Superlattice

A superlattice is a

.

Discovery

Superlattices were discovered early in 1925 by Johansson and Linde[1] after the studies on gold-copper and palladium-copper systems through their special X-ray diffraction patterns. Further experimental observations and theoretical modifications on the field were done by Bradley and Jay,^[2] Gorsky,^[3] Borelius,^[4] Dehlinger and Graf,^[5] Bragg and Williams^[6] and Bethe.^[7] Theories were based on the transition of arrangement of atoms in crystal lattices from disordered state to an ordered state.

Mechanical properties

J.S. Koehler theoretically predicted

cannot operate in the nanolayers.

The increased mechanical hardness of such superlattice materials was confirmed firstly by Lehoczky in 1978 on Al-Cu and Al-Ag,^[9] and later on by several others, such as Barnett and Sproul^[10] on hard PVD coatings.

Semiconductor properties

If the superlattice is made of two semiconductor materials with different

has led to the observation of quantum size effects in isolated quantum well heterostructures and is closely related to superlattices through the tunneling phenomena. Therefore, these two ideas are often discussed on the same physical basis, but each has different physics useful for applications in electric and optical devices.

Semiconductor superlattice types

Superlattice miniband structures depend on the

. Although the bottom of the conduction subband and the top of the valence subband are formed in the same semiconductor layer in Type III superlattice, which is similar with Type I superlattice, the band gap of Type III superlattices can be continuously adjusted from semiconductor to zero band gap material and to semimetal with negative band gap.

Another class of quasiperiodic superlattices is named after Fibonacci. A Fibonacci superlattice can be viewed as a one-dimensional quasicrystal, where either electron hopping transfer or on-site energy takes two values arranged in a Fibonacci sequence.

Semiconductor materials

Semiconductor materials, which are used to fabricate the superlattice structures, may be divided by the element groups, IV, III-V and II-VI. While group III-V semiconductors (especially GaAs/Al_xGa_1−xAs) have been extensively studied, group IV heterostructures such as the Si_xGe_1−x system are much more difficult to realize because of the large lattice mismatch. Nevertheless, the strain modification of the subband structures is interesting in these quantum structures and has attracted much attention.

In the GaAs/AlAs system both the difference in lattice constant between GaAs and AlAs and the difference of their thermal expansion coefficient are small. Thus, the remaining strain at room temperature can be minimized after cooling from

temperatures. The first compositional superlattice was realized using the GaAs/Al_xGa_1−xAs material system.

A

Production

Superlattices can be produced using various techniques, but the most common are

metal-organic chemical vapor deposition

(MO-CVD) has contributed to the development of superconductor superlattices, which are composed of quaternary III-V compound semiconductors like InGaAsP alloys. Newer techniques include a combination of gas source handling with ultrahigh vacuum (UHV) technologies such as metal-organic molecules as source materials and gas-source MBE using hybrid gases such as arsine (AsH
₃) and phosphine (PH
₃) have been developed.

Generally speaking MBE is a method of using three temperatures in binary systems, e.g., the substrate temperature, the source material temperature of the group III and the group V elements in the case of III-V compounds.

The structural quality of the produced superlattices can be verified by means of

, and changes in elastic and acoustic properties. Depending on the nature of its components, a superlattice may be called magnetic, optical or semiconducting.

Miniband structure

The schematic structure of a periodic superlattice is shown below, where A and B are two semiconductor materials of respective layer thickness a and b (period: ${\displaystyle d=a+b}$). When a and b are not too small compared with the interatomic spacing, an adequate approximation is obtained by replacing these fast varying potentials by an effective potential derived from the band structure of the original bulk semiconductors. It is straightforward to solve 1D Schrödinger equations in each of the individual layers, whose solutions ${\displaystyle \psi }$ are linear combinations of real or imaginary exponentials.

