Magnetic refrigeration
Magnetic refrigeration is a cooling technology based on the magnetocaloric effect. This technique can be used to attain extremely low temperatures, as well as the ranges used in common refrigerators.[1][2][3][4]
A magnetocaloric material warms up when a magnetic field is applied. The warming is due to changes in the internal state of the material releasing heat. When the magnetic field is removed, the material returns to its original state, reabsorbing the heat, and returning to original temperature. To achieve refrigeration, the material is allowed to radiate away its heat while in the magnetized hot state. Removing the magnetism, the material then cools to below its original temperature.
The effect was first observed in 1881 by a German physicist Emil Warburg, followed by French physicist P. Weiss and Swiss physicist A. Piccard in 1917.[5] The fundamental principle was suggested by P. Debye (1926) and W. Giauque (1927).[6] The first working magnetic refrigerators were constructed by several groups beginning in 1933. Magnetic refrigeration was the first method developed for cooling below about 0.3 K (a temperature attainable by pumping on 3
He vapors).
Magnetocaloric effect
The magnetocaloric effect (MCE, from
One of the most notable examples of the magnetocaloric effect is in the chemical element
5(Si
2Ge
2).[7] Praseodymium alloyed with nickel (PrNi
5) has such a strong magnetocaloric effect that it has allowed scientists to approach to within one millikelvin, one thousandth of a degree of absolute zero.[8]
Equation
The magnetocaloric effect can be quantified with the following equation:
where is the adiabatic change in temperature of the magnetic system around temperature T, H is the applied external magnetic field, C is the heat capacity of the working magnet (refrigerant) and M is the magnetization of the refrigerant.
From the equation we can see that the magnetocaloric effect can be enhanced by:
- a large field variation
- a magnet material with a small heat capacity
- a magnet with large changes in net magnetization vs. temperature, at constant magnetic field
The adiabatic change in temperature, , can be seen to be related to the magnet's change in magnetic entropy () since[9]
This implies that the absolute change in the magnet's entropy determines the possible magnitude of the adiabatic temperature change under a thermodynamic cycle of magnetic field variation. T
Thermodynamic cycle
The cycle is performed as a
- Adiabatic magnetization: A magnetocaloric substance is placed in an insulated environment. The increasing external magnetic field (+H) causes the magnetic dipoles of the atoms to align, thereby decreasing the material's magnetic entropy and heat capacity. Since overall energy is not lost (yet) and therefore total entropy is not reduced (according to thermodynamic laws), the net result is that the substance is heated (T + ΔTad).
- Isomagnetic enthalpic transfer: This added heat can then be removed (-Q) by a fluid or gas — gaseous or liquid helium, for example. The magnetic field is held constant to prevent the dipoles from reabsorbing the heat. Once sufficiently cooled, the magnetocaloric substance and the coolant are separated (H=0).
- Adiabatic demagnetization: The substance is returned to another adiabatic (insulated) condition so the total entropy remains constant. However, this time the magnetic field is decreased, the thermal energy causes the magnetic moments to overcome the field, and thus the sample cools, i.e., an adiabatic temperature change. Energy (and entropy) transfers from thermal entropy to magnetic entropy, measuring the disorder of the magnetic dipoles.[10]
- Isomagnetic entropic transfer: The magnetic field is held constant to prevent the material from reheating. The material is placed in thermal contact with the environment to be refrigerated. Because the working material is cooler than the refrigerated environment (by design), heat energy migrates into the working material (+Q).
Once the refrigerant and refrigerated environment are in thermal equilibrium, the cycle can restart.
Applied technique
The basic operating principle of an adiabatic demagnetization refrigerator (ADR) is the use of a strong magnetic field to control the entropy of a sample of material, often called the "refrigerant". Magnetic field constrains the orientation of magnetic dipoles in the refrigerant. The stronger the magnetic field, the more aligned the dipoles are, corresponding to lower entropy and
The operation of a standard ADR proceeds roughly as follows. First, a strong magnetic field is applied to the refrigerant, forcing its various magnetic dipoles to align and putting these degrees of freedom of the refrigerant into a state of lowered entropy. The heat sink then absorbs the heat released by the refrigerant due to its loss of entropy. Thermal contact with the heat sink is then broken so that the system is insulated, and the magnetic field is switched off, increasing the heat capacity of the refrigerant, thus decreasing its temperature below the temperature of the heat sink. In practice, the magnetic field is decreased slowly in order to provide continuous cooling and keep the sample at an approximately constant low temperature. Once the field falls to zero or to some low limiting value determined by the properties of the refrigerant, the cooling power of the ADR vanishes, and heat leaks will cause the refrigerant to warm up.
