User talk:Klaus Schmidt-Rohr

Glad to see another chemist join Wikipedia! Wikipedia:WikiProject Chemistry is one of several informal working-groups if you're looking for editors with interest and/or expertise in chemistry-related topics, ideas of what articles need work, etc. DMacks (talk) 20:38, 1 May 2016 (UTC)[reply]

Welcome to Wikipedia. Here are suggested readings:

• Wikipedia prefers citations to reviews and books, not primary journal references (tens of thousands appear annually). Citing secondary sources is the encyclopedic style.
• Do not cite yourself or your colleagues. It's called conflict of interest. Many new editors cite themselves mainly. That behavior indicates that you either are seeking to promote yourself or you dont know or care enough to promote work not published by you. So avoid self-citations! Tacky.

If you have questions, many editors can offer advice. Happy editing.--Smokefoot (talk) 14:38, 22 March 2020 (UTC)[reply]

Please do not add or change content, as you did at Mass in special relativity, without citing a reliable source. Please review the guidelines at Wikipedia:Citing sources and take this opportunity to add references to the article. Thank you.

Note- see also

Exothermic reaction and exergonic reaction would benefit from your inspection. These articles are probably heavily consulted.--Smokefoot (talk) 21:48, 1 August 2020 (UTC)[reply]

Good morning,

please express your opinion in the thread "relativistic mass" in the discussion with DVdm:

"The legitimacy of removing entries by DVdm in a topic of relativistic mass"

thank you in advance, Best Regards, RodriguesVector.

Thank you Klaus Schmidt-Rohr again for the opinion expressed in my "talk", I would like to ask for its "final" summary.

Unfortunately, the editor of the DVdm did not present the specification of objections as postulated by you. On the contrary, I have demonstrated the misapplication of Wikipedia rules.

In conditions where the editors do not follow Wikipedia's rules, I will be forced to give up.

Anyway, please "final" opinion on the topic.

Best regards RodriguesVector (talk) 10:31, 28 May 2021 (UTC)[reply]

Hello, editor Klaus Schmidt-Rohr. I would be glad if you would kindly chat with me on my talk page about the definition of enthalpy.Chjoaygame (talk) 20:50, 10 September 2021 (UTC)[reply]

Hi Klaus: you should remove your recent self-citations. Our guidelines advise against the practice, especially when the citation is to a primary source. --Smokefoot (talk) 01:17, 28 December 2021 (UTC)[reply]

I see that again you are putting citations to your own work into Wikipedia articles[1]. If your paper is important enough to be cited, other editors will add it. Xxanthippe (talk) 03:56, 7 February 2022 (UTC).[reply]

@

category. The guideline requires that any COI be fully revealed by the editor. A search of Wikipedia with "Schmidt-Rohr, K" gives 101 hits. I have not checked every one of them, and not all of them may be your own edits, but many of them identify citations to your papers inserted by yourself. You may care to fill in the details. I have not yet been able to find where you have given full disclosure of a COI for these edits. 101 is a large number; in contrast, searching Wikipedia with "Onsager, L", a Nobel prize winner who has made fundamental and famous contributions to Thermodynamics, gives 18 hits. It seems that your papers have had more than five times the impact on Wikipedia than Onsager's. You may wish to comment. Xxanthippe (talk) 08:43, 11 February 2022 (UTC).[reply

]

@User: Xxanthippe. All my edits have been of good quality, because I have a high level of expertise in the areas that I edit, and all citations I added are directly relevant to the statements added. Since Smokefoot alerted me to the issue of recent self-citations, I have not added any, except in the one case of Chemical potential that you are aware of.

Let’s take that case as a specific example. You had demanded that I add references to support my edits, so I did, including one self-citation that is fully justified to support a conclusion that even you as an expert were not aware of and that is not made in textbooks (and that editor Petergans has confirmed as correct). Please tell me a more important reference that makes that same scientific point, and I’ll gladly enter it; similarly in other cases. Just deleting relevant references without replacing them does not serve any reader of Wikipedia. Please leave it to other qualified editors without a personal vendetta due to a disagreement about a pet Wikipedia page to decide which citations are relevant and which are not.

