Hamaker theory

Source: Wikipedia, the free encyclopedia.

After the explanation of

H. C. Hamaker, who derived the interaction between two spheres, a sphere and a wall, and presented a general discussion in a heavily cited 1937 paper.[1]

The interaction of two bodies is then treated as the pairwise interaction of a set of N molecules at positions: Ri {i:1,2,... ...,N}. The distance between the molecules i and j is then:

The interaction energy of the system is taken to be:

where is the interaction of molecules i and j in the absence of the influence of other molecules.

The theory is however only an approximation which assumes that the interactions can be treated independently, the theory must also be adjusted to take into account quantum perturbation theory.

References