Potassium amide
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| Names | |
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| IUPAC name
Potassium amide
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| Other names
Potassamide
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| Identifiers | |
3D model (
JSmol ) |
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| ChemSpider | |
ECHA InfoCard
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100.037.508 |
| EC Number |
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PubChem CID
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CompTox Dashboard (EPA)
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SMILES
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| Properties | |
| KNH2 | |
| Molar mass | 55.121 g·mol−1 |
| Appearance | white solid |
| Odor | ammonia-like |
| Density | 1.57 g/cm 3 |
| Melting point | 338 °C (640 °F; 611 K) |
| reacts | |
| Solubility | ammonia: 3.6 g/(100 mL) |
| Thermochemistry | |
Std enthalpy of (ΔfH⦵298)formation |
−128.9 kJ/mol |
| Related compounds | |
Other cations
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Lithium amide Sodium amide |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Potassium amide is an
Production
Potassium amide is produced by the reaction of ammonia with potassium. The reaction typically requires a catalyst.[2]
Structure
Traditionally KNH2 is viewed as a simple salt, but it has significant covalent character and is highly aggregated in ammonia solution.[citation needed] The compound has been characterized by X-ray crystallography as the solvent-free form[3] as well as the mono- and diammonia solvates. In KNH2·2NH3, the potassium centers are each bonded to two amido ligands and four ammonia ligands, all six of which bridge to adjacent potassium centers. The result is a chain of hexacoordinate potassium ions. The K–NH2 distances are 2.7652(11) whereas the K–NH3 distances are respectively 2.9234(11) and 3.0698(11) Å.[4]
References
- ISBN 0471936235.
- ^ O. Glemser, H. Sauer (1963). "Silver Amide". In G. Brauer (ed.). Handbook of Preparative Inorganic Chemistry, 2nd Ed. Vol. 1. NY, NY: Academic Press. p. 1043.
- .
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