.: AFHYPAC Association française pour l'hydrogène et les piles à combustible. August 2020, S. 8 p., p. 5 (in French).
- ^ "Our Earth". V. N. Larin, Agar, 2005 (in Russian)
- ^ "Geologists signal start of hydrogen energy 'gold rush'".
- ^ Paddison, Laura (2023-10-29). "They went hunting for fossil fuels. What they found could help save the world". CNN. Retrieved 2023-10-29.
- S2CID 104328822.
- ^ New York Times.
- ^ "Helium One Itumbula West-1 records positive concentrations". 5 February 2024.
- ^ "The Potential for Geologic Hydrogen for Next-Generation Energy | U.S. Geological Survey". www.usgs.gov.
- ^ L'hydrogène dans une économie décarbonée (connaissancedesenergies.org)
- ^ Gaucher, Éric C. (June 2020). "Une découverte d'hydrogène naturel dans les Pyrénées-Atlantiques, première étape vers une exploration industrielle" [A natural hydrogen discovery in the Pyrénées-Atlantiques region, the first step towards industrial exploration]. Géologues, Société géologique de France (in French) (213). Retrieved May 2, 2023.
- S2CID 105839304.
- S2CID 2222392.
- ^ V.N. Larin (1993). Hydridic Earth, Polar Publishing, Calgary, Alberta. https://archive.org/details/Hydridic_Earth_Larin_1993
- ^ Our Earth. V.N. Larin, Agar, 2005 (rus.) https://archive.org/details/B-001-026-834-PDF-060
Bibliography
- Larin V.N. 1975 Hydridic Earth: The New Geology of Our Primordially Hydrogen-Rich Planet (Moscow: Izd. IMGRE) in Russian
- V.N. Larin (1993). Hydridic Earth, Polar Publishing, Calgary, Alberta. Hydridic Earth: the New Geology of Our Primordially Hydrogen-rich Planet
- Our Earth. V.N. Larin, Agar, 2005 (rus.) Наша Земля (происхождение, состав, строение и развитие изначально гидридной Земли)
- Lopez-Lazaro, Cristina; Bachaud, Pierre; Moretti, Isabelle; Ferrando, Nicolas (2019). "Predicting the phase behavior of hydrogen in NaCl brines by molecular simulation for geological applications". BSGF - Earth Sciences Bulletin. 190: 7. S2CID 197609243.
- .
- . Retrieved August 17, 2023.
- Deville, Eric; Prinzhofer, Alain (November 2016). "The origin of N2-H2-CH4-rich natural gas seepages in ophiolitic context: A major and noble gases study of fluid seepages in New Caledonia". Chemical Geology. 440: 139–147. .
- Gregory Paita, Master Thesis, Engie & Université de Montpellier.[title missing]
- Moretti I., Pierre H. Pour la Science, special issue in partnership with Engie, vol. 485; 2018. p. 28. N march. Moretti I, D'Agostino A, Werly J, Ghost C, Defrenne D, Gorintin L. Pour la Science, special issue, March 2018, vol 485, 24 25XXII_XXVI.[title missing]
- Prinzhofer, Alain; Moretti, Isabelle; Françolin, Joao; Pacheco, Cleuton; D'Agostino, Angélique; Werly, Julien; Rupin, Fabian (March 2019). "Natural hydrogen continuous emission from sedimentary basins: The example of a Brazilian H2-emitting structure" (PDF). International Journal of Hydrogen Energy. 44 (12): 5676–5685. S2CID 104328822.
- Larin, Nikolay; Zgonnik, Viacheslav; Rodina, Svetlana; Deville, Eric; Prinzhofer, Alain; Larin, Vladimir N. (September 2015). "Natural Molecular Hydrogen Seepage Associated with Surficial, Rounded Depressions on the European Craton in Russia". Natural Resources Research. 24 (3): 369–383. S2CID 128762620.
- Zgonnik, Viacheslav; Beaumont, Valérie; Deville, Eric; Larin, Nikolay; Pillot, Daniel; Farrell, Kathleen M. (December 2015). "Evidence for natural molecular hydrogen seepage associated with Carolina bays (surficial, ovoid depressions on the Atlantic Coastal Plain, Province of the USA)". Progress in Earth and Planetary Science. 2 (1): 31. S2CID 55277065.
- Prinzhofer, Alain; Tahara Cissé, Cheick Sidy; Diallo, Aliou Boubacar (October 2018). "Discovery of a large accumulation of natural hydrogen in Bourakébougou (Mali)". International Journal of Hydrogen Energy. 43 (42): 19315–19326. S2CID 105839304.
- Zgonnik, Viacheslav (1 April 2020). "The occurrence and geoscience of natural hydrogen: A comprehensive review". Earth-Science Reviews. 203: 103140. S2CID 213202508.
- Prinzhofer, Alain; Deville, Éric (2015). Hydrogène naturel, la prochaine révolution énergétique. Humensis. OCLC 1158938704.
- Moretti, Isabelle (22 May 2020). "L'hydrogène naturel : curiosité géologique ou source d'énergie majeure dans le futur ?". Connaissance des énergies (in French).
- Trégouët, René (17 July 2020). "L'hydrogène naturel pourrait devenir une véritable source d'énergie propre et inépuisable..." RT Flash (in French).
- Rigollet, Christophe; Prinzhofer, Alain (2022). "Natural Hydrogen: A New Source of Carbon-Free and Renewable Energy That Can Compete with Hydrocarbons". First Break. 40 (10): 78–84. S2CID 252679963.