Working materials
The magnetocaloric effect (MCE) is an intrinsic property of a magnetic solid. This thermal response of a solid to the application or removal of magnetic fields is maximized when the solid is near its magnetic ordering temperature. Thus, the materials considered for magnetic refrigeration devices should be magnetic materials with a magnetic phase transition temperature near the temperature region of interest.[11] For refrigerators that could be used in the home, this temperature is room temperature. The temperature change can be further increased when the order-parameter of the phase transition changes strongly within the temperature range of interest.[2]
The magnitudes of the magnetic entropy and the adiabatic temperature changes are strongly dependent upon the magnetic ordering process. The magnitude is generally small in
In the late 1990s Pecharksy and Gschneidner reported a magnetic entropy change in Gd
5(Si
2Ge
2) that was about 50% larger than that reported for Gd metal, which had the largest known magnetic entropy change at the time.[12] This giant magnetocaloric effect (GMCE) occurred at 270 K, which is lower than that of Gd (294 K).[4] Since the MCE occurs below room temperature these materials would not be suitable for refrigerators operating at room temperature.[13] Since then other alloys have also demonstrated the giant magnetocaloric effect. These include Gd
5(Si
xGe
1−x)
4, La(Fe
xSi
1−x)
13H
x and MnFeP
1−xAs
x alloys.[11][13] Gadolinium and its alloys undergo second-order phase transitions that have no magnetic or thermal hysteresis.[14] However, the use of rare earth elements makes these materials very expensive.
Current research has been used to describe alloys with a significant magnetocaloric effect in terms of a thermodynamic system. Literature says that Gd5(Si2Ge2) for example may be described as a thermodynamic system provided it satisfies the condition of being “a quantity of matter or region in space chosen for study”.[15] Such systems have become relevant to modern research in thermodynamics because they serve as plausible materials for the creation of high performance thermoelectric materials.
Ni
2Mn-X (X = Ga, Co, In, Al, Sb) Heusler alloys are also promising candidates for magnetic cooling applications because they have Curie temperatures near room temperature and, depending on composition, can have martensitic phase transformations near room temperature.
The development of this technology is very material-dependent and will likely not replace vapor-compression refrigeration without significantly improved materials that are cheap, abundant, and exhibit much larger magnetocaloric effects over a larger range of temperatures. Such materials need to show significant temperature changes under a field of two tesla or less, so that permanent magnets can be used for the production of the magnetic field.[19][20]
Paramagnetic salts
The original proposed refrigerant was a paramagnetic salt, such as cerium magnesium nitrate. The active magnetic dipoles in this case are those of the electron shells of the paramagnetic atoms.
In a paramagnetic salt ADR, the heat sink is usually provided by a pumped 4
He (about 1.2 K) or 3
He (about 0.3 K) cryostat. An easily attainable 1 T magnetic field is generally required for initial magnetization. The minimum temperature attainable is determined by the self-magnetization tendencies of the refrigerant salt, but temperatures from 1 to 100 mK are accessible. Dilution refrigerators had for many years supplanted paramagnetic salt ADRs, but interest in space-based and simple to use lab-ADRs has remained, due to the complexity and unreliability of the dilution refrigerator.
At a low enough temperature, paramagnetic salts become either diamagnetic or ferromagnetic, limiting the lowest temperature that can be reached using this method.[citation needed]
Nuclear demagnetization
One variant of adiabatic demagnetization that continues to find substantial research application is nuclear demagnetization refrigeration (NDR). NDR follows the same principles, but in this case the cooling power arises from the magnetic dipoles of the nuclei of the refrigerant atoms, rather than their electron configurations. Since these dipoles are of much smaller magnitude, they are less prone to self-alignment and have lower intrinsic minimum fields. This allows NDR to cool the nuclear spin system to very low temperatures, often 1 µK or below. Unfortunately, the small magnitudes of nuclear magnetic dipoles also makes them less inclined to align to external fields. Magnetic fields of 3 teslas or greater are often needed for the initial magnetization step of NDR.
In NDR systems, the initial heat sink must sit at very low temperatures (10–100 mK). This precooling is often provided by the mixing chamber of a dilution refrigerator[21] or a paramagnetic salt.
