Triphosphorus pentanitride
Names | |
---|---|
IUPAC name
Triphosphorus pentanitride
| |
Other names
Phosphorus(V) nitride, Phosphorus nitride
| |
Identifiers | |
3D model (
JSmol ) |
|
ECHA InfoCard
|
100.032.018 |
EC Number |
|
PubChem CID
|
|
CompTox Dashboard (EPA)
|
|
| |
Properties | |
P3N5 | |
Molar mass | 162.955 g/mol |
Appearance | White solid |
Density | 2.77 g/cm3 (α-P3N5) |
Melting point | 850 °C (1,560 °F; 1,120 K) decomposes |
insoluble | |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
|
Triphosphorus pentanitride is an
Synthesis
Triphosphorus pentanitride can be produced by reactions between various phosphorus(V) and nitrogen anions (such as ammonia and sodium azide):[1]
- 3 PCl5 + 5 NH3 → P3N5 + 15 HCl
- 3 PCl5 + 15 NaN3 → P3N5 + 15 NaCl + 20 N2
The reaction of the elements is claimed to produce a related material.
- (NPCl2)3 + 2 [NH4]Cl → P3N5 + 8 HCl
- 3 PCl5 + 5 [NH4]Cl → P3N5 + 20 HCl
P3N5 has also been prepared at room temperature, by a reaction between phosphorus trichloride and sodium amide.[5]
- 3 PCl3 + 5 NaNH2 → P3N5 + 5 NaCl + 4 HCl + 3 H2
Reactions
P3N5 is thermally less stable than either
- P3N5 → 3 PN + N2
- 4 PN → P4 + 2 N2
It is resistant to weak acids and bases, and insoluble in water at room temperature, however it
Triphosphorus pentanitride reacts with
Structure and properties
Several
Polymorph | Density (g/cm3) |
---|---|
α‑P3N5 | 2.77 |
α′‑P3N5 | 3.11 |
γ‑P3N5 | 3.65 |
δ‑P3N5 | 5.27 (at 72 GPa) |
The structure of all polymorphs of triphosphorus pentanitride was determined by
Potential applications
Triphosphorus pentanitride has no commercial applications, although it found use as a
Related halogen containing cyclic polymers, trimeric hexabromophosphazene (PNBr2)3 (melting point 192 °C) and tetrameric octabromophosphazene (PNBr2)4 (melting point 202 °C) find similar lamp gettering applications for tungsten halogen lamps, where they perform the dual processies of gettering and precise halogen dosing.[10]
Triphosphorus pentanitride has also been investigated as a
As a fuel in pyrotechnic obscurant mixtures, it offers some benefits over the more commonly used red phosphorus, owing mainly to its higher chemical stability. Unlike red phosphorus, P3N5 can be safely mixed with strong oxidizers, even potassium chlorate. While these mixtures can burn up to 200 times faster than state-of-the-art red phosphorus mixtures, they are far less sensitive to shock and friction. Additionally, P3N5 is much more resistant to hydrolysis than red phosphorus, giving pyrotechnic mixtures based on it greater stability under long-term storage.[13]
Patents have been filed for the use of triphosphorus pentanitride in fire fighting measures.[14][15]
See also
References
- ^ .
- .
- .
- .
- .
- .
- ^ .
- ^ .
- ^ S2CID 251743071.
- ISBN 0 7131 3267 1
- doi:10.1063/1.331380.
- S2CID 67837168.
- PMID 27862760
- ^ Phosphorus nitride agents to protect against fires and explosions
- ^ Manufacture of flame-retardant regenerated cellulose fibres, December 20, 1977