Fuel

Source: Wikipedia, the free encyclopedia.

Firewood was one of the first fuels used by humans.[1]

A fuel is any material that can be made to react with other substances so that it releases energy as thermal energy or to be used for work. The concept was originally applied solely to those materials capable of releasing chemical energy but has since also been applied to other sources of heat energy, such as nuclear energy (via nuclear fission and nuclear fusion).

The heat energy released by reactions of fuels can be converted into mechanical energy via a heat engine. Other times, the heat itself is valued for warmth, cooking, or industrial processes, as well as the illumination that accompanies combustion. Fuels are also used in the cells of organisms in a process known as cellular respiration, where organic molecules are oxidized to release usable energy. Hydrocarbons and related organic molecules are by far the most common source of fuel used by humans, but other substances, including radioactive metals, are also utilized.

Fuels are contrasted with other substances or devices storing potential energy, such as those that directly release electrical energy (such as batteries and capacitors) or mechanical energy (such as flywheels, springs, compressed air, or water in a reservoir).

History

Wood as fuel for combustion

The first known use of fuel was the combustion of firewood by Homo erectus nearly two million years ago.[citation needed] Throughout most of human history only fuels derived from plants or animal fat were used by humans. Charcoal, a wood derivative, has been used since at least 6,000 BCE for melting metals. It was only supplanted by coke, derived from coal, as European forests started to become depleted around the 18th century. Charcoal briquettes are now commonly used as a fuel for barbecue cooking.[citation needed]

Muhammad ibn Zakarīya Rāzi.[2] He described the process of distilling crude oil/petroleum into kerosene, as well as other hydrocarbon compounds, in his Kitab al-Asrar (Book of Secrets). Kerosene was also produced during the same period from oil shale and bitumen by heating the rock to extract the oil, which was then distilled. Rāzi also gave the first description of a kerosene lamp using crude mineral oil, referring to it as the "naffatah".[3]

The streets of

Abu al-Hasan 'Alī al-Mas'ūdī in the 10th century, and by Marco Polo in the 13th century, who described the output of those wells as hundreds of shiploads.[4]

With the development of the steam engine in the United Kingdom in 1769, coal came into more common use, the combustion of which releases chemical energy that can be used to turn water into steam.[5] Coal was later used to drive ships and locomotives. By the 19th century, gas extracted from coal was being used for street lighting in London. In the 20th and 21st centuries, the primary use of coal is to generate electricity, providing 40% of the world's electrical power supply in 2005.[6]

Fossil fuels were rapidly adopted during the

global warming and related effects that are caused by burning them.[7]

Currently the trend has been towards renewable fuels, such as

biofuels
like alcohols.

Chemical

Chemical fuels are substances that release energy by reacting with substances around them, most notably by the process of combustion.

Chemical fuels are divided in two ways. First, by their physical properties, as a solid, liquid or gas. Secondly, on the basis of their occurrence: primary (natural fuel) and secondary (artificial fuel). Thus, a general classification of chemical fuels is:

General types of chemical fuels
Primary (natural) Secondary (artificial)
Solid fuels wood, coal, peat, dung, etc. coke, charcoal
Liquid fuels petroleum diesel, gasoline, kerosene, LPG, coal tar, naphtha, ethanol
Gaseous fuels
natural gas
CNG

Solid fuel

Coal is a solid fuel

Solid fuel refers to various types of

industrial revolution, from firing furnaces, to running steam engines. Wood was also extensively used to run steam locomotives. Both peat and coal are still used in electricity generation
today. The use of some solid fuels (e.g. coal) is restricted or prohibited in some urban areas, due to unsafe levels of toxic emissions. The use of other solid fuels as wood is decreasing as heating technology and the availability of good quality fuel improves. In some areas, smokeless coal is often the only solid fuel used. In Ireland, peat briquettes are used as smokeless fuel. They are also used to start a coal fire.

Liquid fuels

A filling station

Liquid fuels are combustible or energy-generating molecules that can be harnessed to create mechanical energy, usually producing kinetic energy. They must also take the shape of their container; the fumes of liquid fuels are flammable, not the fluids.

Most liquid fuels in widespread use are derived from the

bio-diesel, which are all categorized as liquid fuels. Emulsified fuels of oil in water, such as orimulsion
, have been developed as a way to make heavy oil fractions usable as liquid fuels. Many liquid fuels play a primary role in transportation and the economy.

Some common properties of liquid fuels are that they are easy to transport and can be handled easily. They are also relatively easy to use for all engineering applications and in home use. Fuels like kerosene are rationed in some countries, for example in government-subsidized shops in India for home use.