I have been fully transparent about my identity – my username is my real name and the name under which I publish peer-reviewed articles. So there are no hidden conflicts of interest.

Instead of acting like an inquisitor, please focus on making Wikipedia better. I see that you have time but still have not corrected the four scientific errors (confirmed as such by editor Petergans) that you had re-introduced on Chemical potential. Please direct your energy to Wikipedia content corrections.

Klaus Schmidt-Rohr (talk) 14:11, 11 February 2022 (UTC)[reply]

No matter what level of expertise editors have (and it is rumored that some Nobel prize winners edit Wikipedia), they are expected to follow Wikipedia conventions like

WP:COI editing, and what you are going to do about the 101 violations of COI that you appear to have been responsible for in the past. Xxanthippe (talk) 03:40, 15 February 2022 (UTC).[reply

]

To avoid any appearance of COI, I can commit to adding no self-citations in the next three years (2022-2024). Klaus Schmidt-Rohr (talk) 01:27, 16 February 2022 (UTC)[reply]

• @User:Klaus Schmidt-Rohr. There is a COI matter[2] with which you may be involved. Also @User:Smokefoot. Xxanthippe (talk) 00:12, 21 February 2022 (UTC).[reply]

Just a note to tell you that I have fixed your citation for the Gislason and Craig article. You had written "ref name Gislason & Craig 2005", which the system rejected with the message "Cite error: The <ref> tag has too many names". This means that the system does not allow spaces inside a ref name, and apparently reads Gislason, &, Craig and 2005 as 4 separate ref names!! AnomieBOT produced another incorrect version, so I went back to yours and just removed the spaces, and also added an = after ref name. I fixed all 3 citations to this reference, and they are correctly shown now. Dirac66 (talk) 03:30, 3 February 2022 (UTC)[reply]

This is just to let you know I've reverted this edit of yours. I think I've explained why on the talk page, which is where further discussion of this, if any is required, should probably go. IpseCustos (talk) 21:11, 7 June 2022 (UTC)[reply]

Heat of combustion has an RFC for possible consensus. A discussion is taking place. If you would like to participate in the discussion, you are invited to add your comments on the discussion page. Thank you. IpseCustos (talk) 16:49, 11 June 2022 (UTC)[reply]

Hello, thanks for continuing the discussion in various forums. While you have reverted some of my changes, I notice you haven't reverted those referring to oxygen as "high-energy", an "energy source", or a storage medium of energy. I'm talking about these 56 articles, 9 of which have already been edited:

