Sulfate fluoride
The sulfate fluorides are double salts that contain both
Fluoride sulfates were first discovered by Jean Charles de Marignac in 1859.[1][2]
Some elements such as cobalt or uranium can form complexes that contain fluoride and sulfate groups, and would be referred to as fluoro and sulfato metallates.
List
Minerals
name | formula | ratio | system | space group | unit cell Å | volume | density | optical | references |
---|---|---|---|---|---|---|---|---|---|
Chukhrovite-(Ca) | Ca4.5Al2(SO4)F13·12H2O | 1:13 | Isometric | Fd3 | a = 16.749 Z=8 | 4698.6 | 2.23 | isotropic n = 1.432 | [3] |
Chukhrovite-(Ce) | Ca3(Y,Ce)(AlF6)2(SO4)F · 10H2O | 1:13 | Isometric | Fd3 | [4] | ||||
Chukhrovite-(Y) | Ca3(Ce,Y)(AlF6)2(SO4)F · 10H2O | 1:13 | Isometric | Fd3 | [5] | ||||
Chukhrovite-(Nd) | Ca3(Nd,Y)Al2(SO4)F13·12H2O | 1:13 | Isometric | Fd3 | a = 16.759 Z=8 | 4,707.0 | 2.42 | isotropic nα = 1.443 | [6] |
Meniaylovite | Ca4[(SO4)(SiF6)(AlF6)]F · 12H2O | 1:13 | Isometric | Fd3 | a = 16.722 Z=8 | 4,675.89 | Isotropic n = 1.43 | ||
Pseudograndreefite | Pb6(SO4)F10 | 1:10 | Orthorhombic | F2 2 2 | a = 8.51 b = 19.57 c = 8.49 Z=4 | 1,413.93 | Biaxial (+) nα = 1.864 nβ = 1.865 nγ = 1.873
2V: measured: 30° , calculated: 40° Max birefringence: δ = 0.009 |
[7] | |
Creedite | Ca3SO4Al2F8(OH)2 · 2H2O | 1:8 | Monoclinic | B2/b | a = 13.936, b = 8.606, c = 9.985 β = 94.39° Z=4 | 1,194.02 | 2.713 | Biaxial (-) nα = 1.461 nβ = 1.478 nγ = 1.485
Max birefringence: δ = 0.024 |
[8] |
Thermessaite | K2AlF3(SO4) | 1:3 | Orthorhombic | Pbcn | a = 10.81 b = 8.336 c = 6.822 | 614.75 | 2.77 | ||
Grandreefite | Pb2(SO4)F2 | 1:2 | monoclinic | A2/a | a = 8.667 b = 4.4419 c = 14.242 β = 107.418 Z=4 | 523.15 | 7.15 | Biaxial (+) nα = 1.872 nβ = 1.873 nγ = 1.897
2V: Measured: 23° Max Birefringence: δ = 0.025 |
[9] |
Arangasite | Al2F(PO4)(SO4) · 9H2O | 1:1 | monoclinic | P2/a | a = 7.073 b = 9.634 c = 10.827 β = 100.40 Z = 2 | 725.7 | 2.01 | Biaxial (+) ?nα = 1.493(5) nγ = 1.485(5)
Max birefringence: δ = 0.008 |
[10][11] |
Khademite | Al(SO4)F · 5H2O | 1:1 | orthorhombic | a = 11.17 b = 13.05 c = 10.88 | 1,585.96 | 1.925 | Biaxial (-) nα = 1.440 nβ = 1.460 nγ = 1.487
2V: measured: 68° calculated: 84° Max birefringence δ = 0.047 colourless |
[12] | |
Kogarkoite | Na3(SO4)F | 1:1 | Monoclinic | ?P21 | a = 18.07 b = 6.94 c = 11.44 β = 107.72° Z=12 | 1,366.58 | 2.676 | Biaxial (+) nα = 1.439 nβ = 1.439 nγ = 1.442
Max Birefringence: δ = 0.003 |
[13] |
kononovite | NaMg(SO4)F | 1:1 | monoclinic | C2/c | a = 6.662 b = 8.584 c = 7.035 β = 114.06 Z=4 | 367.4 | 2.91 | biaxial (+), nα = 1.488 nβ = 1.491 nγ = 1.496 2Vmeas = 75°
Max birefringence: δ = 0.008 |
