Number density

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The number density (symbol: n or ρN) is an

N) is sometimes used in chemistry for the same quantity, particularly when comparing with other concentrations
.

Definition

Volume number density is the number of specified objects per unit volume:[1]

where N is the total number of objects in a volume V.

Here it is assumed

error, however V is chosen to be small enough that the resulting n does not depend much on the size or shape
of the volume V because of large-scale features.

Area number density is the number of specified objects per unit area, A:

Similarly, linear number density is the number of specified objects per unit length, L:

Column number density is a kind of areal density, the number or count of a substance per unit area, obtained integrating volumetric number density along a vertical path:

It's related to
column mass density
, with the volumetric number density replaced by the volume mass density.

Units

In

yardstick: n0 = 1 amg = 2.6867774 × 1025 m−3 is often introduced as a unit of number density, for any substances at any conditions (not necessarily limited to an ideal gas at 0 °C and 1 atm).[3]

Usage

Using the number density as a function of spatial coordinates, the total number of objects N in the entire volume V can be calculated as

where dV = dx dy dz is a volume element. If each object possesses the same mass m0, the total mass m of all the objects in the volume V can be expressed as

Similar expressions are valid for

extensive quantity
associated with countable objects. For example, replacing m with q (total charge) and m0 with q0 (charge of each object) in the above equation will lead to a correct expression for charge.

The number density of

solute molecules in a solvent is sometimes called concentration, although usually concentration is expressed as a number of moles per unit volume (and thus called molar concentration
).

Relation to other quantities

Molar concentration

For any substance, the number density can be expressed in terms of its

/m3) as
where NA is the
spatial dimension unit, metre, in both n and c is consistently replaced by any other spatial dimension unit, e.g. if n is in cm−3 and c is in mol/cm3, or if n is in L
−1 and c is in mol/L, etc.

Mass density

For

mass density
ρm (in kg/m3) as
Note that the ratio M/NA is the mass of a single atom or molecule in kg.

Examples

The following table lists common examples of number densities at 1 atm and 20 °C, unless otherwise noted.

Molecular[4] number density and related parameters of some materials[citation needed]
Material Number density, n
Amount concentration
, c
Mass density
, ρm
Molar mass, M
(1027 m−3 = 1021 cm−3) (amg) (103 mol/m3 = mol/L) (103 kg/m3 = g/cm3) (10−3 kg/mol = g/mol)
Ideal gas 0.02504 0.932 0.04158 41.58 × 10−6 M M
Dry air 0.02504 0.932 0.04158 1.2041 × 10−3 28.9644
Water 33.3679 1,241.93 55.4086 0.99820 18.01524
Diamond 176.2 6,556 292.5 3.513 12.01

See also

  • Columnar number density

References and notes

  1. ^ For elemental substances, atomic densities/concentrations are used