Zinc cadmium phosphide arsenide
Zinc cadmium phosphide arsenide (
List of all binary compounds
This system of elements contains numerous binary compounds and their solid solutions.
Stable at atmospheric pressure
The binary compounds thermodynamically stable at atmospheric pressure are listed in the following table:[1][3]
Anion Cation
|
P | As | ||
---|---|---|---|---|
Zn | ||||
Cd |
|
Metastable or unstable at atmospheric pressure
Compounds metastable or unstable at atmospheric pressure are the following:
Anion Cation
|
P | As | ||
---|---|---|---|---|
Zn |
|
|
|
|
Cd |
|
|
|
|
Quaternary compounds
The compounds of the form II3V2 have similar crystalline structures and exhibit full solid solution over the whole compositional range. The compounds of the form II-V2 allow only partial solid solution.[3]
Ternary compounds
The binary compounds in this system form a wide range of solid solutions. This miscibility reflects the close similarity of the structures of the binary phases. The IIV2 compounds exhibit wide solid solution ranges with CdP4 even though the stoichiometry and structures of the components differ.[3]
The optoelectronic and band properties of some ternary compounds have also been studied. For example, the bandgap of Zn3(P1−yAsy)2 solid solutions is direct and tunable from 1.0 eV to 1.5 eV. This solubility enables the fabrication of tunable nanowire photodetectors.[8] The solid solution (Zn1−xCdx)3As2 exhibit a topological phase transition at x ~ 0.62.[9]
Notable binary compounds
Cadmium arsenide (Cd3As2)
Cadmium arsenide is a 3D Dirac semimetal exhibiting the Nernst effect.
Zinc phosphide (Zn3P2)
Zinc phosphide is a semiconductor material with a direct band gap of 1.5 eV[10] used in photovoltaics.[11] It is also used as a rodenticide in the pest control industry.
Zinc arsenide (Zn3As2)
Zinc arsenide is a semiconductor material with a band gap of 1.0 eV.[12]
References
- ^ S2CID 94409384.
- .
- ^ a b c d e f Yakimovich, V. N.; Rubtsov, V. A.; Trukhan, V. M. (1996). "Phase equilibria in the Zn-P-As-Cd System". Inorganic Materials. 32 (7): 705–709.
- ^ S2CID 140792691.
- ^ a b Okamoto, H. (1992). "The As-Zn (Arsenic-Zinc) System". Journal of Phase Equilibria. 13 (2).
- ^ Berak, J.; Pruchnik, Z. (1971). "Phase Equilibria in the Zinc-Cadmium-Phosphorus System. Part III. The Cd3P2-Zn3P2 System". Roczniki Chemii. 45: 1425.
- ^ PMID 12428990.
- PMID 25602167.
- PMID 28600553.
- ISSN 0003-6951.
- doi:10.1063/1.92124.
- doi:10.1063/1.371569.