Phosphide iodide
Appearance
Phosphide iodides or iodide phosphides are compounds containing
mixed anion compounds. They are in the category of pnictidehalides. Related compounds include the phosphide chlorides, arsenide iodides antimonide iodides and phosphide bromides
.
Phosphorus can form clusters or chains in these compounds, so that some are 1-dimensional or fibrous.
Phosphide iodides are often metallic, black or dark red in colour.
List
formula | system | space group | unit cell Å | volume | density | comment | ref |
---|---|---|---|---|---|---|---|
[Si40P6]I6.5 | cubic | Pm3n | a=10.1293 Z=1 | 1039.3 | 3.412 | clathrate | [1] |
K4P21I | orthorhombic | Ccmm | a = 12.853; b = 21.795; c = 9.748 Z = 4 | 2730.7 | 2.271 | ruby red;sensitive to air | [2] |
Ca2PI | trigonal | R3m | a=4.30 c=22.17 | 3.2 | yellow | [3] | |
Ca3PI3 | cubic | I4132 | a=12.31 Z=8 | 3.78 | colourless | [3] | |
Cu2P3I2 | monoclinic | P21c | a = 15.343, b = 12.925, c = 15.260, β = 116.38°, Z = 16 | band gap 0.72 eV; Cu ion conductor | [4][5][6] | ||
Cu3P15I2 | monoclinic | P21/n | a=9.667, b=19.475, c=9.886, β =108.75(2)°, Z=4 | 1762.4 | grey | [5][7] | |
(CuI)3P12 | monoclinic | P21 | a=12.846 b=13.857 c=9.651 β=109.43 Z=4 | 1620.2 | 3.866 | shiny | [5] |
(CuI)2P14 | monoclinic | P21/c | a = 9.919, b = 9.718, c = 16.478, β = 105.71°, Z = 4 | 1529.0 | 3.539 | [8] | |
(CuI)5P16S | [9] | ||||||
(CuI)3P4S4 | hexagonal | P63cm | a=19.082, c=6.691 Z=6 | 2109.9 | [10] | ||
(CuI)8P12 | monoclinic | P121/c1 | a=15.343, b=12.925, c=15.26, β=116.38 | 4.64 | [11] | ||
Ge38P8I8 | Cubic | P43n | a=10.507 | silvery | [12] | ||
(CuI)5P16Se | [9] | ||||||
(CuI)2P8Se3 | Pbcm | a=9.1348 b=12.351 c=13.873 Z=4 | 1565.2 | 3.673 | red; melt 408 °C; P8Se3 clusters | [13] | |
(CuI)3P4Se4 | hexagonal | P63cm | a = 19.601, c = 6.7196, Z = 6 | orange | [14] | ||
Zn3PI3 | cubic | F42m | a=5.945 | 4.87 | dark grey; dec 300 °C | [15] | |
(ZnI2)6ZnSP4S3 | [11] | ||||||
(ZnI2)6ZnSeP4Se3 | cubic | F43c | a=19.542 | 7463.1 | 4.325 | brown | [11] |
Rb4P21I | orthorhombic | Ccmm | a = 13.281; b = 21.868; c = 9.771 Z=4 | 2838.1 | 2.619 | dark red | [2] |
Sr2P7I | cubic | P213 | a=10.25 | dark red; contains heptaphosphanortricyclane | [16] | ||
Zr6I14P | orthorhombic | Cmca | [17] | ||||
Ag2P3I2 | monoclinic | Ag ion conductor | [4] | ||||
(AgI)2Ag3PS4 | hexagonal | P63mc | a=7.395 c=12.224 Z=2 | 579.1 | Ag ion conductor | [18] | |
Cd2P3I | monoclinic | C2/c | a=8.255 b=9.304 c=7.514 β =99.66 | [19] | |||
Cd3PI3 | hexagonal | P63mc | band gap 2.44 eV | [20] | |||
Cd4P2I3 | orthorhombic | Pbca | a=12.890 b=12.725 c=12.654 | P24− | [19] | ||
SnIP | soft and flexible; double helix SnI+ and P−; band gap 1.9 eV | [21][22] | |||||
Sn24P19.3I8 | cubic | Pm3n | a=10.9554 | [23] | |||
Sn24P19.3BrxI8−x | cubic | Pm3n | [24] | ||||
Sn24P19.3(2)ClyI8−y (y ≤ 0.8) | cubic | Pm3n | [24] | ||||
Sn20Zn4P20.8I8 | cubic | Pm3n | a=10.883 Z=1 | [25] | |||
Sn17Zn7P22I8 | cubic | Pm3n | a=10.8458 Z=1 | [25] | |||
Sn14In10P22I8 | cubic | Pm3n | a=11.0450 Z=1 | 1347.4 | 5.535 | black | [26] |
Sn14In10P21.2I8 | P42/m | a=24.745, c=11.067, Z=5 | 6776 | 5.521 | black | [26] | |
[Ge30.5Sn7.7P7.75]I7.88 | cubic | Pm3n | a=10.721 Z=1 | [27] | |||
Sn24AsxP19.3−xI8 | cubic | Pm3n | a = 10.9358—11.1495 | [28] | |||
Cs0.35Zr6I14P | orthorhombic | Cmca | a=15.934 b=14.287 c=12.939 Z=4 | black | [17] | ||
Ba2P7I | monoclinic | P21/m | a=6.3538 b=6.8990 c=12.0392 β =95.515 Z=2 | 524.93 | 3.912 | orange-yellow; water sensitive | [29] |
Ba3P3I2 | orthorhombic | Pnma | a = 17.195, b = 4.624, c = 14.272, Z = 4, | [30] | |||
Ba5P5I3 | monoclinic | C2/m | a = 42.664, b = 4.56.3, c = 9.431, β = 92.20, Z = 4 | [30] | |||
La2PI2 | trigonal | P3m1 | a=4.236 c=10.121 Z=1 | 157.25 | 4.95 | [31] | |
Eu2PI | R3m | a = 4.445, c = 23.12.6, Z = 3 | [32] | ||||
Eu2P7I | cubic | P213 | dark red; contains heptaphosphanortricyclane; band gap 1.7 eV | [16] | |||
Au7P10I | trigonal | P31m | a=6.180 c=11.122 Z=1 | [33] | |||
Hg9P5I6 | monoclinic | a=13.112 b=12.486 c=17.031 β=119.90 | [34] | ||||
Hg4ZnPI4 | monoclinic | P21 | a = 7.850, b = 12.719, c = 7.861, β = 119.52°, Z = 2 | like Millon phases | [35] | ||
Hg7Ag2P8I6 | monoclinic | C12/m1 | a=13.146 b=11.037 c=8.336 β=102.210 Z=2 | 1182.1 | 7.386 | black | [36] |
Hg12Ag41P88I41 | cubic | Fm3 | a=26.705 Z=4 | 19045 | 5.147 | dark red; air stable; P113− clusters | [37] |
HgAg6P20I2 | monoclinic | P21/m | a = 6.718, b = 27.701, c = 7.383, β = 113.98°, Z = 2 | [38] |
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