Thallium(I) fluoride

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Thallium(I) fluoride
Names
Preferred IUPAC name
Thallium(I) fluoride
Other names
Thallium monofluoride
Thallous fluoride
Identifiers
3D model (
JSmol
)
ChemSpider
ECHA InfoCard
100.029.231 Edit this at Wikidata
EC Number
  • 232-154-1
RTECS number
  • XG4900000
UNII
  • InChI=1S/FH.Tl/h1H;/q;+1/p-1 ☒N
    Key: CULOEOTWMUCRSJ-UHFFFAOYSA-M ☒N
  • F[Tl]
Properties
TlF
Molar mass 223.3817 g/mol
Appearance White crystals
Density 8.36 g cm−3
Melting point 327 °C (621 °F; 600 K)
Boiling point 655 °C (1,211 °F; 928 K) (decomposes)
78.6 g/100 mL (at 15 °C)[1]
Solubility slightly soluble in ethanol
−44.4·10−6 cm3/mol
Structure
Orthorhombic, oP8
Fmmm, No. 28
Hazards[2]
GHS labelling:
GHS06: ToxicGHS08: Health hazardGHS09: Environmental hazard
Danger
H300, H330, H373, H411
P260, P264, P270, P271, P273, P284, P301+P310, P304+P340, P310, P314, P320, P321, P330, P391, P403+P233, P405, P501
Related compounds
Other anions
Thallium(I) chloride

Thallium(I) bromide
Thallium(I) iodide

Other cations
Gallium(III) fluoride

Indium(III) fluoride

Thallium(III) fluoride

Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Thallium(I) fluoride is the

inert pair on Tl+.[5]

This salt is unusual among the thallium(I) halides in that it is very soluble in water.[6]

Reactions

Thallium(I) fluoride can be prepared by the reaction of thallium(I) carbonate with hydrofluoric acid.[3]

References

  1. ^ , retrieved 2008-06-17
  2. ^ "399833 Thallium(I) fluoride 99%". Sigma-Aldrich. Retrieved 2008-06-17.
  3. ^ a b Wiberg, Nils; Wiberg, Egon; Holleman, A. F. (2001), Inorganic Chemistry, Academic Press, p. 1037, , retrieved 2008-06-17
  4. ^ Meyer, Gerd; Naumann, Dieter; Wesemann, Lars (2006), Inorganic Chemistry in Focus III, Wiley-VCH, p. 21, , retrieved 2008-06-17
  5. .
  6. ^ Arora, M. G. (2003), P-block Elements, Anmol Publications, p. 35, , retrieved 2008-06-17