Commercial development
Research and a demonstration proof of concept device in 2001 succeeded in applying commercial-grade materials and permanent magnets at room temperatures to construct a magnetocaloric refrigerator.[22]
On August 20, 2007, the
As of 2013 this technology had proven commercially viable only for ultra-low temperature
In November 2015, at the Medica 2015 fair, Cooltech Applications presented, in collaboration with Kirsch medical GmbH, the world's first magnetocaloric medical cabinet.[26] One year later, in September 2016, at the 7th International Conference on Magnetic Refrigeration at Room Temperature (Thermag VII)] held in Torino, Italy, Cooltech Applications presented the world's first magnetocaloric frozen heat exchanger.[27]
In 2017, Cooltech Applications presented a fully functional 500 liters' magnetocaloric cooled cabinet with a 30 kg (66 lb) load and an air temperature inside the cabinet of +2 °C. That proved that magnetic refrigeration is a mature technology, capable of replacing the classic refrigeration solutions.
One year later, in September 2018, at the 8th International Conference on Magnetic Refrigeration at Room Temperature (Thermag VIII]), Cooltech Applications presented a paper on a magnetocaloric prototype designed as a 15 kW proof-of-concept unit.[28] This has been considered by the community as the largest magnetocaloric prototype ever created.[29]
At the same conference, Dr. Sergiu Lionte announced that, due to financial issues, Cooltech Applications declared bankruptcy.[30] Later on, in 2019 Ubiblue company, today named Magnoric, is formed by some of the old Cooltech Application's team members. The entire patent portfolio form Cooltech Applications was taken over by Magnoric since then, while publishing additional patents at the same time.
In 2019, at the 5th Delft Days Conference on Magnetocalorics, Dr. Sergiu Lionte presented Ubiblue's (former Cooltech Application) last prototype.[31] Later, the magnetocaloric community acknowledged that Ubiblue had the most developed magnetocalorics prototypes.[32]
Thermal and magnetic hysteresis problems remain to be solved for first-order phase transition materials that exhibit the GMCE.[19]
One potential application is in spacecraft.
Vapor-compression refrigeration units typically achieve performance coefficients of 60% of that of a theoretical ideal Carnot cycle, much higher than current MR technology. Small domestic refrigerators are however much less efficient.[33]
In 2014 giant anisotropic behaviour of the magnetocaloric effect was found in HoMn
2O
5 at 10 K. The anisotropy of the
magnetic entropy change gives rise to a large rotating MCE offering the possibility to build simplified, compact, and efficient magnetic cooling systems by rotating it in a constant magnetic field.[34]
In 2015 Aprea et al.[35] presented a new refrigeration concept, GeoThermag, which is a combination of magnetic refrigeration technology with that of low-temperature geothermal energy. To demonstrate the applicability of the GeoThermag technology, they developed a pilot system that consists of a 100-m deep geothermal probe; inside the probe, water flows and is used directly as a regenerating fluid for a magnetic refrigerator operating with gadolinium. The GeoThermag system showed the ability to produce cold water even at 281.8 K in the presence of a heat load of 60 W. In addition, the system has shown the existence of an optimal frequency f AMR, 0.26 Hz, for which it was possible to produce cold water at 287.9 K with a thermal load equal to 190 W with a COP of 2.20. Observing the temperature of the cold water that was obtained in the tests, the GeoThermag system showed a good ability to feed the cooling radiant floors and a reduced capacity for feeding the fan coil systems.
History
The effect was discovered first observed by German physicist Emil Warburg in 1881[36] Subsequently by French physicist Pierre Weiss and Swiss physicist Auguste Piccard in 1917.[5]
Major advances first appeared in the late 1920s when cooling via adiabatic demagnetization was independently proposed by chemistry
It was first demonstrated experimentally by Giauque and his colleague D. P. MacDougall in 1933 for cryogenic purposes when they reached 0.25 K.[37] Between 1933 and 1997, advances in MCE cooling occurred.[38]
In 1997, the first near room-temperature
A major breakthrough came 2002 when a group at the University of Amsterdam demonstrated the giant magnetocaloric effect in MnFe(P,As) alloys that are based on abundant materials.[39]
Refrigerators based on the magnetocaloric effect have been demonstrated in laboratories, using magnetic fields starting at 0.6 T up to 10 T. Magnetic fields above 2 T are difficult to produce with permanent magnets and are produced by a superconducting magnet (1 T is about 20.000 times the Earth's magnetic field).
