Biodegradable athletic footwear

Source: Wikipedia, the free encyclopedia.
Most athletic footwear is not biodegradable

Biodegradable athletic footwear is

end-of-life phase. Such materials include natural biodegradable polymers, synthetic biodegradable polymers, and biodegradable blends. The use of biodegradable materials is a long-term solution to landfill
pollution that can significantly help protect the natural environment by replacing the synthetic, non-biodegradable polymers found in athletic footwear.

Problem of non-degradable waste

The United States athletic shoe market is a $13 billion-per-year dollar industry that sells more than 350 million pairs of athletic shoes annually.

end-of-life
waste.

Ethylene vinyl acetate copolymer

The athletic shoe

tropospheric ozone, which is harmful to humans and plant life."[5] Thermal degradation of EVA is temperature-dependent and occurs in two stages; in the first stage acetic acid is lost, followed by the degradation of the unsaturated polyethylene polymer.[4]

Environmental impact

The

environmental pollution of groundwater and rivers when disposed into landfills.[2] When disposed of in landfills, athletic footwear can take up to thousands of years to naturally degrade. EVA athletic shoe midsoles can be kept in contact with moist soil for a period of 12 years and experience little to no evidence of biodeterioration.[6]

Although there are some that are taking initiatives to produce environmentally friendly athletic footwear, most of the footwear industry's response to this increasing problem of end-of-life shoe waste has been negligible.

synthetic polymers such as ethylene-vinyl acetate with the ability to compost
at the end-of-life phase.

Biodegradable materials

"

biodegradable, there has been an increasing interest of biodegradable polymers that can lead to waste management options for polymers in the environment. These biodegradable polymers can be broken down into three categories: natural biodegradable polymer, synthetic biodegradable polymer, and biodegradable blends.[2]

Natural biodegradable polymers

Natural biodegradable polymers are formed in nature during growth cycles of all organisms.[4] When searching for natural fibers to replace synthetic materials in athletic shoes, the major natural biodegradable polymer that offers the most potential are polysaccharides. Starch is a polysaccharide that is useful because it readily degrades into harmless products when placed in contact with soil microorganisms.[8]

Enzymatic hydrolysis of starch.
Enzymatic hydrolysis of starch.[9]

Starch is not often used alone as a plastic material because of its brittle nature, but is commonly used as a biodegradation additive.[4] Many plasticizers use starch-glycerol-water to modify starch's brittle nature.[10] Biodegradation of this blend was tested and was found that by the second day the degraded carbon had already attained about 100% of the initial carbon of the sample.[2]

Synthetic biodegradable polymer

tri-carboxylic acid cycle and eliminated as carbon dioxide.[7]

Hydrolytic Degradation of the aliphatic polyester, PLA.
Hydrolytic Degradation of the aliphatic polyester, PLA.[7]

Biodegradable blends

Most synthetic polymers are resistant to microbial attack because of their physical and chemical properties.[9] However, they can become biodegradable when introducing natural polymers such as starch. Natural polymers introduce ester groups that attach to the backbone of non-biodegradable polymers, making them more susceptible to degradation.[9] Due to biodegradable polymers having limited properties; blending synthetic polymers can bring economic advantages and superior properties.[12]

Insertion of an ester group into vinyl polymer
Insertion of an ester group into vinyl polymer.[9]

End-of-life management

Although total elimination of post-consumer waste is not encouraged by any current change-causing agent due to the enormous change in infrastructure that the elimination of waste requires and the consequent lack of profitability for those agents, proactive approaches to reduce the enormous amount of waste that 350 million pairs of athletic shoes create can make a difference in the environment. Biodegradable materials, such as biodegradable polymers, are a viable solution to aid in avoiding the end-of-life athletic footwear waste consumption.[13] The major advantage of introducing biodegradable polymers to athletic footwear is the ability to compost with other organic wastes for it to become useful soil attendant products.

