Iodine heptafluoride
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| Names | |||
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| Other names
Iodine(VII) fluoride
Heptafluoroiodine | |||
| Identifiers | |||
3D model (
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ECHA InfoCard
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100.037.241 | ||
PubChem CID
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CompTox Dashboard (EPA)
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| Properties | |||
| IF7 | |||
| Molar mass | 259.90 g/mol | ||
| Appearance | colorless gas | ||
| Density | 2.6 g/cm3 (6 °C) 2.7 g/cm3 (25 °C) | ||
| Melting point | 4.5 °C (40.1 °F; 277.6 K) (triple point) | ||
| Boiling point | 4.8 °C (40.6 °F; 277.9 K) (sublimes at 1 atm) | ||
| soluble [1] | |||
| Related compounds | |||
Related compounds
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iodine pentafluoride | ||
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Iodine heptafluoride is an
pentagonal bipyramidal structure, with D5h symmetry, as predicted by VSEPR theory.[4] The molecule can undergo a pseudorotational rearrangement called the Bartell mechanism, which is like the Berry mechanism but for a heptacoordinated system.[5]
Below 4.5 °C, IF7 forms a snow-white powder of colorless crystals, melting at 5-6 °C. However, this melting is difficult to observe, as the liquid form is thermodynamically unstable at
760 mmHg: instead, the compound begins to sublime at 4.77 °C. The dense vapor has a mouldy, acrid odour.[6][7]
Preparation
IF7 is prepared by passing
palladium or potassium iodide to minimize the formation of IOF5, an impurity arising by hydrolysis.[8][9] Iodine heptafluoride is also produced as a by-product when dioxygenyl hexafluoroplatinate is used to prepare other platinum(V) compounds such as potassium hexafluoroplatinate(V), using potassium fluoride in iodine pentafluoride solution:[10]
- 2 O2PtF6 + 2 KF + IF5 → 2 KPtF6 + 2 O2 + IF7
Reactions
Iodine heptafluoride decomposes at 200 °C to fluorine gas and iodine pentafluoride.[11]
Safety considerations
IF7 is highly irritating to both the skin and the mucous membranes. It also is a strong oxidizer and can cause fire on contact with organic material.
References
- ISBN 0-07-049439-8
- ^ Macintyre, J. E. (Ed.). (1992). Dictionary of Inorganic Compounds (Vol. 3). London: Chapman & Hall.
- ^ O'Neil, Maryadele J. (Ed.). (2001). The Merck Index (13th ed.). Whitehouse Station, NJ: Merck.
- .
- hdl:2027.42/71219.
- The CRC Handbook of Chemistry and Physics, 89th ed. p. 4-67.
- ^ Ruff & Keim 1930, pp. 180–182: "Das reine Jod-7-fluorid ist bei Zimmertemperatur ein farbloses Gas, das an der Luft infolge seiner Umsetzung mit dem Wasserdampf Nebel bildet und muffig sauer riecht. Beim Abkühlen wird es je nach den Versuchsbedingungen als leicht bewegliche, farblose Flüssigkeit als schneeweißes lockeres Pulver oder in Form farbloser Kristalle erhalten....Die Schmelztemperatur wurde durch Eintauchen von Proben, die in Quarzröhrchen eingeschmolzen waren, in Bäder passender Temperatur ermittelt und zu 5 bis 6° C gefunden. [Durch] Messung der Dampfdrucke...gelangt man zu der Gleichung ....Für den Druck von 760 mm errechnet sich eine Temperatur von 4,5° C. [Pure iodine heptafluoride is at room temperature a colorless gas, which forms a fog in air on account of its reaction with the humidity and smells musty and acrid. When cooled, it takes the form, depending on experimental conditions, of a free-flowing colorless liquid, a loose snow-white powder, or colorless crystals....The melting point was measured by immersion of a probe in a bath of the right temperature, which was melting in a little quartz tube and found to be 5‑6 °C. [From] measurement of the vapor pressure...one arrives at the equation....At a pressure of 760 mm it computes a temperature of 4.5 °C.]"
- .
- ^ Ruff & Keim 1930.
- ISBN 9780323148474.
- OCLC 19556260.
Common sources
- Ruff, Otto; Keim, Rudolf (1930-10-21). "Das Jod-7-fluorid" [Iodine Heptafluoride]. Zeitschrift für anorganische und allgemeine Chemie (in German). 193 (1/2): 176–186. ISSN 0863-1786.