Henry Louis Le Chatelier

Henry Louis Le Chatelier^[1] (French pronunciation: [ɑ̃ʁi lwi lə ʃɑtəlje]; 8 October 1850 – 17 September 1936) was a French chemist of the late 19th and early 20th centuries. He devised Le Chatelier's principle, used by chemists and chemical engineers to predict the effect a changing condition has on a system in chemical equilibrium.

Early life

Le Chatelier was born on 8 October 1850 in Paris and was the son of French materials engineer

At the Collège de France, Le Chatelier succeeded Schützenberger as chair of inorganic chemistry. Later he taught at the Sorbonne university, where he replaced Henri Moissan.

At the Collège de France, Le Chatelier taught:

• Phenomena of combustion (1898)
• Theory of chemical equilibria, high temperature measurements and phenomena of dissociation (1898–1899)
• Properties of metal alloys (1899–1900)
• Iron alloys (1900–1901)
• General methods of analytical chemistry (1901–1902)
• General laws of analytical chemistry (1901–1902)
• General laws of chemical mechanics (1903)
• Silica and its compounds (1905–1906)
• Some practical applications of the fundamental principles of chemistry (1906–1907)
• Properties of metals and some alloys (1907)

After four unsuccessful campaigns (1884, 1897, 1898 and 1900), Le Chatelier was elected to the Académie des sciences (Academy of Science) in 1907. He was also elected to the Royal Swedish Academy of Sciences in 1907. In 1924, he became an Honorary Member of the Polish Chemical Society.^[3]

Scientific work

In chemistry, Le Chatelier is best known for his work on his principle of chemical equilibrium, Le Chatelier's principle, and on varying solubility of salts in an ideal solution. He published no fewer than thirty papers on these topics between 1884 and 1914. His results on chemical equilibrium were presented in 1884 at the Académie des sciences in Paris.

Le Chatelier also carried out extensive research on metallurgy and was one of the founders of the technical newspaper La revue de métallurgie (Metallurgy Review).

Part of Le Chatelier's work was devoted to industry. For example, he was a consulting engineer for a cement company, the Société des chaux et ciments Pavin de Lafarge, today known as Lafarge Cement. His 1887 doctoral thesis was dedicated to the subject of mortars: Recherches expérimentales sur la constitution des mortiers hydrauliques (Experimental Research on the Composition of Hydraulic Mortars).

On the advice of a paper of Le Chatelier that the combustion of a mixture of

Le Chatelier in 1901 attempted the direct combination of the two gases nitrogen and hydrogen at a pressure of 200 atm and 600 °C in the presence of metallic iron. An air compressor forced the mixture of gases into a steel Berthelot bomb, where a platinum spiral heated them and the reduced iron catalyst.[7] A terrific explosion occurred which nearly killed an assistant. Le Chatelier found that the explosion was due to the presence of air in the apparatus used. And thus it was left for Fritz Haber to succeed where several noted French chemists, including Thenard, Sainte Claire Deville and even Berthelot had failed. Less than five years later, Haber and Carl Bosch were successful in producing ammonia on a commercial scale. Near the end of his life, Le Chatelier wrote, "I let the discovery of the ammonia synthesis slip through my hands. It was the greatest blunder of my scientific career”.^[8]

Le Chatelier's principle

Le Chatelier's Principle states that a system always acts to oppose changes in chemical equilibrium; to restore equilibrium, the system will favor a chemical pathway to reduce or eliminate the disturbance so as to restabilize at thermodynamic equilibrium. Put another way,

If a chemical system at equilibrium experiences a change in

concentration, temperature or total pressure

, the equilibrium will shift in order to minimize that change.

N₂(g) + 3H₂(g) ⇌ 2NH₃(g)

If one increases the pressure of the reactants, the reaction will tend to move towards the products to decrease the pressure of the reaction.

However consider another example: in the contact process for the production of sulfuric acid, the second stage is a reversible reaction:

2SO₂(g) + O₂(g) ⇌ 2SO₃(g)

The forward reaction is exothermic and the reverse reaction is endothermic. Viewed by Le Chatelier's principle a larger amount of thermal energy in the system would favor the endothermic reverse reaction, as this would absorb the increased energy; in other words the equilibrium would shift to the reactants in order to remove the stress of added heat. For similar reasons, lower temperatures would favor the exothermic forward reaction, and produce more products. This works in this case, since due to loss of entropy the reaction becomes less exothermic as temperature increases; however reactions that become more exothermic as temperature increases would seem to violate this principle.

Politics

It was then typical for scientists and engineers to have a very scientific vision of industry. In the first issue of La revue de métallurgie, Le Chatelier published an article describing his convictions on the subject,

Le Chatelier was politically conservative. In 1934, he published an opinion on the French forty-hour work week law in the Brussels publication Revue économique internationale. However, in spite of certain anti-parliamentarian convictions, he kept away from any extremist or radical movements.^{[citation needed]}

His brother Alfred Le Chatelier, a former soldier, opened the Atelier de Glatigny in the rural area of Glatigny (Le Chesnay), near Versailles, in 1897. The workshop made sandstone ceramics, high-quality porcelain and glassware. In 1901, the critic Henri Cazalis (alias Jean Lahor), listed the workshop as one of the best producers in France of Art Nouveau ceramics.^[10] Henry Louis Le Chatelier seems to have encouraged Alfred's workshop and assisted with experiments in the composition of porcelain and the reactions of quartz inclusions, and also designed a thermoelectric pyrometer to measure temperature in the kilns.^[11]

Works

• Cours de chimie industrielle (1896; second edition, 1902)
• High Temperature Measurements, translated by
  G. K. Burgess
  (1901; second edition, 1902)
• Recherches expérimentales sur la constitution des mortiers hydrauliques (1904; English translation, 1905)
• Leçons sur le carbone (1908)
• Introduction à l'étude de la métallurgie (1912)
• La silice et les silicates (1914)

Honours and awards

Le Chatelier named "chevalier" (knight) of the

He was awarded the