Zircon

Source: Wikipedia, the free encyclopedia.
This article is about the mineral and gemstone. For other uses, see Zircon (disambiguation).

Zircon
radioactive,
May form pleochroic halos,
Relief: high
References[2][3][4][5][6]

Zircon (

tetragonal crystal system
. The natural color of zircon varies between colorless, yellow-golden, red, brown, blue, and green.

The name derives from the

hyacinthus, whose name is of Ancient Greek
origin.

Properties

μm

Zircon is common in the

accessory mineral in igneous rocks (as primary crystallization products), in metamorphic rocks and as detrital grains in sedimentary rocks.[2] Large zircon crystals are rare. Their average size in granite rocks is about 0.1–0.3 mm (0.0039–0.0118 in), but they can also grow to sizes of several cm, especially in mafic pegmatites and carbonatites.[2] Zircon is fairly hard (with a Mohs hardness of 7.5) and chemically stable, and so is highly resistant to weathering. It also is resistant to heat, so that detrital zircon grains are sometimes preserved in igneous rocks formed from melted sediments.[13] Its resistance to weathering, together with its relatively high specific gravity (4.68), make it an important component of the heavy mineral fraction of sandstones.[5]

Because of their

metamictization. Connected to internal radiation damage, these processes partially disrupt the crystal structure and partly explain the highly variable properties of zircon. As zircon becomes more and more modified by internal radiation damage, the density decreases, the crystal structure is compromised, and the color changes.[15]

Zircon occurs in many colors, including reddish brown, yellow, green, blue, gray, and colorless.

color centers. Color in this red or pink series is annealed in geological conditions above temperatures of around 400 °C (752 °F).[17]

Structurally, zircon consists of parallel chains of alternating silica tetrahedra (silicon ions in fourfold coordination with oxygen ions) and zirconium ions, with the large zirconium ions in eightfold coordination with oxygen ions.[18]

Applications

Sand-sized grains of zircon

Zircon is mainly consumed as an opacifier, and has been known to be used in the decorative ceramics industry.[19] It is also the principal precursor not only to metallic zirconium, although this application is small, but also to all compounds of zirconium including zirconium dioxide (ZrO2), an important refractory oxide with a melting point of 2,717 °C (4,923 °F).[20]

Other applications include use in refractories and foundry casting and a growing array of specialty applications as

zirconia and zirconium chemicals, including in nuclear fuel rods, catalytic fuel converters and in water and air purification systems.[21]

Zircon is one of the key minerals used by geologists for geochronology.[22]

Zircon is a part of the ZTR index to classify highly-weathered sediments.[23]

Gemstone

A pale blue zircon gemstone weighing 3.36 carats

Transparent zircon is a well-known form of semi-precious

Mohs hardness is between that of quartz and topaz, at 7.5 on the 10 point scale, though below that of the similar manmade stone cubic zirconia (8-8.5). Zircons may sometimes lose their inherent color after long exposure to bright sunlight, which is unusual in a gemstone. It is immune to acid attack except by sulfuric acid and then only when ground into a fine powder.[25]

Most gem-grade zircons show a high degree of birefringence which, on stones cut with a table and pavilion cuts (i.e., nearly all cut stones), can be seen as the apparent doubling-up of the latter when viewed through the former, and this characteristic can be used to distinguish them from diamonds and cubic zirconias (CZ) as well as soda-lime glass, none of which show this characteristic. However, some zircons from Sri Lanka display only weak or no birefringence at all, and some other Sri Lanka stones may show clear birefringence in one place and little or none in another part of the same cut stone.[26] Other gemstones also display birefringence, so while the presence of this characteristic may help distinguish a given zircon from a diamond or a CZ, it will not help distinguish it from, for example, a topaz gemstone. The high specific gravity of zircon, however, can usually separate it from any other gem and is simple to test.

Also, birefringence depends on the cut of the stone in relation to its optical axis. If a zircon is cut with this axis perpendicular to its table, birefringence may be reduced to undetectable levels unless viewed with a jeweler's loupe or other magnifying optics. The highest grade zircons are cut to minimize birefringence.[27]

The value of a zircon gem depends largely on its color, clarity, and size. Prior to World War II, blue zircons (the most valuable color) were available from many gemstone suppliers in sizes between 15 and 25 carats; since then, stones even as large as 10 carats have become very scarce, especially in the most desirable color varieties.[27]

Synthetic zircons have been created in laboratories.[28] They are occasionally used in jewellery such as earrings. Zircons are sometimes imitated by spinel and synthetic sapphire, but are not difficult to distinguish from them with simple tools.

Occurrence

World production trend of zirconium mineral concentrates

Zircon is a common accessory to trace mineral constituent of all kinds of igneous rocks, but particularly granite and felsic igneous rocks. Due to its hardness, durability and chemical inertness, zircon persists in sedimentary deposits and is a common constituent of most sands.[29][30] Zircon can occasionally be found as a trace mineral in ultrapotassic igneous rocks such as kimberlites, carbonatites, and lamprophyre, owing to the unusual magma genesis of these rocks.[citation needed]

Zircon forms economic concentrations within

Dubbo, New South Wales Australia[31] in association with the zirconium-hafnium minerals eudialyte
and armstrongite.

