Chemical garden

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Comparison of chemical gardens grown by NASA scientists on the International Space Station (left) and on the ground (right)
A chemical garden while growing
Cobalt(II) chloride
A chemical garden

A chemical garden is a set of complex biological-looking structures created by mixing inorganic chemicals. This experiment in chemistry is usually performed by adding metal salts, such as copper sulfate or cobalt(II) chloride, to an aqueous solution of sodium silicate (otherwise known as waterglass). This results in the growth of plant-like forms in minutes to hours.[1][2][3][4]

The chemical garden was first observed and described by

ferrous chloride (FeCl2) crystals into a solution of potassium silicate
(K2SiO3).

Process

The chemical garden relies on most transition metal silicates being insoluble in water and colored.

When a metal salt, such as

osmotic
effects will increase the pressure within the membrane. This will cause the membrane to tear, forming a hole. The cobalt cations will react with the silicate anions at this tear to form a new solid. In this way, growths will form in the tanks; they will be colored (according to the metal cation) and may look like plant-like structures.

The usual upward direction of growth depends on the density of the fluid inside the semi-permeable membrane of the "plant" being lower than that of the surrounding waterglass solution. If one uses a metal salt that produces a very dense fluid inside the membrane, the growth is downward. For example, a green solution of trivalent chromium sulfate or chloride refuses to crystallize without slowly changing into the violet form[clarification needed], even if boiled until it concentrates into a tarry mass. That tar, if suspended in the waterglass solution, forms downward twig-like growths. This is because all the fluid inside the membrane is too dense to float and thereby exerts a downward force. The concentration of sodium silicate becomes important in growth rate.

After the growth has ceased, the sodium silicate solution can be removed by a continuous addition of water at a very slow rate. This prolongs the life of the garden.[6]

In one specific experimental variation, researchers produced the chemical garden with a single growth "tube".[7]

Common salts used

Common salts used in a chemical garden include:[8]

Practical uses

While at first the chemical garden may appear to be primarily a toy, some serious work has been done on the subject.[3] For instance, this chemistry is related to the setting of Portland cement, the formation of hydrothermal vents, and during the corrosion of steel surfaces on which insoluble tubes can be formed.

The nature of the growth of the insoluble silicate tubes formed within chemical gardens is also useful in understanding classes of related behavior seen in fluids separated by membranes. In various ways, the growth of the silicate tubes resembles the growth of spikes or blobs of ice extruded above the freezing surface of still water,[9] the patterns of growth of gum drying as it drips from wounds in trees such as Eucalyptus, and the way molten wax forms twig-like growths, either dripping from a candle, or floating up through cool water.[citation needed]

Paleontology

If the conditions are good, chemical gardens can also occur in nature. There is evidence from

pseudofossils can be very difficult to distinguish from fossilized organisms. Indeed, some of the earliest purported fossils of life might be fossilized chemical gardens.[10]

Mixing iron-rich particles with alkaline liquids containing the chemicals silicate or carbonate have created biological-looking structures. Such structures may appear to be biological and/or fossils.[11][12][13] According to researchers, "Chemical reactions like these have been studied for hundreds of years but they had not previously been shown to mimic these tiny iron-rich structures inside rocks. These results call for a re-examination of many ancient real-world examples to see if they are more likely to be fossils or non-biological mineral deposits."[11][12]

One use of the study of chemical gardening is to be better able to distinguish biological structures, including fossils, from non-biological structures on the planet Mars.[11][12]

See also

References

  1. PMID 26176351
    .
  2. S2CID 54973427
    .
  3. ^
    doi:10.1006/jcis.2002.8620
    .
  4. PMID 12670257. Archived from the original
    (PDF) on 11 August 2017. Retrieved 23 May 2009.
  5. ^ Glauber, Johann Rudolf (1646). "Wie man in diesem Liquore von allen Metallen in wenig Stunden Bäume mit Farben soll wachsen machen." [How one shall make grow—in this solution, from all metals, in a few hours—trees with color]. Furni Novi Philosophici (German-language 1661 ed.). Amsterdam: Johan Jansson. pp. 186–189.
  6. ^ Helmenstine, Anne Marie (16 March 2019). "Magic Rocks". thoughtco.com. Archived from the original on 16 May 2020. Retrieved 16 May 2020.
  7. PMID 22431259
    .
  8. S2CID 256932493
    . Retrieved 16 March 2023.
  9. ^ Carter, James R. "Ice Formations with Daily (Diurnal) Freeze/Thaw Cycles". Illinois State University. Archived from the original on 26 November 2017. Retrieved 14 November 2020.
  10. PMID 31771469
    .
  11. ^
    EurekAlert!
    . Retrieved 27 November 2019.
  12. ^
    PMID 31771469
    .
  13. doi:10.1063/PT.3.3108
    .

External links

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