An alternative short-term approach to

end-of-life management is recycling activities in the footwear industry. One major shoe manufacture, Nike Inc., created Reuse-A-Shoe program that involves recycling discarded athletic shoes by grinding and shredding the shoes to produce a material called Nike Grind, which can be used in surfacing for tennis and basketball playgrounds or running tracks.[13] Currently, the Reuse-A-Shoe program recycles approximately 125,000 pairs of shoes per year in the United States. [citation needed
]

Recycling and composting are two major proposed solutions to end-of-life management. However, the use of biodegradable materials is a long-term solution that can significantly help protect the natural environment by replacing synthetic, non-biodegradable polymers found in athletic footwear. [citation needed]

See also

References

  1. ^ Pribut, Dr. Stephen. "A Brief History of Sneakers". Dr. Stephen M. Pribut's Sports Pages. APMA NEWS. Archived from the original on 28 July 2020. Retrieved 26 November 2014.
  2. ^ a b c d e Staikos, Theodoros; Heath, Richard; Haworth, Barry; Rahimifard, Shahin (2006). "End-of-Life Management of Shoes and the Role of Biodegradable Materials" (PDF). Proceedings of the 13th CIRP International Conference on Life Cycle Engineering: 497–502.
  3. ^ Chen, Nan. "The Effects of Crosslinking on Foaming." Diss. U of Toronto, 2012. Abstract. (2012): n. pag. Print.
  4. ^ a b c d e Costache, Marius C., David D. Jiang, and Charles A. Wilkie. "Thermal Degradation of Ethylene-vinyl Acetate Copolymer Nanocomposites." Polymer 46.18 (2005): 6947-958. Web.
  5. ^ a b Albers, Kyle, Peter Canepa, and Jennifer Miller. "Analyzing the Environmental Impacts of Simple Shoes." Diss. U of Santa Barbara, 2008. Abstract. (2008): n. pag. Print.
  6. ^ a b Katarzyna Leja, Grazyna Lewandowicz. "Polymer Biodegradation and Biodegradable Polymers-a Review." Polish Journal of Environmental Studies 2nd ser. 19.2010 (2012): 255-66. Web.
  7. ^ a b c d Albertsson, Ann-Christine. Degradable Aliphatic Polyesters. Vol. 157. Berlin: Springer, 2002. Print.
  8. ^ a b Díaz, Angélica, Ramaz Katsarava, and Jordi Puiggalí. "Synthesis, Properties and Applications of Biodegradable Polymers Derived From Diols and Dicarboxylic Acids: From Polyesters to Poly(Ester Amide)S." International Journal of Molecular Sciences 15.5 (2014): 7064-7123. Academic Search Complete. Web. 20 Oct. 2014.
  9. ^ a b c d e Chandra, R. "Biodegradable Polymers." Progress in Polymer Science 23.7 (1998): 1273-335. Web.
  10. ^ Wang, Xiu-Li, Ke-Ke Yang, and Yu-Zhong Wang. "Properties of Starch Blends with Biodegradable Polymers." Journal of Macromolecular Science, Part C: Polymer Reviews 43.3 (2003): 385-409. Web.
  11. ^ Renard, E., V. Langlois, and P. Guérin. "Chemical Modifications of Bacterial Polyesters: From Stability to Controlled Degradation of Resulting Polymers." Corrosion Engineering, Science and Technology 42.4 (2007): 300-11. Web.
  12. ^ Ma, Jianzhong, Liang Shao, Chaohua Xue, Fuquan Deng, and Zhouyang Duan. "Compatibilization and Properties of Ethylene Vinyl Acetate Copolymer (EVA) and Thermoplastic Polyurethane (TPU) Blend Based Foam." Springer-Verlag Berlin Heidelberg 71 (2014): 2219-234. Academic Search Complete. Web.
  13. ^ a b Song, J. H., R. J. Murphy, R. Narayan, and G. B. H. Davies. "Biodegradable and Compostable Alternatives to Conventional Plastics." Philosophical Transactions of the Royal Society B: Biological Sciences 364.1526 (2009): 2127-139. Web.open access