Kupferschiefer

Coordinates: 51°00′N 10°00′E / 51.0°N 10.0°E / 51.0; 10.0
Source: Wikipedia, the free encyclopedia.
Kupferschiefer
Ma
Approximate paleocoordinates
15°18′N 22°36′E / 15.3°N 22.6°E / 15.3; 22.6
RegionNorth-central Europe
Country Denmark
 Germany
 Lithuania
 Netherlands
 Poland
 Russia (Kaliningrad)
ExtentSouthern Permian Basin
Type section
Named for"Kupfer" = copper, "Schiefer" = shale

Extent of the Zechstein sea, where the Kupferschiefer was deposited

The Kupferschiefer (

Marl Slate
.

Despite its distinctive nature, the Kupferschiefer is not ranked as a formation but is officially declared a sub-unit of the

Rotliegend Group. The unit has been dated to 257.3 ± 1.6 Ma, placing it in the Wuchiapingian stage of the Late Permian
.

The Kupferschiefer comprises

bituminous marls, mudstones and limestones deposited mostly in an open marine setting, with the borders of its extension deposited in a shallow marine environment. At time of deposition, the area what is now northern Europe was covered by an enclosed sea; the Zechstein sea, characterized by anoxic
conditions.

The Kupferschiefer is renowned for hosting one of the most important copper deposits in the world, which were mined at least since 1199 AD. Other mineral resources found in the unit include zinc, vanadium, lead and silver.

The Kupferschiefer is also an important

Glaurung schneideri
.

Description

Stratigraphic succession including the Kupferschiefer in the Kamsdorf mine near Saalfeld, Thuringia

The Kupferschiefer is a regional stratigraphic unit stretching across an area of 600,000 square kilometres (230,000 sq mi) in the

Werra Formation, the lowest formation of the Zechstein Group. The Kupferschiefer is overlain by the Zechstein Limestone sub-unit of the Werra Formation.[3]

The unit has been dated to 257.3 ± 1.6 Ma, placing it in the

The Kupferschiefer contains up to 30% organic matter,

TOC, while the marginal facies present values up to 7% TOC and swell facies are much poorer in organic matter with values below 1%.[6]

Basin history

Paleogeography of the Late Permian (260 Ma), with Archosauromorpha fossil locations indicated. Note the Zechstein sea is not shown as an inland sea.

Depositional environment

The Kupferschiefer was deposited in a

Pangea.[10] The basin possibly had periodic connections to the Paleo-Tethys Ocean.[11] Sedimentation rates during Kupferschiefer deposition were low, estimated at 5 millimetres (0.20 in) per thousand years.[12]

The climate of the Late Permian was extremely variable, with polar icecaps present near the south pole and hot and arid conditions prevailing in the tropic and paleotemperate regions of the northern and southern hemispheres.[13] The Zechstein sea in the Late Permian was located at paleolatitudes around 15 to 16 degrees north.[14] Large areas of Pangea were covered by deserts and arid conditions also prevailed near the Zechstein sea of the time.[15]

Permian-Triassic extinction event, the biggest extinction event in geologic history, is thought to have been caused mostly by large volcanic provinces of the Siberian Traps
.

Mining

Miners extracting copper in Mansfeld

Prehistoric finds of slag and bronze from smelting sites on top of or immediately adjacent to outcropping Kupferschiefer ores at

Mohrungen, and Bottendorf in Central Germany evidence Early to Middle Bronze Age mining of the Kupferschiefer ores. The medieval mining history of the Kupferschiefer ores is documented in written sources since at least 1199 A.D. from the Mansfeld district in Central Germany. The Counts of Mansfeld developed several copper mines, smelters, and a mint at the town of Eisleben, where copper and silver coins were minted from the metals of the Kupferschiefer ores.[17]

Germany

Kupferschiefer from Mansfeld with a vein of bornite

The main mining district of the Kupferschiefer in Germany was Mansfeld Land, which operated from at least 1199 AD,[18] and has provided 2,009,800 tonnes of copper and 11,111 tonnes of silver.[19] The Mansfeld mining district was exhausted in 1990.[18][20]

Eisleben in the Mansfeld Land is the type locality of two minerals;[21] the nickel-arsenate maucherite,[22] and betekhtinite, a copper-lead-iron sulfide.[23] The latter mineral has a co-type locality in the Ernst-Thälmann shaft, that operated from 1906 to 1962 and produced 260,000 tons of copper; about 10% of the overall production from the Mansfeld area.[24]