For a large barrier thickness, tunneling is a weak perturbation with regard to the uncoupled dispersionless states, which are fully confined as well. In this case the dispersion relation ${\displaystyle E_{z}(k_{z})}$, periodic over ${\displaystyle 2\pi /d}$ with over ${\displaystyle d=a+b}$ by virtue of the Bloch theorem, is fully sinusoidal:

${\displaystyle \ E_{z}(k_{z})={\frac {\Delta }{2}}(1-\cos(k_{z}d))}$

and the effective mass changes sign for ${\displaystyle 2\pi /d}$:

${\displaystyle \ {m^{*}={\frac {\hbar ^{2}}{\partial ^{2}E/\partial k^{2}}}}|_{k=0}}$

In the case of minibands, this sinusoidal character is no longer preserved. Only high up in the miniband (for wavevectors well beyond ${\displaystyle 2\pi /d}$) is the top actually 'sensed' and does the effective mass change sign. The shape of the miniband dispersion influences miniband transport profoundly and accurate dispersion relation calculations are required given wide minibands. The condition for observing single miniband transport is the absence of interminiband transfer by any process. The thermal quantum k_BT should be much smaller than the energy difference ${\displaystyle E_{2}-E_{1}}$ between the first and second miniband, even in the presence of the applied electric field.

Bloch states

For an ideal superlattice a complete set of

states can be constructed by products of plane waves ${\displaystyle e^{i\mathbf {k} \cdot \mathbf {r} }/2\pi }$ and a z-dependent function ${\displaystyle f_{k}(z)}$ which satisfies the eigenvalue equation

${\displaystyle \left(E_{c}(z)-{\frac {\partial }{\partial z}}{\frac {\hbar ^{2}}{2m_{c}(z)}}{\frac {\partial }{\partial z}}+{\frac {\hbar ^{2}\mathbf {k} ^{2}}{2m_{c}(z)}}\right)f_{k}(z)=Ef_{k}(z)}$.

As ${\displaystyle E_{c}(z)}$ and ${\displaystyle m_{c}(z)}$ are periodic functions with the superlattice period d, the eigenstates are

${\displaystyle f_{k}(z)=\phi _{q,\mathbf {k} }(z)}$ with energy ${\displaystyle E^{\nu }(q,\mathbf {k} )}$. Within first-order perturbation theory in k², one obtains the energy

${\displaystyle E^{\nu }(q,\mathbf {k} )\approx E^{\nu }(q,\mathbf {0} )+\langle \phi _{q,\mathbf {k} }\mid {\frac {\hbar ^{2}\mathbf {k} ^{2}}{2m_{c}(z)}}\mid \phi _{q,\mathbf {k} }\rangle }$.

Now, ${\displaystyle \phi _{q,\mathbf {0} }(z)}$ will exhibit a larger probability in the well, so that it seems reasonable to replace the second term by

${\displaystyle E_{k}={\frac {\hbar ^{2}\mathbf {k} ^{2}}{2m_{w}}}}$

where ${\displaystyle m_{w}}$ is the effective mass of the quantum well.

Wannier functions

By definition the

.

Wannier–Stark ladder

Applying an electric field F to the superlattice structure causes the Hamiltonian to exhibit an additional scalar potential eφ(z) = −eFz that destroys the translational invariance. In this case, given an eigenstate with wavefunction ${\displaystyle \Phi _{0}(z)}$ and energy ${\displaystyle E_{0}}$, then the set of states corresponding to wavefunctions ${\displaystyle \Phi _{j}(z)=\Phi _{0}(z-jd)}$ are eigenstates of the Hamiltonian with energies E_j = E₀ − jeFd. These states are equally spaced both in energy and real space and form the so-called Wannier–Stark ladder. The potential ${\displaystyle \Phi _{0}(z)}$ is not bounded for the infinite crystal, which implies a continuous energy spectrum. Nevertheless, the characteristic energy spectrum of these Wannier–Stark ladders could be resolved experimentally.

Transport

The motion of charge carriers in a superlattice is different from that in the individual layers: mobility of charge carriers can be enhanced, which is beneficial for high-frequency devices, and specific optical properties are used in semiconductor lasers.

If an external bias is applied to a conductor, such as a metal or a semiconductor, typically an electric current is generated. The magnitude of this current is determined by the band structure of the material, scattering processes, the applied field strength and the equilibrium carrier distribution of the conductor.

