Silicon disulfide

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Silicon disulfide
Names
IUPAC name
silicon(IV) sulfide
Other names
silicon disulfide
Identifiers
3D model (
JSmol
)
ChemSpider
ECHA InfoCard
 100.033.935 Edit this at Wikidata
UNII
  • InChI=1S/S2Si/c1-3-2 checkY
    Key: KHDSWONFYIAAPE-UHFFFAOYSA-N checkY
  • InChI=1/S2Si/c1-3-2
    Key: KHDSWONFYIAAPE-UHFFFAOYAO
SMILES
  • monomer: S=[Si]=S
  • polymer: S=[Si](S0)S[Si]0(S0)S[Si]0(S0)S[Si]0(S0)S[Si]0(S0)S[Si]0(S0)S[Si]0=S
Properties
SiS2
Molar mass 92.218 g/mol
Appearance White (samples are sometimes grey or brown) needles.
Rotten egg smell in moist air.
Density 1.853 g/cm3
Melting point 1,090 °C (1,990 °F; 1,360 K) sublimes
Decomposes
Structure
Orthorhombic, oI12
Ibam, No.72[1]
Tetrahedral
Hazards
NFPA 704 (fire diamond)
NFPA 704 four-colored diamondHealth 2: Intense or continued but not chronic exposure could cause temporary incapacitation or possible residual injury. E.g. chloroformFlammability 2: Must be moderately heated or exposed to relatively high ambient temperature before ignition can occur. Flash point between 38 and 93 °C (100 and 200 °F). E.g. diesel fuelInstability 3: Capable of detonation or explosive decomposition but requires a strong initiating source, must be heated under confinement before initiation, reacts explosively with water, or will detonate if severely shocked. E.g. hydrogen peroxideSpecial hazards (white): no code
2
2
3
Related compounds
Other anions
 silicon dioxide
Other cations
 carbon disulfide
germanium disulfide
tin(IV) sulfide
lead(IV) sulfide
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
☒N verify (what is checkY☒N ?)

Silicon disulfide is the

forms
of SiO2.

Synthesis, structure, and properties

The material is formed by heating silicon and sulfur or by the exchange reaction between

tetrahedra, -Si(μ-S)2Si(μ-S)2-.[2]

Like other silicon sulfur-compounds (e.g., bis(trimethylsilyl)sulfide) SiS2 hydrolyzes readily to release H2S. In liquid ammonia it is reported to form the imide Si(NH)2 and NH4SH,[3] but a recent report has identified crystalline (NH4)2[SiS3(NH3)]·2NH3 as a product which contains the tetrahedral thiosilicate anion, SiS3(NH3)2-.[4]

Reaction with ethanol gives the alkoxide tetraethyl orthosilicate and H2S.[3] With bulky tert-butanol, alcoholysis gives tris(tert-butoxy)silanethiol:[5]

3 (CH3)3COH + SiS2 → [(CH3)3CO]3SiSH + H2S

Reaction with

aluminum sulfide give thiosilicates.[3]

SiS2 is claimed to occur in certain interstellar objects.[6]

References

  1. doi:10.1002/zaac.19542760110
    .
  2. picometers
    , when in fact that distance describes rSiS.
  3. ^
    ISBN 978-0-08-022057-4
    .
  4. PMID 19421590
    .
  5. doi:10.1002/zaac.19623180310
    .
  6. Bibcode:1993A&A...278..226G
    .


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