Dioxathion

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Dioxathion
Skeletal formula of dioxathion
Ball-and-stick model of the dioxathion molecule
Names
IUPAC name
S,S'-1,4-dioxane-2,3-diyl O,O,O',O'-tetraethyl bis(dithiophosphate)
Other names
phosphorodithoic acid; S,S’-1,4-Dioxane- 2,3-Diyl
0,0,0’,0’-Tetraethyl Ester; Navadel; Delnatex;
Delnav; Deltic; dioxane phosphate
p-Dioxane-2,3-diyl ethyl phosphorodithioate
2,3-p-Dioxanethiol-S,S-bis(O,O-diethyl phosphoro-dithioate)
Identifiers
3D model (
JSmol
)
ChemSpider
ECHA InfoCard
100.001.007 Edit this at Wikidata
UNII
  • InChI=1S/C12H26O6P2S4/c1-5-15-19(21,16-6-2)23-11-12(14-10-9-13-11)24-20(22,17-7-3)18-8-4/h11-12H,5-10H2,1-4H3 checkY
    Key: VBKKVDGJXVOLNE-UHFFFAOYSA-N checkY
  • InChI=1/C12H26O6P2S4/c1-5-15-19(21,16-6-2)23-11-12(14-10-9-13-11)24-20(22,17-7-3)18-8-4/h11-12H,5-10H2,1-4H3
    Key: VBKKVDGJXVOLNE-UHFFFAOYAS
  • S=P(SC1OCCOC1SP(=S)(OCC)OCC)(OCC)OCC
Properties
C12H26O6P2S4
Molar mass 456.2 g/mol
Appearance Thick reddish-brown liquid/powder
Odor garlicky
Density 1.26 g/cm3
Melting point −20 °C (−4 °F; 253 K)
Insoluble
Hazards
Flash point noncombustible[1]
NIOSH (US health exposure limits):
PEL (Permissible)
none[1]
REL (Recommended)
TWA 0.2 mg/m3[1]
IDLH
(Immediate danger)
N.D.[1]
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
checkY verify (what is checkY☒N ?)

Dioxathion,

systematically known as p-dioxane-2,3-diyl ethyl phosphorodithioate, is an organophosphate pesticide. It is used as an insecticide on livestock and as an acaricide
on citrus fruits, deciduous fruits and nuts.

Uses

Under the trade name Delnav, it can be used to control insects and mites on apples, pears, quince, grapes, and walnuts, and finds use in the control of ticks, horn flies, lice and sheep keds in various livestock, either as a spray or as a dip. Under the trade name Deltic, it is a restricted use pesticide for exterior control of fleas, ticks and mites, in kennels, dog houses, yards, and other recreational areas.

Toxicity

Dioxathion is an

depression or irritability
.

Short-term effects may include irritation to the

salivation. These are mostly classic symptoms of organophosphate poisoning
.

Dioxathion must be stored away from

in case of severe poisoning.

References

  1. ^ a b c d NIOSH Pocket Guide to Chemical Hazards. "#0238". National Institute for Occupational Safety and Health (NIOSH).

External links