User:Graeme Bartlett/arsenide carbide

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Arsenide carbides or carbide arsenides are compounds containing

mixed anion compounds. Related compounds include the arsenide silicides, germanide arsenides, and phosphide carbides
.


Some of these compounds are what are called
MAX phases, where M is a metal and A and X are main group elements. Ratios can be 2:1:1 or 3:2:1.

Another class is perovskite carbides of the form M3AsC.

The bonds between the metal and arsenic can be classified as metallic, but between the metal and carbon are covalent.

List

formula system space group unit cell Å volume density comment ref
V2AsC hexagonal P63/mmc a=3.113 c=11.38 Z=2 [1]
V3As2C hexagonal P63/mmc a=3.298 c=18.007 Z=2 169.7 6.8 [2]
V3AsC a=3.128 b=10.10.14 c=7.590 244.2 [3]
Cr3AsC a=3.057 b=9.704 c=7.299 216.3 [3]
Nb2AsC hexagonal P63/mmc a=3.31 c=11.9 Z=2 metallic; superconductor Tc = 2K [4][5]
Nb3As2C hexagonal P63/mmc a=3.3606 c=18.6951 Z=2 182.846 8.0 [2]
triclinic P1
monoclinic P21

References