Australia leads the world in zircon mining, producing 37% of the world total and accounting for 40% of world EDR (

economic demonstrated resources) for the mineral.[32] South Africa is Africa's main producer, with 30% of world production, second after Australia.[33]

Radiometric dating

SEM-CL image of Zircon grain showing zonations and poly-cycles (core-rim structure)

Zircon has played an important role during the evolution of

uranium-lead (U-Pb), fission-track, and U+Th/He techniques. Imaging the cathodoluminescence emission from fast electrons can be used as a prescreening tool for high-resolution secondary-ion-mass spectrometry (SIMS) to image the zonation pattern and identify regions of interest for isotope analysis. This is done using an integrated cathodoluminescence and scanning electron microscope.[34] Zircons in sedimentary rock can identify the sediment source.[35]

Zircons from

oldest minerals so far dated on Earth. In addition, the oxygen isotopic compositions of some of these zircons have been interpreted to indicate that more than 4.3 billion years ago there was already liquid water on the surface of the Earth.[36][37][38][39] This interpretation is supported by additional trace element data,[40][41] but is also the subject of debate.[42][43][44] In 2015, "remains of biotic life" were found in 4.1-billion-year-old rocks in the Jack Hills of Western Australia.[45][46] According to one of the researchers, "If life arose relatively quickly on Earth ... then it could be common in the universe."[45]

Similar minerals

Hafnon (HfSiO4), xenotime (YPO4), béhierite, schiavinatoite ((Ta,Nb)BO4), thorite (ThSiO4), and coffinite (USiO4)[14] all share the same crystal structure (IVX IVY O4, IIIX VY O4 in the case of xenotime) as zircon.

Gallery

  • Crystal structure of zircon
    Crystal structure of zircon
  • Unit cell of zircon
    Unit cell of zircon
  • Scanning electron microscope image of zircon
    Scanning electron microscope image of zircon
  • Unusual olive-green zircon
    Unusual olive-green zircon
  • Cluster of three compound crystals of zircon
    Cluster of three compound crystals of zircon

See also

References

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  2. ^
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  3. ^ "Zircon: Mineral information, data and localities". Mindat.org. Retrieved October 19, 2021.
  4. ^ "Zircon Mineral Data". Webmineral. Retrieved October 19, 2021.
  5. ^
    ISBN 0-471-80580-7
    .
  6. S2CID 67779734
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  7. CollinsDictionary.com. HarperCollins
    . Retrieved April 29, 2018.
  8. ^ "zircon". The American Heritage Dictionary of the English Language (5th ed.). HarperCollins.
  9. ^ "zircon". Merriam-Webster.com Dictionary. Retrieved April 29, 2018.
  10. ISBN 978-0-19-508083-4
    .
  11. ^ Harper, Douglas. "zircon". Online Etymology Dictionary.
  12. ^ "Hyacinth (gem)". Encyclopædia Britannica. Encyclopædia Britannica Inc. Retrieved October 7, 2016.
  13. ISBN 9780195106916
    .
  14. ^
    S2CID 210256739
    – via Elsevier Science Direct.
  15. ^ Nesse 2000, pp. 93–94.
  16. ^ "Zircon gemstone information". www.gemdat.org. Retrieved April 29, 2018.
  17. doi:10.1016/S0040-1951(02)00054-9
    .
  18. ^ Nesse 2000, p. 313.
  19. ISBN 978-3527306732
    .
  20. S2CID 120967147
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  21. ^ "Products". Mineral Commodities Ltd. Archived from the original on October 7, 2016. Retrieved August 8, 2016.
  22. ^ Nesse 2000, p. 314.
  23. ISBN 0136427103
    .
  24. ^ Brauns, Reinhard (1912). The Mineral Kingdom (Volume 1). Translated by Leonard James Spencer. J.F. Schreiber. p. 217.
  25. ^ Oliver Cummings Farrington (1903). Gems and Gem Minerals. A.W. Mumford. p. 109.
  26. ^ L.J. Spencer (1905). Report of the Seventy-Fourth Meeting of the British Association for the Advancement of Science. John Murray. pp. 562–563.
  27. ^ a b "Physical & Optical Properties of Zircon". Colored Gemstones Guide. Retrieved October 19, 2021.
  28. S2CID 102001496
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  29. ^ Nesse 2000, pp. 313–314.
  30. ^ Hurlbut & Klein 1985, p. 454.
  31. ^ Staff (June 2007). "Dubbo Zirconia Project Fact Sheet June 2014" (PDF). Alkane Resources Limited. Archived from the original (PDF) on February 28, 2008. Retrieved September 10, 2007.
  32. ^ "The Mineral Sands Industry Factbook" (PDF). Archived from the original (PDF) on August 18, 2016.
  33. ^ "Heavy Minerals Mining in Africa – Titanium And Zirconium". Archived from the original on May 28, 2008. Retrieved August 8, 2016.
  34. ^ "Zircons – Application Note". DELMIC. Retrieved February 10, 2017.
  35. hdl:10023/3575
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  36. ^
    S2CID 4319774
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  37. S2CID 2819082
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  38. doi:10.1130/0091-7613(2002)030<0351:ACEE>2.0.CO;2
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  40. doi:10.1016/j.epsl.2008.05.032
    .
  41. ^ "Ancient mineral shows early Earth climate tough on continents". Physorg.com. June 13, 2008.
  42. doi:10.1016/j.epsl.2006.01.054
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  43. doi:10.1016/j.epsl.2005.04.028
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  44. doi:10.1038/ngeo2075
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  45. ^ a b Borenstein, Seth (October 19, 2015). "Hints of life on what was thought to be desolate early Earth". Excite. Yonkers, NY: Mindspark Interactive Network. Associated Press. Archived from the original on October 23, 2015. Retrieved October 8, 2018.
  46. PMID 26483481
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Further reading

External links

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