Many minerals have been found in the Sangerhausen district of Saxony-Anhalt,[1][2] which produced 619,200 tonnes of copper and 3,102 tonnes of silver as of 2012, with 860,000; respectively 4,650 tonnes as remaining proven reserves.[19]

In the Spremberg-Graustein-Schleife mining area, stretching across the Brandenburg district Spree-Neiße and Görlitz in Saxony, the Kupferschiefer is estimated to contain 130 million tonnes of ore, of which 1,486,000 tonnes of copper,[19] with a copper content of 1.47%. The mining district is about 15 by 3 kilometres (9.3 mi × 1.9 mi) and the copper-bearing beds lie at a depth between 980 and 1,580 metres (3,220 and 5,180 ft).[25]

The Kupferschiefer contains up to 3% copper, 10

ppm of platina and up to 3000 ppm gold.[9]

The "Im Lochborn" mine, mining from the Kupferschiefer,

Hessen is the type locality of the mineral bieberite,[27] a cobalt sulfate named after the location.[28] The mineral rösslerite, a magnesium arsenate, also has the mine as type locality.[29]

Poland

Two main Kupferschiefer mining areas in Poland are the North-Sudetic trough, with 212,894 tonnes of copper and 756.7 tonnes of silver mined as of 2012 and an estimated remaining reserves of 1,460,000 tonnes of copper, and the Fore-Sudetic monocline, with more than 20,000,000 tonnes of copper and more than 14,085 tonnes of silver mined since 1949. Main mining districts in Poland are the Głogów industrial district, the Lubichów and Grodziec fields, and the Konrad, Lena, Lubin, Nowy Kosciół, Polkowice, Rudna and Sieroszowice mines.

quicksilver amalgame, eugenite.[31] The Polkowice mine is the type locality for two rare lead and germanium-bearing sulfide minerals;[32] polkovicite, named after the mine,[33] and morozeviczite.[34]

Paleontological significance

The Kupferschiefer has provided unique fossils of an early reptile;

Pareiasauria
, fish, an insect and fossil flora.

As of 2014, at least 28 Protorosaurus speneri specimens are known from the Kupferschiefer in the states of Thuringia and Hesse in central Germany.[35] The type locality for the species is Glücksbrunn, Heidelberg, near Schweina in Thuringia.[14][36] The type locality for Parasaurus geinitzi is Walkenried in Lower Saxony.[37][38] Fossils of both species were found containing quartz pebbles in their guts.[39][40]

Fossil fish of the species Palaeoniscum freieslebeni [de] are abundantly found in different locations in the Kupferschiefer. The species epithet of the "Eisleben Shale Fish", or "Kupferschiefer Herring" refers to Johann Karl Freiesleben, the Berghauptmann [de] (mining inspection director) of Saxony.[41] Other fish found in the Kupferschiefer include Coelacanthus granulatus, Hopleacanthus richelsdorfensis, Acentrophorus glaphyurus, Menaspis armata, Muensterichthys buergeri, Platysomus striatus, and two species of Janassa and Wodnika.

Fossil content

Group Fossils Image Notes
Archosauromorpha Protorosaurus speneri
[35]
Weigeltisauridae
Weigeltisaurus jaekeli
[42]
Glaurung schneideri
[43]
Pareiasauria
Parasaurus geinitzi [37]
Fish Palaeoniscum freieslebeni
[9]
Coelacanthus granulatus
[44]
Hopleacanthus richelsdorfensis
[45]
Janassa bituminosa, J. korni
[46][47][48]
Menaspis armata [49]
Wodnika althausi, W. striatula
[44]
Acentrophorus glaphyurus [50]
Dorypterus hoffmanni [44]
Eurysomus macrurus [44]
Globulodus elegans [44]
Muensterichthys buergeri [51]
Platysomus striatus [52]
Pygopterus humboldti [44]
Reticulolepis exsculpta [44]
Acrolepis sp. [53]
Ctenacanthus richelsdorfensis [4][54]
Insects Protereisma rossenrayensis [55][56]
Nautiloids Peripetoceras freieslebeni [52]
Pteronautilus seebachianus [50]
Bivalves
Aviculopinna prisca [57]
Bakevellia sp. [50]
Macroflora Neocalamites mansfeldicus [4]
Sphenobaiera digitata
[4]
Baiera mansfeldensis [58]
Esterella gracilis [59]
Bhenania reichelti, Calipteris martinsi, Pseudovoltzia liebeana, Quadrocladus orobiformis, Q. solmsi, Sphenopteris kukukiana, Ullmannia bronni, U. frumentaria [4]
Pollen Crustaesporites globosus, Illenites cf. bentzi, I. cf. unicus, Jugasporites delasaucei delasaucei, J. delasaucei moersensis, Lueckisporites richteri, L. virkkiae, Nuskoisporites dulhuntyi, Pityosporites granulatus, P. schaubergeri, P. zapfei, Platysaccus papilionis [60][61]

