Organokrypton chemistry

Organokrypton chemistry describes the synthesis and properties of organokrypton compounds, chemical compounds containing a carbon to krypton chemical bond.

Far fewer such compounds are known than organoxenon compounds. The first organokrypton compound, HKrCCH, was reported in 2003 and made by photolytic insertion of a krypton atom into acetylene.^[1] Similar work was then done on diacetylene and cyanoacetylene, producing HKrC₄H and HKrC₃N.^[2] All these were made in matrix isolation and are stable up to 40 K.^[3] HKrCCF and HCCKrF have also been experimentally produced in matrix isolation.^[4]

Dications generated by dissociative electron ionisation of

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