Peroxyureidoacrylate/ureidoacrylate amidohydrolase
Peroxyureidoacrylate/ureidoacrylate amidohydrolase | |||||||||
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Identifiers | |||||||||
ExPASy | NiceZyme view | ||||||||
KEGG | KEGG entry | ||||||||
MetaCyc | metabolic pathway | ||||||||
PRIAM | profile | ||||||||
PDB structures | RCSB PDB PDBe PDBsum | ||||||||
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Peroxyureidoacrylate/ureidoacrylate amidohydrolase (EC 3.5.1.110, RutB) is an enzyme with systematic name (Z)-3-ureidoacrylate peracid amidohydrolase.[1] This enzyme catalyses the following chemical reaction sequences:
- (Z)-3-ureidoacrylate peracid + H2O ⇌ (Z)-3-peroxyaminoacrylate + CO2 + NH3 (overall reaction)
- (Z)-3-ureidoacrylate peracid + H2O ⇌ (Z)-3-peroxyaminoacrylate + carbamate
- carbamate ⇌ CO2 + NH3 (spontaneous)
- (Z)-2-methylureidoacrylate peracid + H2O ⇌ (Z)-2-methylperoxyaminoacrylate + CO2 + NH3 (overall reaction)
- (Z)-2-methylureidoacrylate peracid + H2O ⇌ (Z)-2-methylperoxyaminoacrylate + carbamate
- carbamate ⇌ CO2 + NH3 (spontaneous)
The enzyme also shows activity towards ureidoacrylate.
References
- PMID 20400551.
External links
- Peroxyureidoacrylate/ureidoacrylate+amidohydrolase at the U.S. National Library of Medicine Medical Subject Headings (MeSH)