1. Adenosine triphosphate#Citric acid cycle "Oxygen provides the chemical energy driving the process"
2. Allotropes of oxygen#Dioxygen "the chemical energy stored in the weak sigma bond of atmospheric dioxygen"
3. Anaerobic organism#Energy metabolism "taking advantage of the high energy of O₂"
4. Anaerobic respiration: lede "molecular oxygen is a high-energy oxidizing agent"
5. Atmosphere of Earth#Evolution of Earth's atmosphere "oxygen is the high-energy molecule needed to power all complex life-forms"
6. Bioenergetic systems#Overview "the energy of oxygen"
7. Bioenergetics#Overview "energy sources, mostly sunlight and O₂"
8. Bioluminescence#Chemical mechanism "molecular oxygen, which provides chemical energy"
9. Cambrian explosion#Increase in oxygen levels "which need O₂ for its chemical energy"
10. Cellular respiration: lede "the most common oxidizing agent providing most of the chemical energy is molecular oxygen"
11. Chemical energy: lede "Some examples of storage media of chemical energy include [...] oxygen gas, which is of relatively high energy"
12. Chemical thermodynamics#Chemical energy "the energy (mostly of O₂)"
13. Chemosynthesis#Hydrogen sulfide chemosynthesis process "oxygen or nitrate as an energy source"
14. Chemotroph#Chemoheterotroph "obtaining most of their energy from O₂"
15. Citric acid cycle#Major metabolic pathways converging on the citric acid cycle "with the energy of O₂"
16. Electron acceptor#Examples "to a high-energy electron acceptor"
17. Electron transport chain#Mitochondrial redox carriers "releases the energy of oxygen"
18. Energy content of biofuel#Energy and CO2 output of common biofuels "mostly the energy of the O₂ consumed"
19. Energy density#In energy storage and fuels "the oxygen that provides most of the energy released in combustion"
20. Energy development#Fossil fuels "solar energy stored in O₂"
21. Energy flow (ecology)#Secondary production "Most energy is stored in plants and oxygen"
22. Exothermic reaction#Examples "most of the energy released was stored in O₂"
23. Fermentation#Biochemical overview "It releases the chemical energy of O₂"
24. Geological history of oxygen "O₂, a high-energy molecule"
25. Great Oxidation Event#Consequences of oxygenation "oxygen is a high-energy molecule"
26. Heterotroph#Ecology "the energy of O₂"
27. History of life#Environmental and evolutionary impact of microbial mats "due to its [oxygen's] chemical energy"
28. Hydrogen oxidizing bacteria
    "oxygen as final electron acceptor and source of energy"
29. Hypoxia (environmental)#Aquatic hypoxia "rely on oxygen for its chemical energy"
30. Hypoxia in fish: lede "the chemical energy of O₂"
31. Indirect calorimetry#History "the chemical energy of oxygen and nutrients"
32. Light-dependent reactions: lede "oxygen as a high-energy waste product"
33. Lithotroph#Overview of the metabolic process "unlock the chemical energy of O₂"
34. Luciferin#Types "molecular oxygen, which provides the needed energy"
35. Metabolism#Energy from inorganic compounds "high-energy electron acceptors such as oxygen"
36. Methanotroph: lede "unlock the energy of oxygen"
37. Microbial fuel cell: lede "high-energy oxidized compounds such as oxygen"
38. Microbial metabolism#Hydrogen oxidation "unlock the chemical energy of O₂"
39. Microbial oxidation of sulfur#Ecology "energy-rich electron acceptors"
40. Muscle contraction#Eccentric contraction "chemical energy (originally of oxygen, unlocked by fat or glucose"
41. Nitrobacter#Metabolism and Growth "O₂ as a source of energy"
42. Ocean deoxygenation#Overview "oxygen for its chemical energy"
43. Oxidative phosphorylation: lede "more energy (provided by oxygen)"
44. Oxygen: lede "Dioxygen provides most of the chemical energy released in combustion"
45. Photosystem#Reaction centers "creating high-energy oxygen as a byproduct"
46. Redox#Rates, mechanisms, and energies "use oxygen as electron acceptor and the main source of energy"
47. Primary nutritional groups#Primary sources of reducing equivalents "Both use oxygen in respiration as electron acceptor and the main source of energy"
48. Wet sulfuric acid process#The process fixed June 9 "The energy released by the above-mentioned reactions is mostly derived from O₂"
49. Oxygen saturation#In medicine fixed June 9 "oxygen, their source of chemical energy"
50. Animal#Ecology fixed June 9 "unlock the chemical energy of molecular oxygen"
51. Dioxygen in biological reactions: lede fixed June 9 fixed further June 10 "the chemical energy of oxygen" "high-energy O₂"
52. Fuel#Chemical fixed June 9 "Most of the chemical energy released in combustion was not stored in the chemical bonds of the fuel, but in the weak double bond of molecular oxygen"
53. Aerobic organism#Glucose fixed June 9 "the chemical energy stored in the relative weak double bond of oxygen"
54. Nicotinamide adenine dinucleotide#Role in redox metabolism fixed June 9 "the energy stored in the relatively weak double bond of oxygen"
55. Dead zone (ecology)#Effects fixed June 9 "switch their energy source from oxygen"
56. Fatty acid metabolism: lede fixed June 9 "unlock the energy of more O₂"

Is it okay to fix the remaining 47, as well?

Thanks, and sorry for the long message (feel free to delete it if it overwhelms your talk page).