Conventional

LP gas is a mixture of propane and butane, both of which are easily compressible gases under standard atmospheric conditions. It offers many of the advantages of compressed natural gas
(CNG) but is denser than air, does not burn as cleanly, and is much more easily compressed. Commonly used for cooking and space heating, LP gas and compressed propane are seeing increased use in motorized vehicles. Propane is the third most commonly used motor fuel globally.

  • Locomotive diesel
    Locomotive diesel
  • Gasoline
    Gasoline
  • Kerosene
    Kerosene
  • Petroleum based motor oil
    Petroleum based motor oil
  • Residual fuel oil or Bunker C oil
    Residual fuel oil or
    Bunker C oil

Fuel gas

A 20-pound (9.1 kg) propane cylinder

Fuel gas is any one of a number of fuels that are

light energy that can be readily transmitted and distributed through pipes from the point of origin directly to the place of consumption. Fuel gas is contrasted with liquid fuels and from solid fuels, though some fuel gases are liquefied for storage or transport. While their gaseous nature can be advantageous, avoiding the difficulty of transporting solid fuel and the dangers of spillage inherent in liquid fuels, it can also be dangerous. It is possible for a fuel gas to be undetected and collect in certain areas, leading to the risk of a gas explosion. For this reason, odorizers are added to most fuel gases so that they may be detected by a distinct smell. The most common type of fuel gas in current use is natural gas
.

Biofuels

Biofuel can be broadly defined as solid, liquid, or gas fuel consisting of, or derived from biomass. Biomass can also be used directly for heating or power—known as biomass fuel. Biofuel can be produced from any carbon source that can be replenished rapidly e.g. plants. Many different plants and plant-derived materials are used for biofuel manufacture.

Perhaps the earliest fuel employed by humans is wood. Evidence shows controlled fire was used up to 1.5 million years ago at

Homo were present at the sites.[8] As a fuel, wood has remained in use up until the present day, although it has been superseded for many purposes by other sources. Wood has an energy density of 10–20 MJ/kg.[9]

Recently biofuels have been developed for use in automotive transport (for example

]

Fossil fuels

Extraction of petroleum

Fossil fuels are

tar sands
. These latter sources are properly known as mineral fuels.

Fossil fuels contain high percentages of carbon and include coal, petroleum, and natural gas.[12] They range from

Georg Agricola in 1556 and later by Mikhail Lomonosov
in the 18th century.

It was estimated by the

World energy consumption
was growing about 2.3% per year.

Fossil fuels are

adverse effects
. Fuels are a source of energy.

Energy

The amount of energy from different types of fuel depends on the

stoichiometric ratio, the chemically correct air and fuel ratio to ensure complete combustion of fuel, and its specific energy
, the energy per unit mass.

Energy capacities
of common types of fuel
Fuel type Specific energy
(MJ/kg)
Air–fuel ratio
(stoichiometric)
Energy @ λ=1
(MJ/kg(Air))
Diesel 48 14.5 : 1 3.310
Ethanol 26.4 9 : 1 2.933
Gasoline 46.4 14.7 : 1 3.156
Hydrogen 142 34.3 : 1 4.140
Kerosene 46 15.6 : 1 2.949
LPG 46.4 17.2 : 1 2.698
Methanol 19.7 6.47 : 1 3.045
Methane 55.5 17.2 : 1 3.219
Nitromethane 11.63 1.7 : 1 6.841
Notes

kWh ≈ 0.37 HPh
.

(The fuel-air ratio (FAR) is the reciprocal of the air-fuel ratio (AFR).)

λ is the air-fuel equivalence ratio, and λ=1 means that it is assumed that the fuel and the oxidising agent (oxygen in air) are present in exactly the correct proportions so that they are both fully consumed in the reaction.

Nuclear

CANDU
("CANada Deuterium Uranium") fuel bundles, each about 50 cm long and 10 cm in diameter

Nuclear fuel is any material that is consumed to derive nuclear energy. In theory, a wide variety of substances could be a nuclear fuel, as they can be made to release nuclear energy under the right conditions. However, the materials commonly referred to as nuclear fuels are those that will produce energy without being placed under extreme duress. Nuclear fuel can be "burned" by nuclear fission (splitting nuclei apart) or fusion (combining nuclei together) to derive nuclear energy. "Nuclear fuel" can refer to the fuel itself, or to physical objects (for example bundles composed of fuel rods) composed of the fuel material, mixed with structural, neutron moderating, or neutron-reflecting materials.

Nuclear fuel has the highest energy density of all practical fuel sources.

