User:Graeme Bartlett/arsenide carbide
Arsenide carbides or carbide arsenides are compounds containing
mixed anion compounds. Related compounds include the arsenide silicides, germanide arsenides, and phosphide carbides
.
Some of these compounds are what are called MAX phases, where M is a metal and A and X are main group elements. Ratios can be 2:1:1 or 3:2:1.
Another class is perovskite carbides of the form M3AsC.
The bonds between the metal and arsenic can be classified as metallic, but between the metal and carbon are covalent.
List
formula | system | space group | unit cell Å | volume | density | comment | ref |
---|---|---|---|---|---|---|---|
V2AsC | hexagonal | P63/mmc | a=3.113 c=11.38 Z=2 | [1] | |||
V3As2C | hexagonal | P63/mmc | a=3.298 c=18.007 Z=2 | 169.7 | 6.8 | [2] | |
V3AsC | a=3.128 b=10.10.14 c=7.590 | 244.2 | [3] | ||||
Cr3AsC | a=3.057 b=9.704 c=7.299 | 216.3 | [3] | ||||
Nb2AsC | hexagonal | P63/mmc | a=3.31 c=11.9 Z=2 | metallic; superconductor Tc = 2K | [4][5] | ||
Nb3As2C | hexagonal | P63/mmc | a=3.3606 c=18.6951 Z=2 | 182.846 | 8.0 | [2] | |
triclinic | P1 | ||||||
monoclinic | P21 |