Cyclopentadienylvanadium tetracarbonyl
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3D model (
JSmol ) |
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EC Number |
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PubChem CID
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CompTox Dashboard (EPA)
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Properties | |
Appearance | orange solid |
Density | 1.56 g/cm3 |
Boiling point | sublimes |
Hazards | |
GHS labelling: | |
Danger | |
H301, H311, H315, H319, H330, H335 | |
P260, P261, P264, P270, P271, P280, P284, P301+P310, P302+P352, P304+P340, P305+P351+P338, P310, P312, P320, P321, P322, P330, P332+P313, P337+P313, P361, P362, P363, P403+P233, P405, P501 | |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Cyclopentadienylvanadium tetracarbonyl is the
The compound has no commercial applications.Reactions
Reduction with sodium amalgam gives the dianion of the tricarbonyl:
- CpV(CO)4 + 2 Na → Na2CpV(CO)3 + CO
Protonation of this salt gives Cp2V2(CO)5.[3]
Heating a mixture of cycloheptatriene and cyclopentadienylvanadium tetracarbonyl gives (cycloheptatrienyl)(cyclopentadienyl)vanadium ("trovacene").[4]
References
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