Rhenium trioxynitrate
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Other names
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3D model (
JSmol ) |
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| Properties | |
| ReO3NO3 | |
| Molar mass | 296.21 g/mol |
| Appearance | Pale yellow solid[1] |
| Melting point | 75 °C (167 °F; 348 K)[1] (decomposes) |
| Reacts | |
| Solubility | Insoluble in carbon tetrachloride and DCM, soluble in N2O5[1][2] |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Rhenium trioxynitrate, also known as rhenium(VII) trioxide nitrate, is a chemical compound with the formula ReO3NO3. It is a white solid that readily hydrolyzes in moist air.[1]
Preparation and properties
Rhenium trioxynitrate is prepared by the reaction of ReO3Cl (produced by reacting rhenium trioxide and chlorine) and dinitrogen pentoxide:[1]
- ReO3Cl + N2O5 → ReO3NO3 + NO2Cl
The ReO3Cl can be replaced with
rhenium heptoxide, however, this produces an impure product. This compound reacts with water to produce perrhenic acid and nitric acid.[1]
When heated above 75 °C, it decomposes to rhenium heptoxide, nitrogen dioxide, and oxygen:[1]
- 4 ReO3NO3 → 2 Re2O7 + 2 NO2 + O2
A graphite intercalation compound can be produced by reacting a mixture of rhenium trioxynitrate and dinitrogen pentoxide with graphite.[2]
Structure
IR spectroscopic evidence rejects the formulations NO2+ReO4– or Re2O7·N2O5, but instead suggests a polymeric structure with a monodentate nitrate ligand.[1][3]
References
- ^ .
- ^ .
- PMID 11851489.