Tris(acetonitrile)cyclopentadienylruthenium hexafluorophosphate
Identifiers | |
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ECHA InfoCard
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100.152.130 |
PubChem CID
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CompTox Dashboard (EPA)
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Properties | |
C11H14N3RuPF6 | |
Molar mass | 434.28 |
Appearance | yellow/brown solid |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Tris(acetonitrile)cyclopentadienylruthenium hexafluorophosphate is an
cyclopentadienyl ligand (Cp) is bonded in an η5
manner to the Ru(II) center.
Preparation
The title complex is synthesized in two steps from the (benzene)ruthenium dichloride dimer. In the first step, the Cp− group is installed using cyclopentadienylthallium:[1]
- [(C6H6)RuCl2]2 + 2 TlCp + 2 NH4PF6 → 2 [Cp(C6H6)Ru]PF6 + 2 TlCl + 2 NH4Cl
The second step entails photochemical displacement of the benzene ligand, which is replaced by three equivalents of acetonitrile (MeCN):
- [Cp(C6H6)Ru]PF6 + 3 MeCN → [CpRu(NCMe)3]PF6 + C6H6
References
- ^ .
- PMID 11710241.