Manganese(III) fluoride
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| Names | |
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| IUPAC name
Manganese(III) fluoride
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| Other names
Manganese trifluoride, manganic fluoride
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| Identifiers | |
3D model (
JSmol ) |
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| ChemSpider | |
ECHA InfoCard
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100.029.096 |
| EC Number |
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PubChem CID
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RTECS number
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| UNII | |
CompTox Dashboard (EPA)
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SMILES
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| Properties | |
| MnF3 | |
| Molar mass | 111.938 g/mol |
| Appearance | purple-pink powder hygroscopic
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| Density | 3.54 g/cm3 |
| Melting point | > 600 °C (1,112 °F; 873 K) (decomposes) |
| hydrolysis | |
| +10,500·10−6 cm3/mol | |
| Structure | |
Monoclinic, mS48
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| C2/c, No. 15 | |
| distorted octahedral | |
| Hazards | |
| Occupational safety and health (OHS/OSH): | |
Main hazards
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toxic fumes |
| GHS labelling:[1] | |
 
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| Danger | |
| H272, H301, H312, H315, H319, H332, H335 | |
| P220, P261, P280, P301+P310, P305+P351+P338 | |
| Related compounds | |
Other anions
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manganese(III) oxide, manganese(III) acetate |
Other cations
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chromium(III) fluoride, iron(III) fluoride. cobalt(III) fluoride |
Related compounds
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manganese(II) fluoride, manganese(IV) fluoride |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Manganese(III) fluoride (also known as Manganese trifluoride) is the
Synthesis, structure and reactions
MnF3 can be prepared by treating a solution of MnF2 in hydrogen fluoride with fluorine:[3]
- MnF2 + 0.5 F2 → MnF3
It can also be prepared by the reaction of elemental fluorine with a manganese(II) halide at ~250 °C.[4]
Structure
Like
The hydrate MnF3.3H2O is obtained by crystallisation of MnF3 from hydrofluoric acid. The hydrate exists as two polymorphs, with space groups P21/c and P21/a. Each consists of the salt [Mn(H2O)4F2]+[Mn(H2O)2F4]− ).[8]
Reactions
MnF3 is Lewis acidic and forms a variety of derivatives. One example is K2MnF3(SO4).[9] MnF3 reacts with sodium fluoride to give the octahedral hexafluoride:[4]
- 3NaF + MnF3 → Na3MnF6
Related reactions salts of the anions MnF52− or MnF4−. These anions adopt chain and layer structures respectively, with bridging fluoride. Manganese remains 6 coordinate, octahedral, and trivalent in all of these materials.[4]
Manganese(III) fluoride fluorinates organic compounds including aromatic hydrocarbons,[10] cyclobutenes,[11] and fullerenes.[12]
On heating, MnF3 decomposes to manganese(II) fluoride.[13][14]
MnF3 is a source of MnCl3 complexes by reaction with bismuth trichloride.[15]
See also
- CoF3, another fluorinating agent based on a transition metal in an oxidising +3 state.
References
- ^ GHS: sigma-aldrich 339296 [dead link]
- ISBN 0-471-93623-5.
- .
- ^ a b c Inorganic chemistry, Catherine E. Housecroft, A.G. Sharpe, pp.711-712, section Manganese (III) , googlebooks link
- ISBN 0-19-855370-6.
- S2CID 4208409.
- .
- .
- )
- ^ Fluorination of p-chlorobenzotrifluoride by manganese trifluoride Archived 2011-08-23 at the Wayback Machine A. Kachanov, V. Kornilov, V.Belogay , Fluorine Notes :Vol. 1 (1) November–December 1998 , via notes.fluorine1.ru
- .
- S2CID 94250136.
- ^ Chisholm, Hugh, ed. (1911). . Encyclopædia Britannica. Vol. 17 (11th ed.). Cambridge University Press. p. 570.
- ^ In situ time-resolved X-ray diffraction study of manganese trifluoride thermal decomposition , J.V. Raua, V. Rossi Albertinib, N.S. Chilingarova, S. Colonnab, U. Anselmi Tamburini, Journal of Fluorine Chemistry 4506 (2001) 1–4 , online version
- .
Further reading
- Novel syntheses of some binary fluorides: the role of anhydrous hydrogen fluoride Acta Chim. Slov. 1999, 46(2), pp. 229–238, Zoran Mazej, Karel Lutar and Boris Žemva
- Knudsen Cell mass spectrometry study of Manganese Trifluoride vaporisation, High temperature corrosion and materials chemistry IV: proceedings of the International Symposium, pp. 521–525, google books