Wine chemistry
Wine is a complex mixture of chemical compounds in a hydro-alcoholic solution with a pH around 4. The chemistry of wine and its resultant quality depend on achieving a balance between three aspects of the berries used to make the wine: their sugar content, acidity and the presence of secondary compounds. Vines store sugar in grapes through
Environmental factors such as soil, rainfall and fog affect flavor in ways that can be described collectively as "character" or the French term “
Types of natural molecules present in wine
- Acids in wine[2]
- Phenolic compounds in wine[2]
- Proteins in wine
- Sugars in wine
- Yeast assimilable nitrogen
- Minerals
- Dissolved gas(CO2)
- α-terpineol[5]
- Glutathione (reduced and oxidized)[6][7]
Volatiles
- Methoxypyrazines
- Esters:[2] Ethyl acetate is the most common ester in wine, being the product of the most common volatile organic acid — acetic acid, and the ethyl alcohol generated during the fermentation.
- glycosidases.[11]
Other molecules found in wine
Preservatives
- Ascorbic acidis used during wine making
- Sulfur dioxide (SO2), a preservative often added to wine
Fining agents
Gum arabic has been used in the past as fining agent.[12]
List of additives permitted for use in the production of wine under European Union law:
Type or purpose of addition | Permitted additives |
---|---|
Acidification | tartaric acid |
Clarification | calcium alginate potassium alginate |
Decolourants | polyvinyl-polypyrrolidone (PVPP) |
Deacidification | lactic bacteria neutral potassium tartrate |
Deodorant | copper sulfate |
Elaboration | oak chips metatartaric acid |
Enrichment | concentrated grape must rectified concentrated grape must |
Enzymes | betaglucanase pectolytics |
Fermentation | fresh lees ammonium bisulphite |
Sequestrants | fresh lees potassium ferrocyanide |
Stabilisation | calcium tartrate potassium bitartrate |
Others
- Melatonin[13]
- Wine lactone
- Anthocyanone A, a degradation product of malvidin under acidic conditions
Wine faults
A wine fault or defect is an unpleasant characteristic of a wine often resulting from poor
The yeast
Coumaric acid is sometimes added to microbiological media, enabling the positive identification of Brettanomyces by smell.
Fusel alcohols are a mixture of several alcohols (chiefly amyl alcohol) produced as a by-product of alcoholic fermentation.
See also
- Alcohol (drug)
- Beer chemistry
- Food chemistry
- Premature oxidation
- Congener (alcohol), such as tryptophol
Notes
- ^ . Retrieved 11 July 2022.
- ^ PMID 23464569. Retrieved 11 July 2022.
- ^ Terpenes in the aroma of grapes and wines: A review. J. Marais, S. Afr. J. Enol. Vitic., 1983, volume 4, number 2, pages 49-58 (article)
- ^ Inhibition of the decline of linalool and α-terpineol in muscat wines by glutathione and N-acetyl-cysteine. Papadopoulou D. and Roussis I. G., Italian journal of food science, 2001, vol. 13, no4, pages 413-419, INIST 13441184
- ISBN 0-8412-3729-8.
- S2CID 101007887.
- PMID 19817422.
- .
- ^ Vivas N, Vivas de Gaulejac N, Nonier M.F and Nedjma M (2001). "Incidence de la gomme arabique sur l'astringence des vins et leurs stabilites colloidales" [Effect of gum arabic on wine astringency and colloidal stability]. Progres Agricole et Viticole (in French). 118 (8): 175–176.
{{cite journal}}
: CS1 maint: multiple names: authors list (link) - S2CID 8034935.
- ISBN 0-932664-69-5
- ^ Brettanomyces Monitoring by Analysis of 4-ethylphenol and 4-ethylguaiacol Archived 2008-02-19 at the Wayback Machine at etslabs.com
References
- Comprehensive Natural Products II — Chemistry and Biology, chapter 3.26 – Chemistry of Wine, volume 3, pages 1119–1172. Véronique Cheynier, Rémi Schneider, Jean-Michel Salmon and Hélène Fulcrand,
External links
- Wine Chemistry and Biochemistry, by M. Victoria Moreno-Arribas, Carmen Polo and María Carmen Polo, on Google books
- Mass Spectrometry in Grape and Wine Chemistry, by Riccardo Flamini and Pietro Traldi, on Google books
- Antoine de Saporta La Chimie des vins : les vins naturels, les vins manipulés et falsifiés (1889). Google Books