[14] |
Lannonite | Mg2Ca4Al4(SO4)8F8 · 24H2O | 8:8 | Tetragonal | I4/m | a = 6.860 c = 28.053 | 1,320.16 | 2.22 | Uniaxial (+) nω = 1.460 nε = 1.478
Max Birefringence:δ = 0.018 |
[15] |
Sulphohalite | Na6(SO4)2FCl | 2:1 | Isometric | Fm3m | Isotropic | [16] | |||
Uklonskovite | NaMgSO4F•2H2O | 1:1 | monoclinic | a = 7.2 Å, b = 7.21 Å, c = 5.73 β = 113.23° | 273.34 | Biaxial (+) nα = 1.476 nγ = 1.500
Max Birefringence δ = 0.024 |
[17] | ||
Vlodavetsite | AlCa2(SO4)2F2Cl · 4H2O | 2:2 | Tetragonal | I4/m | a = 6.870, c = 13.342 Z=2 | 629.70 | Uniaxial (+) nω = 1.509 nε = 1.526
Max birefringence: δ = 0.017 |
[18] | |
Schairerite | Na21(SO4)7ClF6 | 7:6 | trigonal | 3_2/m | a = 12.17 c = 19.29 | 2,474.25 | 2.67 | Uniaxial (+) nω = 1.440 nε = 1.445
Max birefringence: δ = 0.005 |
[19] |
Galeite | Na15(SO4)5F4Cl | 5:4 | Trigonal | a = 12.17 c = 13.94 | 1,788.03 | Uniaxial (+) nω = 1.447 nε = 1.449
Max Birefringence: δ = 0.002 |
[20] | ||
Fluorellestadite | Ca10(SiO4)3(SO4)3F2 | 3:2 | hexagonal | a = 9.53 c = 6.91 | 543.49 | 3.03 | Uniaxial (-) nω = 1.655 nε = 1.650
Max birefringence:δ = 0.005 |
[21] | |
Straßmannite | Al(UO2)(SO4)2F·16H2O | 2:1 | monoclinic | C2/c | a = 11.0187 b = 8.3284 c = 26.673 β = 97.426° | 2427.2 | 2.20 | pale yellowish green
Biaxial (-) nα = 1.477(2) nβ = 1.485(2) nγ = 1.489(2) 2V: measured: 70° calculated: 70.2° Max birefringence: δ = 0.012 |
[22] |
Svyazhinite | (Mg,Mn2+,Ca)(Al,Fe3+)(SO4)2F · 14H2O | 2:1 | triclinic | a = 6.21 b = 13.3 c = 6.25 α = 90.15°, β = 93.56°, γ = 82.08° | 510.29 | Biaxial (-) nα = 1.423 nβ = 1.439 nγ = 1.444
2V: calculated: 56° Max birefringence: δ = 0.021 |
[23] | ||
Wilcoxite | MgAl(SO4)2F · 17H2O | 2:1 | triclinic | P1 | a = 6.644, b = 6.749, c = 14.892 α = 79.664°, β = 80.113°, γ = 62.487 | 579.6 | 1.58 | Biaxial (-) nα = 1.424 nβ = 1.436 nγ = 1.438
2V: measured: 48° , calculated: 44° Max birefringence: δ = 0.014 |
[24] |
Krasheninnikovite | KNa2CaMg(SO4)3F | 3:1 | hexagonal | P63/mcm | a = 16.6682 c = 6.9007 Z = 6 | 1660.36 | 2.68 | Uniaxial (-) nω = 1.500 nε = 1.492
Max birefringence: δ = 0.008 |
[25] |
Shuvalovite | K2(Ca2Na)(SO4)3F | 3:1 | orthorhombic | Pnma | a = 13.2383 b = 10.3023 c = 8.9909 Z = 4 | 1226.22 | 2.64 | biaxial (−), nα = 1.493 nβ = 1.498 nγ = 1.498 2Vmeasured ≤ 20 | [26] |
Thermessaite-(NH4) | (NH4)2AlSO4F3 | 1:3 | orthorhombic | Pbcn | a = 11.3005 b = 8.6125 c = 6.8501 Z = 4 | 666.69 | [27] |
Artificial
name | formula | MW | ratio | system | space group | unit cell | volume | density | optical | CAS | references |
---|---|---|---|---|---|---|---|---|---|---|---|
LiMgFSO4 | 1:1 | triclinic | P1 | a = 5.1623 b = 5.388 c = 7.073 α = 106.68 β=107.40 and γ=97.50° Z=2 | [28] | ||||||