A particular case of superlattices called superstripes are made of superconducting units separated by spacers. In each miniband the superconducting order parameter, called the superconducting gap, takes different values, producing a multi-gap, or two-gap or multiband superconductivity.

Recently, Felix and Pereira investigated the thermal transport by phonons in periodic^[13] and quasiperiodic^[14][15][16] superlattices of graphene-hBN according to the Fibonacci sequence. They reported that the contribution of coherent thermal transport (phonons like-wave) was suppressed as quasiperiodicity increased.

Other dimensionalities

Soon after two-dimensional electron gases (

(i.e. along z-direction) to an additional modulation potential V(x,y). Contrary to the classical superlattices (1D/3D, that is 1D modulation of electrons in 3D bulk) described above, this is typically achieved by treating the heterostructure surface: depositing a suitably patterned metallic gate or etching. If the amplitude of V(x,y) is large (take ${\displaystyle V(x,y)=-V_{0}(\cos 2\pi x/a+\cos 2\pi y/a),V_{0}>0}$ as an example) compared to the Fermi level, ${\displaystyle |V_{0}|\gg E_{f}}$, the electrons in the superlattice should behave similarly to electrons in an atomic crystal with square lattice (in the example, these "atoms" would be located at positions (na,ma) where n,m are integers).

The difference is in the length and energy scales. Lattice constants of atomic crystals are of the order of 1Å while those of superlattices (a) are several hundreds or thousands larger as dictated by technological limits (e.g. electron-beam lithography used for the patterning of the heterostructure surface). Energies are correspondingly smaller in superlattices. Using the simple quantum-mechanically confined-particle model suggests ${\displaystyle E\propto 1/a^{2}}$. This relation is only a rough guide and actual calculations with currently topical graphene (a natural atomic crystal) and artificial graphene^[18] (superlattice) show that characteristic band widths are of the order of 1 eV and 10 meV, respectively. In the regime of weak modulation (${\displaystyle |V_{0}|\ll E_{f}}$), phenomena like commensurability oscillations or fractal energy spectra (Hofstadter butterfly) occur.

Artificial two-dimensional crystals can be viewed as a 2D/2D case (2D modulation of a 2D system) and other combinations are experimentally available: an array of quantum wires (1D/2D) or 3D/3D photonic crystals.

Applications

The superlattice of palladium-copper system is used in high performance alloys to enable a higher electrical conductivity, which is favored by the ordered structure. Further alloying elements like silver, rhenium, rhodium and ruthenium are added for better mechanical strength and high temperature stability. This alloy is used for probe needles in probe cards.^[19]

See also

• Cu-Pt type ordering in III-V semiconductor
• Tube-based nanostructures
• Wannier function

References

• H.T. Grahn, "Semiconductor Superlattices", World Scientific (1995).
  ISBN 978-981-02-2061-7
• Schuller, I. (1980). "New Class of Layered Materials". Physical Review Letters. 44 (24): 1597–1600.
  doi:10.1103/PhysRevLett.44.1597
  .
• Morten Jagd Christensen, "Epitaxy, Thin Films and Superlattices", Risø National Laboratory, (1997).
  ISBN 8755022987 Superlattice at Google Books [1]
• C. Hamaguchi, "Basic Semiconductor Physics", Springer (2001). Superlattice at
  ISBN 3540416390
• Wacker, A. (2002). "Semiconductor superlattices: A model system for nonlinear transport". Physics Reports. 357 (1): 1–7.
  S2CID 118885849
  .
• Haugan, H. J.; Szmulowicz, F.; Mahalingam, K.; Brown, G. J.; Munshi, S. R.; Ullrich, B. (2005). "Short-period InAs/GaSb type-II superlattices for mid-infrared detectors". Applied Physics Letters. 87 (26): 261106.
  doi:10.1063/1.2150269. [2]^{[dead link}
  ]

Further reading

• Mendez, E. E.;
  doi:10.1063/1.881353
  .