Fission

Nuclear fuel pellets are used to release nuclear energy.

The most common type of nuclear fuel used by humans is heavy

fuel rods) composed of the fuel material, perhaps mixed with structural, neutron moderating
, or neutron reflecting materials.

When some of these fuels are struck by neutrons, they are in turn capable of emitting neutrons when they break apart. This makes possible a self-sustaining chain reaction that releases energy at a controlled rate in a nuclear reactor, or at a very rapid uncontrolled rate in a nuclear weapon.

The most common fissile nuclear fuels are

plutonium-239 (239Pu). The actions of mining, refining, purifying, using, and ultimately disposing of nuclear fuel together make up the nuclear fuel cycle. Not all types of nuclear fuels create energy from nuclear fission. Plutonium-238 and some other elements are used to produce small amounts of nuclear energy by radioactive decay in radioisotope thermoelectric generators and other types of atomic batteries
.

Fusion

In contrast to fission, some light nuclides such as tritium (3H) can be used as fuel for nuclear fusion. This involves two or more nuclei combining into larger nuclei. Fuels that produce energy by this method are currently not utilized by humans, but they are the main source of fuel for stars. Fusion fuels are light elements such as hydrogen whose nucleii will combine easily. Energy is required to start fusion by raising the temperature so high that nuclei can collide together with enough energy that they stick together before repelling due to electric charge. This process is called fusion and it can give out energy.

In stars that undergo nuclear fusion, fuel consists of

inertial confinement
(heating by laser) and heating by strong electric currents are the popular methods.

Liquid fuels for transportation

Most transportation fuels are liquids, because vehicles usually require high energy density. This occurs naturally in liquids and solids. High energy density can also be provided by an internal combustion engine. These engines require clean-burning fuels. The fuels that are easiest to burn cleanly are typically liquids and gases. Thus, liquids meet the requirements of being both energy-dense and clean-burning. In addition, liquids (and gases) can be pumped, which means handling is easily mechanized, and thus less laborious. As there is a general movement towards a low carbon economy, the use of liquid fuels such as hydrocarbons is coming under scrutiny.

See also

Footnotes

  1. .
  2. ^ Forbes, Robert James (1958). Studies in Early Petroleum History. Brill Publishers. p. 149.
  3. Saudi Aramco World
    . 46 (1): 20–27.
  4. .
  5. ^  One or more of the preceding sentences incorporates text from a publication now in the public domainChisholm, Hugh, ed. (1911). "Fuel". Encyclopædia Britannica. Vol. 11 (11th ed.). Cambridge University Press. pp. 274–286.
  6. ^ "History of Coal Use". World Coal Institute. Archived from the original on 7 October 2006. Retrieved 10 August 2006.
  7. ^ IPCC AR5 WG1 Summary for Policymakers 2013, p. 4: Warming of the climate system is unequivocal, and since the 1950s many of the observed changes are unprecedented over decades to millennia. The atmosphere and ocean have warmed, the amounts of snow and ice have diminished, sea level has risen, and the concentrations of greenhouse gases have increased; IPCC SR15 Ch1 2018, p. 54: Abundant empirical evidence of the unprecedented rate and global scale of impact of human influence on the Earth System (Steffen et al., 2016; Waters et al., 2016) has led many scientists to call for an acknowledgment that the Earth has entered a new geological epoch: the Anthropocene.
  8. ^ Rincon, Paul (22 March 2004). "Bones hint at first use of fire". BBC News. Retrieved 11 September 2007.
  9. ^ Elert, Glenn (2007). "Chemical Potential Energy". The Physics Hypertextbook. Retrieved 11 September 2007.
  10. ^ a b Dr. Irene Novaczek. "Canada's Fossil Fuel Dependency". Elements. Retrieved 18 January 2007.
  11. EPA. Archived from the original
    on 12 March 2007. Retrieved 18 January 2007.
  12. ^ "Fossil fuel". Archived from the original on 10 May 2012.
  13. ^ "Fossil fuel". EPA. Archived from the original on 12 March 2007. Retrieved 18 January 2007.
  14. ^ "U.S. EIA International Energy Statistics". Archived from the original on 27 May 2013. Retrieved 12 January 2010.
  15. ^ "International Energy Annual 2006". Archived from the original on 5 February 2009. Retrieved 8 February 2009.
  16. ^ "US Department of Energy on greenhouse gases". Retrieved 9 September 2007.
  17. .

Works cited

References

  • Ratcliff, Brian; et al. (2000). Chemistry 1. Cambridge University press. .

Further reading

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