NaMgSO4F | 1:1 | monoclinic | C2/c | Z=4 | 109.802 | 2.84 | [29] | ||||
Na2AlSO4F3 | 1:1 | monoclinic | P2/c | a=6.3562 b=6.2899 c=7.1146 β=115.687° Z=2 | 256.33 | 2.928 | [30] | ||||
Li4NH4Al(SO4)2F4 | 2:4 | monoclinic | C2/c | a=13.6561 b=4.9761 c=13.9919 β=92.135° Z=4 | 950.2 | 2.383 | [30] | ||||
Na4TiF4(SO4)2 | 2:4 | [31] | |||||||||
β-K3[SO4]F | 1:1 | tetragonal | I4/mcm | a= 7.2961 c= 10.854 | [32] | ||||||
α-K3[SO4]F | 1:1 | cubic | Pm3m | a≈5.43 ≥585 °C | [32] | ||||||
KMgSO4F | 178.47 | 1:1 | orthorhombic | Pna21 | a=12.973 b=6.4585 c=10.635 Z=8 | 891.1 | 2.661 | colourless | [33][34] | ||
Li6K3Al(SO4)4F4 | 4:4 | triclinic | P1 | a=5.0304 b=9.5690 c=9.7078 α=70.968° β=75.531° γ=75.183° Z=1 | 420.08 | 2.554 | [30] | ||||
sodium calcium sulfapatite | Na6Ca4(SO4)6F2 | 6:2 | |||||||||
K3Ca2(SO4)3F | 3:1 | orthorhombic | Pn21a | a=13.467 b=10.521 c=9.167 Z=4 | 1299.9 | [35] | |||||
[N2C10H12] TiF4SO4 | 378.16? | 1:4 | triclinic | P1 | a=8.691 b=9.208 c=9.288 α=68.56 β=84.30 γ=81.59 Z=2 | 683.6 | 1.837 | colourless | [31] | ||
[N2C10H12]TiF2(SO4)2 | 436.22? | 2:2 | triclinic | P1 | a=4.5768 b=8.9162 c=10.1236 α=112.888 β=95.196 γ=98.706 Z=1 | 371.11 | 1.952 | colourless | [31] | ||
Rb2TiF2(SO4)2 · 2H2O | 1:1 | [36] | |||||||||
Cs2TiF2(SO4)2 · 3H2O | 1:1 | [36] | |||||||||
[N2C6H16]V(SO4)2F | 378.27 | 2:1 | monoclinic | P21/c | a=10.262 b =17.761 c=7.0518 β=93.93 Z=4 | 1282.3 | 1.959 | green | [31] | ||
Na2VF3SO4 | 1:3 | [31] | |||||||||
Na3CrF2(SO4)2 | 2:2 | [31] | |||||||||
LiMnSO4F | 1:1 | monoclinic | a=13.2406 b=6.4082 c=10.0229 β=120.499 | 732.76 | [37] | ||||||
[N2C6H16]2+Mn2F2(SO4)2 | 2:2 | [31] | |||||||||
Li2MnF3(SO4) | 1:3 | pink-brown | [38] | ||||||||
(NH4)2MnF3(SO4) | 1:3 | pink-brown | [38] | ||||||||
Na2MnF3(SO4) | 1:3 | pink-brown | [38] | ||||||||
Dipotassium trifluorosulfato manganate(III) | K2MnF3(SO4) | 1:3 | pink-brown | [38] | |||||||
FeFSO4 | 170.91 | 1:1 | monoclinic | C2/c | a = 7.3037 b = 7.0753 c = 7.3117 β = 119.758° | 328.017 | 3.461 | [39] | |||
K2FeF3SO4 | 1:3 | [31] | |||||||||
Li3FeF2(SO4)2·H2O | 2:2 | [31] | |||||||||
[N2C6H16]Fe(SO4)2F | 383.18 | 2:1 | monoclinic | P21/c | a=10.2220 b=17.6599 c=7.0437 β=93.894 Z=4 | 1268.59 | 2.006 | brown | [31] | ||
LiFeFSO4 | 177.85 | 1:1 | triclinic | P1 | a = 5.1751 b = 5.4915 c = 7.2211 α = 106.506° β = 107.178° γ=97.865° | 182.44 | 3.237 | grass green | [39] | ||
sodium ferrous sulfate fluoride | NaFeFSO4 | 193.91 | 1:1 | monoclinic | P21/c | a = 6.6739 b = 8.6989 c = 7.1869 β = 113.525° | 382.567 | 3.366 | [39] | ||