Geologic maps

Zechstein in blue

  • Rhoen
    Rhoen
  • Thuringian Forest
    Thuringian Forest
  • Thuringian-Franconian mountains
    Thuringian-Franconian mountains
  • Eastern Brunswick
    Eastern Brunswick

See also

References

  1. ^ a b Copper slate deposits, Sangerhausen at Mindat.org
  2. ^ a b Bernard Koenen shafts I and II, Copper slate deposits, Sangerhausen at Mindat.org
  3. ^ a b c Paleo-ecosystems, p.4
  4. ^ a b c d e Bachmayer & Malzahn, 1983, p.101
  5. ^ Paleo-ecosystems, p.2
  6. ^ a b Paleo-ecosystems, p.22
  7. ^ Ezcurra et al., 2014b
  8. ^ Tsuji & Müller, 2008, p.1112
  9. ^ a b c (in German) Drama im Kupferschiefermeer
  10. ^ Paleo-ecosystems, p.7
  11. ^ Paleo-ecosystems, p.6
  12. ^ Schwarzer Philipp at Fossilworks.org
  13. ^ Paleo-ecosystems, p.9
  14. ^ a b Glücksbrunn/Heidelberg near Schweina at Fossilworks.org
  15. ^ Paleo-ecosystems, p.10
  16. ^ Paleo-ecosystems, p.11
  17. ^ Borg et al., 2012, p.457
  18. ^ a b Borg et al., 2012, p.455
  19. ^ a b c d Borg et al., 2012, p.458
  20. ^ Borg et al., 2012, p.475
  21. ^ Eisleben, Mansfeld at Mindat.org
  22. ^ Maucherite at Mindat.org
  23. ^ Betekhtinite at Mindat.org
  24. ^ Ernst-Thälmann shaft, Mansfeld at Mindat.org
  25. ^ (in German) KSL Kupferschiefer Lausitz GmbH
  26. ^ Borg et al., 2012, p.456
  27. ^ "Im Lochborn" mine, Bieber, Hessen at Mindat.org
  28. ^ Bieberite at Mindat.org
  29. ^ Rösslerite at Mindat.org
  30. ^ Sieroszowice mine at Mindat.org
  31. ^ Eugenite at Mindat.org
  32. ^ Polkowice mine at Mindat.org
  33. ^ Polkovicite at Mindat.org
  34. ^ Morozeviczite at Mindat.org
  35. ^ a b Ezcurra et al., 2014a, p.7
  36. ^ Ezcurra, 2016, p.22
  37. ^ a b Tsuji & Müller, 2008
  38. ^ Walkenried at Fossilworks.org
  39. ^ Munk & Kues, 1993, p.171
  40. ^ Munk & Kues, 1993, p.172
  41. ^ (in German) Palaeoniscum freieslebeni at Museum Schloss Bernburg
  42. ^ Weichelt, 1930
  43. ^ Bulanov & Sennikov, 2015, p.1357
  44. ^ a b c d e f g Richelsdorf (Althaus collection) at Fossilworks.org
  45. ^ Wolfsberg pit at Fossilworks.org
  46. ^ Mansfeld, Dresden collection at Fossilworks.org
  47. ^ Freieslebenschacht at Fossilworks.org
  48. ^ Brandt, 2009, p.16
  49. ^ Lonau at Fossilworks.org
  50. ^ a b c Hasbergen Excavation Planum II at Fossilworks.org
  51. ^ Bodental at Fossilworks.org
  52. ^ a b Hasbergen Excavation Planum I at Fossilworks.org
  53. ^ Hasbergen Excavation Planum III at Fossilworks.org
  54. ^ Richelsdorf Mountains at Fossilworks.org
  55. ^ Guthörl, 1965, p.229
  56. ^ Rossenray 2 Shaft, 415 m depth, Kamp-Lintfort at Fossilworks.org
  57. ^ Merzenberg, near Milbitz at Fossilworks.org
  58. ^ Bauer et al., 2013, p.546
  59. ^ Bauer et al., 2013, p.549
  60. ^ Grebe, 1957
  61. ^ Kupferschiefer 450 m floor Friedrich Heinrich Mine Kamp-Lintfort Germany at Fossilworks.org

Bibliography

Geology
Paleontology

External links