IpseCustos (talk) 13:39, 12 June 2022 (UTC)[reply]

Like most Wikipedia editors, I do seriously consider other editors’ opinions and viewpoints, and often it is not appropriate to just revert changes another editor has made, for instance because the relevance of the disputed statement is debatable. Some of the nine articles you mentioned fall in this category. We can take the lede of photosynthesis as a specific example. The statement about the energy of oxygen fit into the context of the sentence that had been there before my edit and the statement is true scientifically, based on textbook principles of weak bonds and chemical energy, but it may not be essential. A more targeted edit (e.g. just removing “three times”) would have seemed like a better approach, but the deletion did not leave an apparent conceptual gap.

So in some cases, the flagged statement might be considered dispensable. The sentence in “Animal” may be an example. But elsewhere ‘fixing’ could mean making edits other than just wholesale deletions. In some cases it may be possible to refer to “the chemical energy of food molecules and oxygen” together (textbook principles do show clearly that chemical energy is stored in the weak bonds of the reactants of a combustion or aerobic-respiration reaction). Or maybe something like “due to its weak double bond, oxygen contributes chemical energy”? If you have phrasing suggestions that somehow include oxygen as an energetically important reactant, for instance in aerobic respiration of glucose where oxygen obviously contributes the energy for at least 22 of the 30 ATP formed, and are consistent with your worldview, please let me know.

If you give me four days, I will look through the statements on your list and try to propose revised phrasing that might be agreeable to you. Klaus Schmidt-Rohr (talk) 01:54, 13 June 2022 (UTC)[reply]

the chemical energy of food molecules and oxygen together

That is a good suggestion. I have no objection to that turn of phrase.

due to its weak double bond, oxygen contributes chemical energy

No. That is as bad as ever.

Unfortunately, what you have done so far appears to be to add new references mid-way through your existing statements and claim they support your synthesis of new statements. That's not the right way to go about this, and I propose we seek dispute resolution at this point. IpseCustos (talk) 04:06, 13 June 2022 (UTC)[reply]

I really think it would be better if you stopped and discussed which wordings are acceptable (or used the wording above) rather than replacing one unacceptable version by another.

If you prefer discussing this in a different central venue rather than in Talk:Oxygen, please let me know, but I'm not going to open 57 individual discussions repeating the same arguments.

Please remember discussion to establish consensus is the priority, not editing the articles as quickly as possible. IpseCustos (talk) 09:19, 13 June 2022 (UTC)[reply]

Since there is now an RfC open about this specific question, I believe it would be more productive for you to participate in that discussion than to continue editing a large number of articles. I will also refrain from editing the articles as long as productive discussion is taking place.

Please be aware that even if we agree on factually accurate wording, it may still be best to remove the claim because it is not helpful to the article, too long, or improperly sourced. IpseCustos (talk) 04:29, 13 June 2022 (UTC)[reply]

Oxygen has an RFC for possible consensus. A discussion is taking place. If you would like to participate in the discussion, you are invited to add your comments on the discussion page. Thank you. IpseCustos (talk) 05:19, 13 June 2022 (UTC)[reply]

• Please give a link. Xxanthippe (talk) 04:24, 13 June 2022 (UTC).[reply]

I tried to fix the rfc notice template invocation to include a link. Please let me know whether that worked IpseCustos (talk) 04:33, 13 June 2022 (UTC)[reply]

There is currently a discussion at Wikipedia:Conflict of interest/Noticeboard regarding a possible conflict of interest incident with which you may be involved. Thank you. IpseCustos (talk) 19:50, 13 June 2022 (UTC)[reply]

As you did here.

I know it's frustrating, but discussion is the only way (well, the only way either one of us can possibly want) to get out of this mess. Once you have arrived at a suggestion you consider to be good, I'll either agree to it or you are free to start an RfC to convince the community at large that it should be done that way.

Given the circumstances, this absolutely needs to happen on talk pages, not in the live article. Please remember the D in

IpseCustos (talk) 13:26, 15 June 2022 (UTC)[reply]

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