sodium ferrous sulfate fluoride dihydrate | NaFeFSO4·2H2O | 1:1 | monoclinic | P21/m | a=5.75959 b=7.38273 c=7.25047 β=113.3225 | 283.109 | white | [40] | |||
trisodium ferric disulfate difluoride | Na3Fe(SO4)2F2 | 2:2 | orthorhombic | Pnca | a = 6.6419 b = 8.8115 c = 14.0023 | [41] | |||||
NaCoFSO4 | 1:1 | monoclinic | C2/c | a=6.6687 b=8.6251 c=7.1444 β=114.323 | 374.46 | [42] | |||||
NaCoFSO4·2H2O | 1:1 | monoclinic | P21/m | a=5.73364 b=7.31498 c=7.18640 β=113.5028 | 276.40 | pink | [40] | ||||
NH4CoFSO4·2H2O | 1:1 | [43] | |||||||||
KCoFSO4·2H2O | 1:1 | [43] | |||||||||
NaNiFSO4·2H2O | 1:1 | monoclinic | P21/m | a=5.70118 b=7.27603 c=7.15634 β=113.8883 | 271.429 | green | [40] | ||||
LiZnSO4F | 1:1 | orthorhombic | Pnma | 7.40357 b=6.32995 c=7.42016 | 347.740 | [44] | |||||
KZnSO4F | 219.53 | 1:1 | orthorhombic | Pna21 | a=13.0602 b=6.4913 c=10.7106 Z=8 | 908.02 | 3.212 | transparent <190 nm | [34] | ||
K2Zn3(SO4)(HSO4)2F4 | 1:4 | orthorhombic | Cmc21 | a=17.725 b=7.6650 c=9.7505 Z=4 | 1324.7 | 3.212 | colourless | [45] | |||
Li4RbAl(SO4)2F4 | 2:4 | monoclinic | C2/c | a=13.6503 b=4.984 c=14.0081 β=91.509° Z=4 | 948.82 | 2.858 | [46] | ||||
Y(SO4)F | 203.97 | 1:1 | orthorhombic | Pnma | a=8.3128, b=6.9255, c=6.3905 Z=4 | 367.90 | 3.682 | [47] | |||
YSO4F·H2O | 1:1 | monoclinic | P21/n | a=4.9707 b=7.306 c=11.493 β =96.95° | birefringence 0.0357 at 546 nm | [48] | |||||
Y2Cu(OH)3(SO4)2F·H2O | 521.52 | 2:1 | monoclinic | P21/n | a=11.6889, b=6.8660, c=12.5280, β=97.092° Z=4 | 997.8 | 3.472 | blue | [47] | ||
KYSO4F2 | 1:2 | monoclinic | P21/m | a=6.4402 b=5.7784 c=6.992 β=113.684° Z=2 | 238.30 | 3.652 | band gap 7.79 eV; birefringence 0.015 @ 546.1 nm | [49] | |||
RbYSO4F2 | 1:2 | monoclinic | P21/m | a=6.5347 b=5.8212 c=7.1383 β=114.332° Z=2 | 247.42 | 4.140 | band gap 7.82 eV; birefringence 0.02 @ 546.1 nm | [49] | |||
Zr2O2F2SO4 · 6H2O | 1:2 | [50] | |||||||||
α-K3ZrF5SO4 · H2O | 1:5 | [36] | |||||||||
K2ZrF4SO4 | 1:4 | [36] | |||||||||
K2ZrF2(SO4)2 · 2.5H2O | 2:2 | [36] | |||||||||
K3Zr2F9SO4 · 2H2O | 1:9 | [36] | |||||||||
(NH4)3Zr2F9SO4 · 2H2O | 1:9 | [36] | |||||||||
(NH4)2ZrF4SO4 | 1:4 | [36] | |||||||||
(NH4)2ZrF2(SO4)2 · 2.5H2O | 2:2 | [36] | |||||||||
Rb2ZrF4SO4 | 1:4 | [36] | |||||||||
Rb2ZrF2(SO4)2 · 3H2O | 2:2 | [36] | |||||||||
Rb3Zr2F9SO4 ·2H2O | 1:9 | [36] | |||||||||
RbZr2O2F(SO4)2 · 5H2O | 2:1 | [36] | |||||||||
Cs2ZrF4SO4 | 1:4 | [36] | |||||||||
Cs2ZrF2(SO4)2 · 2H2O | 2:2 | [36] | |||||||||
Cs8Zr4F2(SO4)11 · 16H2O | 11:2 | [36] | |||||||||
CsZr2O2F(SO4)2 · 6H2O | 2:1 | [36] | |||||||||
Zr2O2F2SO4 · 5H2O | 1:2 | [36] | |||||||||
triindium trifluoride sulfate ditellurite hydrate | In3(SO4)(TeO3)2F3(H2O) | 866.74 | 1:3 | orthorhombic | P212121 | a=8.3115 b=9.4341 c=14.8068 | 1161.0 | 4.959 | band gap 4.10 eV; white | [51] | |
