Praseodymium pentaphosphide

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Praseodymium pentaphosphide
Identifiers
3D model (
JSmol
)
  • InChI=1S/5P.Sm
    Key: BOIVIBBFKRHHPN-UHFFFAOYSA-N
  • [Pr+2].[P-].[P-].[P].[P].[P]
Properties
P5Pr
Molar mass 295.78
Appearance black crystals
Density 3.8 g/cm3
Melting point 697 °C (1,287 °F; 970 K)
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Praseodymium pentaphosphide is a binary inorganic compound of praseodymium metal and phosphorus with the chemical formula PrP5.

Preparation

Praseodymium pentaphosphide can be prepared by heating stoichiometric amounts of praseodymium and phosphorus at 700 °C:

Pr + 5P → PrP5

Properties

Praseodymium pentaphosphide crystallizes in the monoclinic crystal system, space group P21/m, cell parameters a = 0.4938 nm, b = 0.9595 nm, c = 0.5482 nm, β = 103.64°, Z = 2, with the same structure as neodymium pentaphosphide (NdP5).[1][2]

The compound is formed by a

peritectic reaction at a temperature of 697 °C.[3]

References