Diindenoperylene

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Diindenoperylene
Skeletal formula
Ball-and-stick model
Names
Preferred IUPAC name
Diindeno[1,2,3-cd:1′,2′,3′-lm]perylene
Other names
Periflanthen; Periflanthene
Identifiers
3D model (
JSmol
)
Abbreviations DIP
ChemSpider
ECHA InfoCard
 100.005.343 Edit this at Wikidata
UNII
  • InChI=1S/C32H16/c1-2-6-18-17(5-1)21-9-13-25-27-15-11-23-19-7-3-4-8-20(19)24-12-16-28(32(27)30(23)24)26-14-10-22(18)29(21)31(25)26/h1-16H ☒N
    Key: BKMIWBZIQAAZBD-UHFFFAOYSA-N ☒N
  • InChI=1/C32H16/c1-2-6-18-17(5-1)21-9-13-25-27-15-11-23-19-7-3-4-8-20(19)24-12-16-28(32(27)30(23)24)26-14-10-22(18)29(21)31(25)26/h1-16H
    Key: BKMIWBZIQAAZBD-UHFFFAOYAB
  • C1=CC2=C3C=CC4=C5C=CC6=C7C=CC=CC7=C8C6=C5C(=C9C4=C3C(=C2C=C1)C=C9)C=C8
Properties
C32H16
Molar mass 400.480 g·mol−1
Appearance Orange solid
Boiling point >330 °C (sublimation)
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
☒N verify (what is checkY☒N ?)

Diindenoperylene (DIP) is an

indeno-groups attached to opposite sides of the perylene core. Its chemical formula is C32H16, the full chemical name is diindeno[1,2,3-cd:1',2',3'-lm]perylene. Its chemical synthesis has been described.[1][2]

Properties and uses

The

soluble, for example in acetone
.

DIP is a red

field effect transistors of DIP have been studied.[8] The charge carrier mobility achieved was up to 0.1 cm2/(V·s) for thin film transistors with silicon dioxide as gate dielectric, making DIP a good candidate for further optimisation.[9]

The structure of bulk DIP crystals has recently been studied by Pflaum et al., who found two distinct phases at room temperature and at temperatures above 160 °C. In thin films for growth ‘near equilibrium’ (at substrate temperature of about 130 °C) by organic molecular beam deposition (OMBD), DIP has been shown to order very well.[2][10] The structure of thin DIP films has been characterized ‘post-growth’,[2][11][12][13] with structures differing from the room-temperature bulk structure. These thin-film structures depend on the substrate used, and also on the substrate temperature during growth.[10]

References

  1. ^ J. von Braun, G. Manz, in Deutsches Reichspatentamt, Berlin. (Germany, 1934).
  2. ^ a b c E. Clar, Polycyclic hydrocarbons (Academic Press, London, New York, 1964), p. 2
  3. doi:10.1063/1.1508436
    .
  4. ^ A. C. Dürr, Ph.D. thesis, Universität Stuttgart (2002)
  5. doi:10.1016/j.jlumin.2004.08.023
    .
  6. ^ H. E. Simmons. (1987)
  7. ^ H. Antoniadis, A. J. Bard. (Hewlett-Packard Company & The Board of Regents of The University of Palo Alto, CA, 1997)
  8. ^ M. Münch, Ph.D. thesis, Universität Stuttgart (2001)
  9. ISBN 3-540-66721-0
    pp. 283 ff.
  10. ^
    S2CID 1223144
    .
  11. PMID 12570630
    .
  12. doi:10.1103/PhysRevB.68.115428
    .
  13. doi:10.1016/0022-0248(91)90854-X
    .
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