Phosphorus tricyanide

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Phosphorus tricyanide
Names
Other names
Tricyanophosphine
Identifiers
3D model (
JSmol
)
ChemSpider
  • InChI=1S/C3N3P/c4-1-7(2-5)3-6
    Key: VXFKMOLPHLQGLH-UHFFFAOYSA-N
  • N#CP(C#N)C#N
Properties
P(CN)3
Appearance white crystals
Boiling point 190 °C (374 °F; 463 K) sublimes[1]
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Phosphorus tricyanide is an inorganic compound with the chemical formula P(CN)3. It can be produced by the reaction of phosphorus trichloride and trimethyl(iso)cyanosilane.[2] The reaction of phosphorus tribromide and silver cyanide in diethyl ether produce phosphorus tricyanide too.[1] Its thermal decomposition can produce graphite phase C3N3P.[3] Phosphorus tricyanide reacts with Re(CO)5FBF3 to form {P[CN-Re(CO)5]3}(BF4)3.[4]

References

  1. ^
    ISSN 0009-2940
    .
  2. ISSN 0002-7863. Archived from the original on 2022-06-25. Retrieved 2022-06-15.{{cite journal}}: CS1 maint: multiple names: authors list (link
    )
  3. ISSN 0897-4756. Archived from the original on 2022-06-15. Retrieved 2022-06-15.{{cite journal}}: CS1 maint: multiple names: authors list (link
    )
  4. doi:10.1002/zaac.201500068. Archived from the original on 2022-06-15. Retrieved 2022-06-15.{{cite journal}}: CS1 maint: multiple names: authors list (link
    )
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