Polymer chemistry

Source: Wikipedia, the free encyclopedia.
nylon 6,6
.

Polymer chemistry is a sub-discipline of chemistry that focuses on the structures of chemicals, chemical synthesis, and chemical and physical properties of polymers and macromolecules. The principles and methods used within polymer chemistry are also applicable through a wide range of other chemistry sub-disciplines like organic chemistry, analytical chemistry, and physical chemistry. Many materials have polymeric structures, from fully inorganic metals and ceramics to DNA and other biological molecules. However, polymer chemistry is typically related to synthetic and organic compositions. Synthetic polymers are ubiquitous in commercial materials and products in everyday use, such as plastics, and rubbers, and are major components of composite materials. Polymer chemistry can also be included in the broader fields of polymer science or even nanotechnology, both of which can be described as encompassing polymer physics and polymer engineering.[1][2][3][4]

History

The work of

Christian Schönbein in 1846 led to the discovery of nitrocellulose, which, when treated with camphor, produced celluloid. Dissolved in ether or acetone, it becomes collodion, which has been used as a wound dressing since the U.S. Civil War. Cellulose acetate was first prepared in 1865. In years 1834-1844 the properties of rubber (polyisoprene) were found to be greatly improved by heating with sulfur, thus founding the vulcanization
process.

In 1884

Emil Fischer, his direct supervisor, denying the possibility of any covalent molecule exceeding 6,000 daltons.[6] Cellophane was invented in 1908 by Jocques Brandenberger who treated sheets of viscose rayon with acid.[7]

aromatic nylon named Kevlar, patented in 1966. Karl Ziegler and Giulio Natta received a Nobel Prize for their discovery of catalysts for the polymerization of alkenes. Alan J. Heeger, Alan MacDiarmid, and Hideki Shirakawa were awarded the 2000 Nobel Prize in Chemistry for the development of polyacetylene and related conductive polymers.[8] Polyacetylene itself did not find practical applications, but organic light-emitting diodes (OLEDs) emerged as one application of conducting polymers.[9]

Teaching and research programs in polymer chemistry were introduced in the 1940s. An Institute for Macromolecular Chemistry was founded in 1940 in Freiburg, Germany under the direction of Staudinger. In America, a Polymer Research Institute (PRI) was established in 1941 by

Polytechnic Institute of NYU
).

Polymers and their properties

The viscosity of polymer solutions is a valued parameter. Viscometers such as this are employed in such measurements.

weight-average molecular weights
and , respectively.

The formation and properties of polymers have been rationalized by many theories including

Hoffman Nucleation Theory, Flory–Stockmayer theory
, and many others.

Segments of polypropylene, showing the slightly different structures of isotactic (above) and syndiotactic (below) polymers.

The study of polymer thermodynamics helps improve the material properties of various polymer-based materials such as

biodegradability, and altering a material's solubility.[10]

Viscosity

As polymers get longer and their molecular weight increases, their viscosity tend to increase. Thus, the measured viscosity of polymers can provide valuable information about the average length of the polymer, the progress of reactions, and in what ways the polymer branches.[11]

Composites are formed by combining polymeric materials to form an overall structure with properties that differ from the sum of the individual components.

Classification

Polymers can be classified in many ways. Polymers, strictly speaking, comprise most solid matter: minerals (i.e. most of the Earth's crust) are largely polymers, metals are 3-d polymers, organisms, living and dead, are composed largely of polymers and water. Often polymers are classified according to their origin:

A strand of cellulose showing the hydrogen bonds (dashed) within and between the chains.

Biopolymers are the structural and functional materials that comprise most of the organic matter in organisms. One major class of biopolymers are proteins, which are derived from amino acids. Polysaccharides, such as cellulose, chitin, and starch, are biopolymers derived from sugars. The polynucleic acids DNA and RNA are derived from phosphorylated sugars with pendant nucleotides that carry genetic information.

rubber, bakelite, Kevlar, and polyepoxide. Almost all synthetic polymers are derived from petrochemicals
.

See also

References

  1. ^ "The Macrogalleria: A Cyberwonderland of Polymer Fun". www.pslc.ws. Retrieved 2018-08-01.
  2. .
  3. ^ "The Early Years of Artificial Fibres". The Plastics Historical Society. Retrieved 2011-09-05.
  4. PMID 16948174{{citation}}: CS1 maint: multiple names: authors list (link
    )
  5. ^ "History of Cellophane". about.com. Archived from the original on June 29, 2012. Retrieved 2011-09-05.
  6. ^ "The Nobel Prize in Chemistry 2000". Retrieved 2009-06-02.
  7. S2CID 4328634
    .
  8. ^ X Zhang, X Peng, SW Zhang. "7 - Synthetic biodegradable medical polymers: Polymer blends" Science and Principles of Biodegradable and Bioresorbable Medical Polymers, 2017. 217-254.
  9. ^ "Viscosity of Polymer Solutions". polymerdatabase.com. Retrieved 2019-03-05.