Room temperature devices
Recent research has focused on near room temperature. Constructed examples of room temperature magnetic refrigerators include:
Sponsor | Location | Announcement date | Type | Max. cooling power (W)[1] | Max ΔT (K)[2] | Magnetic field (T) | Solid refrigerant | Quantity (kg) | COP (-)[3] |
---|---|---|---|---|---|---|---|---|---|
Ames Laboratory/Astronautics[40]
|
Ames, Iowa/Madison, Wisconsin, US | February 20, 1997 | Reciprocating | 600 | 10 | 5 (S) | Gd spheres | ||
Mater. Science Institute Barcelona[41][42] | Barcelona, Spain | May 2000 | Rotary | ? | 5 | 0.95 (P) | Gd foil | ||
Chubu Electric/Toshiba[43] | Yokohama, Japan | Summer 2000 | Reciprocating | 100 | 21 | 4 (S) | Gd spheres | ||
University of Victoria[44][45] | Victoria, British Columbia Canada | July 2001 | Reciprocating | 2 | 14 | 2 (S) | Gd & Gd 1−xTb x L.B. | ||
Astronautics[46] | Madison, Wisconsin, US | September 18, 2001 | Rotary | 95 | 25 | 1.5 (P) | Gd spheres | ||
Sichuan Inst. Tech./Nanjing University[47] | Nanjing, China | 23 April 2002 | Reciprocating | ? | 23 | 1.4 (P) | Gd spheres and Gd5Si1.985Ge1.985Ga0.03 powder | ||
Chubu Electric/Toshiba[48] | Yokohama, Japan | October 5, 2002 | Reciprocating | 40 | 27 | 0.6 (P) | Gd 1−xDy x L.B. | ||
Chubu Electric/Toshiba[48] | Yokohama, Japan | March 4, 2003 | Rotary | 60 | 10 | 0.76 (P) | Gd 1−xDy x L.B. |
1 | |
Lab. d’Electrotechnique Grenoble[49] | Grenoble, France | April 2003 | Reciprocating | 8.8 | 4 | 0.8 (P) | Gd foil | ||
George Washington University[50] | US | July 2004 | Reciprocating | ? | 5 | 2 (P) | Gd foil | ||
Astronautics[51] | Madison, Wisconsin, US | 2004 | Rotary | 95 | 25 | 1.5 (P) | Gd and GdEr spheres / La(Fe 0.88Si130− 0.12H 1.0 | ||
University of Victoria[52] | Victoria, British Columbia Canada | 2006 | Reciprocating | 15 | 50 | 2 (S) | Gd, Gd 0.74Tb 0.26 and Gd 0.85Er 0.15 pucks |
0.12 | |
University of Salerno[53] | Salerno, Italy | 2016 | Rotary | 250 | 12 | 1.2 (P) | Gd 0.600 mm spherical particles | 1.20 | 0.5 - 2.5 |
MISiS[54] | Tver and Moscow, Russia | 2019 | High speed rotary | ? | ? | ? | Gd bricks of two types, cascaded | ||
1maximum cooling power at zero temperature difference (ΔT=0); 2maximum temperature span at zero cooling capacity (W=0); L.B. = layered bed; P = permanent magnet; S = superconducting magnet; 3 COP values under different operating conditions |
In one example, Prof. Karl A. Gschneidner, Jr. unveiled a proof of concept magnetic refrigerator near room temperature on February 20, 1997. He also announced the discovery of the GMCE in Gd
5Si
2Ge
2 on June 9, 1997.[12] Since then, hundreds of peer-reviewed articles have been written describing materials exhibiting magnetocaloric effects.
See also
- Coefficient of performance (COP)
- Cryostat
- Curie's law
- Dilution refrigerator
- Electrocaloric effect
- Thermoacoustic refrigeration
References
- .
- ^ S2CID 122788079.
- ^ S2CID 196706851.
- ^ .
- ^ S2CID 18956148.
- ISBN 0-486-24072-X.
- ^ a b Karl Gschneidner Jr. & Kerry Gibson (December 7, 2001). "Magnetic Refrigerator Successfully Tested". Ames Laboratory News Release. Ames Laboratory. Archived from the original on March 23, 2010. Retrieved 2006-12-17.
- ISBN 0-19-850341-5.
- S2CID 136263783.
- ^ S2CID 98040294.
- ^ .
- ^ PMID 24751772.
- PMID 23887357.
- ISBN 9780073398174.
- S2CID 4646639.
- ^ "GE Global Research Live". Archived from the original on 2015-02-18. Retrieved 2015-02-18.
- ^ "Your next fridge could keep cold more efficiently using magnets". gizmag.com. 2014-02-14.
- ^ S2CID 56381721.
- .
- S2CID 244005391.
- ^ Gibson, Kerry (November 2001). "Magnetic Refrigerator Successfully Tested: Ames Laboratory developments help push boundaries of new refrigeration technology". INSIDER Newsletter for employees of Ames Laboratory. Archived from the original on 2010-05-27.(Vol. 112, No.10 )
- ^ Milestone in magnetic cooling, Risø News, August 20, 2007 Archived September 5, 2007, at the Wayback Machine. Retrieved August 28, 2007.
