Fluoride nitrate
Fluoride nitrates are
mixed anion compounds that contain both fluoride ions and nitrate ions. Compounds are known for some amino acids
and for some heavy elements. Some transition metal fluorido complexes that are nitrates are also known. There are also fluorido nitrato complex ions known in solution.
List
name | formula | mw | crystal system | space group | unit cell Å | volume | density | comment | reference |
---|---|---|---|---|---|---|---|---|---|
L-Argininium | L-Arg2+•F−•NO3− | triclinic | P1 | a=5.0130 b=10.6161 c=11.0352 α=87.471 β=86.038 γ=78.157 Z=2 | [1] | ||||
2L-Arg2+•F−•3NO3−•HF | orthorhombic | P212121 | a=7.3960 b=12.8672 c=26.990 Z=4 | [1] | |||||
L-histidine | L-His2+•F−•NO3− | [1] | |||||||
[Cr(NH3)5F](NO3)2 | [2] | ||||||||
hexakis(1H-imidazole)-cobalt(ii) fluoride nitrate tetrahydrate | [Co(Im)6][F·NO3•(H2O)4] | hexagonal | P63/m | a 8.972 c 21.077 Z=2 | 1469.3 | 1.402 | pink | [3] | |
[Co(NH3)4(OH)F]NO3 | [4] | ||||||||
[Co(NH3)5F](NO3)2 | [5] | ||||||||
[Co(NH3)6]F(NO3)2 | [4] | ||||||||
[Co(en)2F2]NO3 | [4] | ||||||||
[As(ONO2)4]+[AsF6]− | pale yellow; hydroscopic | [6] | |||||||
[Zr2F3OH(NO3)2(H2O)5]2+ | in solution | [7] | |||||||
SnF2(ONO2)2 | [6] | ||||||||
SnF3(ONO2) | stable < 40°C; hydroscopic | [6] | |||||||
SbF(ONO2)4 | [6] | ||||||||
SbF3(ONO2)2 | [6] | ||||||||
Xenon fluoride nitrate | FXeONO2 | monoclinic | a = 4.6663 b = 8.799 c = 9.415 β = 90.325° | 386.6 | 3.648 | ||||
CsFHONO2 | [8] | ||||||||
[HfF4NO3]− | in solution | [7] | |||||||
[HfF3(NO3)2]− | in solution | [7] | |||||||
Hg3O2(NO3)F | orthorhombic | Pnma | a=7.547 b=10.990 c=6.9906 | birefringence Δn = 0.23 @ 1064 nm | [9] | ||||
Pb3F5NO3 | triclinic | P1 | a 7.3796 b 12.147 c 16.8549, α 100.46° β 90.076° γ 95.517° | layered; stable to 450°C | [10][11] | ||||
Pb(OF)Cu3(SeO3)2(NO3) | trigonal | R3m | a 6.6973 c 18.5548 Z=3 | 720.75 | 5.175 | yellow; stable to 400°C | [12] | ||
PbCdF(SeO3)(NO3) | orthorhombic | Pca21 | a=11.121 b=10.366 c=5.3950 | NLO 2.6×KDP; band gap 4.42 eV | [13] | ||||
BaPb2F5NO3 | [14] | ||||||||
Bi2OF3(NO3) | hexagonal | P63/m | band gap 3.5 eV | [15] | |||||
Bi6O6F5(NO3) | trigonal | R3 | band gap 4.0 eV | [15] | |||||
[(UO2)4F13][Sr3(H2O)8](NO3)·H2O | 1814.13 | triclinic | P1 | a = 10.793, b = 10.918, c = 13.231 α = 92.570°, β = 109.147°, γ = 92.778° Z = 2. | 1468.1 | 4.105 | yellow | [16] |
References
- ^ ISBN 978-3-319-06298-3.
- ISSN 0163-1829.
- ISSN 1466-8033.
- ^ ISSN 0022-4944.
- S2CID 97374902.
- ^ ISSN 0009-2940.
- ^ S2CID 233628149.
- .
- ISSN 2052-1553.
- ISSN 1528-7483.
- PMID 11942835.
- S2CID 222235842.
- S2CID 52136440.
- ^ CHARKIN, DMITRI O. (2019). "NEW STRUCTURAL ANALOGIES AMONG LAYERED NITRATES AND HALIDES: SYNTHESIS AND STRUCTURE OF A NEW SILLéN-DERIVED FLUORIDE NITRATE, BAPB2F5NO3".
- ^ ISSN 0020-1669.
- PMID 27934437.