- ^ "Premiere of cutting-edge magnetocaloric cooling appliance". BASF. Archived from the original on 2015-01-06. Retrieved 16 July 2015.
- ^ "Solid state cooling". BASF New Business GmbH. Retrieved 23 March 2018.
- ^ first magnetocaloric medical cabinet
- ^ [1]
- ^ [2]
- ^ largest magnetocaloric prototype
- ^ Dr. Sergiu Lionte's speech at Thermag VIII conference as invited speaker
- ^ "DDMC 2019". TU Delft (in Dutch). Retrieved 2021-11-07.
- S2CID 213786208.
- ^ Sand, J. R.; Vineyard, E. A.; Bohman, R. H. (2012-08-31) [1995]. Improving the energy efficiency of refrigerators in India (PDF). Annual meeting of the American Society of Heating, Refrigeration and Air-Conditioning Engineers, Inc. (ASHRAE), San Diego, CA (United States), 24-28 Jun 1995. US Department of Energy, Office of Scientific and Technical Information. Retrieved 2012-10-04.
- .
- ^ Aprea, C., Greco, A., Maiorino, A. GeoThermag: A geothermal magnetic refrigerator (2015) International Journal of Refrigeration, 59, pp. 75-83.
- .
- .
- .
Gschneidner, K. A. Jr.; Pecharsky, V. K. (2002). Chandra, D.; Bautista, R. G. (eds.). Fundamentals of Advanced Materials for Energy Conversion. Warrendale, PA: The Minerals, Metals and Materials Society. p. 9. - S2CID 52855399.
- ISBN 978-1-4757-9049-8.
- .
- .
- .
- ^ Rowe A.M. and Barclay J.A., Adv. Cryog. Eng. 47 995 (2002).
- S2CID 122081896.
- ^ Zimm C, Paper No K7.003 Am. Phys. Soc. Meeting, March 4, Austin, Texas (2003) "Archived copy". Archived from the original on 2004-02-29. Retrieved 2006-06-12.
{{cite web}}
: CS1 maint: archived copy as title (link) - ^ Wu W., Paper No. K7.004 Am. Phys. Soc. Meeting, March 4, Austin, Texas (2003) "Archived copy". Archived from the original on 2004-02-29. Retrieved 2006-06-12.
{{cite web}}
: CS1 maint: archived copy as title (link) - ^ a b Hirano N., Paper No. K7.002 Am. Phys. Soc. Meeting March 4, Austin, Texas, "Archived copy". Archived from the original on 2004-02-29. Retrieved 2006-06-12.
{{cite web}}
: CS1 maint: archived copy as title (link) - .
- .
- ^ Zimm C, Paper No. K7.003 Am. Phys. Soc. Meeting, March 4, Austin, Texas (2003) "Archived copy". Archived from the original on 2004-02-29. Retrieved 2006-06-12.
{{cite web}}
: CS1 maint: archived copy as title (link) - .
- .
- ^ "Российские инженеры создали высокоэффективный магнитный холодильник".
Further reading
- Lounasmaa, Experimental Principles and Methods Below 1 K, Academic Press (1974).
- Richardson and Smith, Experimental Techniques in Condensed Matter Physics at Low Temperatures, Addison Wesley (1988).
- Lucia, U (2008). "General approach to obtain the magnetic refrigeration ideal Coefficient of Performance COP". Physica A: Statistical Mechanics and Its Applications. 387 (14): 3477–3479. .
- Bouhani, H (2020). "Engineering the magnetocaloric properties of PrVO3 epitaxial oxide thin films by strain effects". Applied Physics Letters. 117 (7): 072402. S2CID 225378969.
- de Souza, M. (2021). "Elastocaloric-effect-induced adiabatic magnetization in paramagnetic salts due to the mutual interactions". Scientific Reports. 11 (9461): 9431. PMID 33941810.
External links
- Cooling by adiabatic demagnetization - The Feynman Lectures on Physics
- What is magnetocaloric effect and what materials exhibit this effect the most?
- Ames Laboratory news release, May 25, 1999, Work begins on prototype magnetic-refrigeration unit.
- Refrigeration Systems Terry Heppenstall's notes, University of Newcastle upon Tyne (November 2000)
- XRS Adiabatic Demagnetization Refrigerator
- Executive Summary: A Continuous Adiabatic Demagnetization Refrigerator (.doc format) (Google cache)
- Origin and tuning of the magnetocaloric effect in the magnetic refrigerant Mn1.1Fe0.9(P0.8Ge0.2)
- [3] Magnetic technology revolutionizes refrigeration]
- Evaluation of thermodynamic quantities in magnetic refrigeration