4,4'-bipyridine distannous difluoride disulfate | (C10H10N2)0.5[SnF(SO4)] | 2:2 | triclinic | P1 | a=4.726 b=7.935 c=11.203 α = 81.05° β = 87.59° γ=73.70° Z=2 | 398.3 | 2.608 | colourless | [52] | ||
diantimony dipotassium hexafluoride sulfate | K2SO4·(SbF3)2 | 531.76 | 1:6 | monoclinic | P21/c | a=9.1962 b=5.6523 c=19.2354 β =103.209 Z=4 | 973.40 | 3.629 | colourless | [53] | |
diantimony dirubidium hexafluoride sulfate | Rb2SO4·(SbF3)2 | 624.50 | 1:6 | monoclinic | P21 | a=9.405 b=5.7210 c=9.879 β = 103.850 Z=2 | 516.1 | 4.018 | colourless | [53] | |
tetraantimony hexarubidium dodecafluoride trisulfate | Rb6Sb4F12(SO4)3 | 1515.989 | 3:12 | trigonal | P3 | a=16.9490 c=7.5405 Z=2 | 1875.94 | 4.026 | white | 53168-89-1 | [54][55] |
hexaammonium dodecafluorotrisulfatotetraantimonate(III) | [NH4]6Sb4F12(SO4)3 | 3:12 | trigonal | P3 | a=17.07 c=7.515 Z=3 | 1896 | 2.92 | [56] | |||
hexarubidium dodecafluorotrisulfatotetraantimonate(III) | Rb6Sb4F12(SO4)3 | 3:12 | [56] | ||||||||
Li4CsAl(SO4)2F4 | 2:4 | monoclinic | C2/c | a=13.574 b=5.0427 c=14.258 β=91.961° Z=4 | 975.7 | 3.103 | [46] | ||||
tetraantimony hexacaesium dodecafluoride trisulfate | Cs6Sb4F12(SO4)3 | 1800.601 | 3:12 | triclinic | P1 | a=7.9044 b=10.5139 c=17.3534 al=90.350 β = 90.151 ga=104.797 Z=4 | 1394.3 | 4.289 | white | 53200-54-7 | [54][57] |
antimony caesium difluoride sulfate | CsSbF2SO4 | 388.72 | 1:2 | orthorhombic | Pna21 | a=9.9759 b=11.6616 c=5.2968 | 515.20 | 4.19 | clear, non-linear SH | [58] | |
LiLa2F3(SO4)2 | 2:3 | monoclinic | I2/a | a = 8.283, b = 6.947, c = 14.209 β = 95.30° Z=4 | [59] | ||||||
CeF2(SO4) | 1:2 | orthorhombic | Pca21 | a=8.3668 b=6.3600 c=8.3862 | birefringence 0.361@ 546 nm; SHG 8×KDP | [60] | |||||
NdFSO4·H2O | 277.32 | 1:1 | monoclinic | P21/n | a = 4.9948 b = 7.3684 c = 11.6366 β = 96.672° Z=4 | 425.37 | 4.330 | pink | [61] | ||
NaPr2F3(SO4)2 | 2:3 | monoclinic | I2/a | a = 8.223, b = 6.9212, c = 14.199, β = 95.88° Z=4 | light green | [62] | |||||
LiEr2F3(SO4)2 | 2:3 | orthorhombic | Pbcn | a = 14.791, b = 6.336, c = 8.137 | [59] | ||||||
hexa(triethylenetriammonium) tetrasamarium tetradecasulfate difluoride | [C4H16N3]6[Sm4F2(SO4)14] | 2621.43 | 14:2 | triclinic | P1 | a = 11.1988 b = 11.4073 c = 16.2666 α = 89.901°, β = 82.406°, γ = 67.757° Z=1 | 1903.9 | 2.286 | colourless | [61] | |
TbFSO4·H2O | 292.00 | 1:1 | monoclinic | P21/n | a = 5.0014 b = 7.377 c = 11.651 β = 96.692° Z=4 | 426.9 | 4.543 | colourless | [61] | ||
gadolinium fluoride sulfate | GdF[SO4] | 1:1 | orthorhombic | Pnma | a=8.436 b=7.0176 c=6.4338 Z=4 | [63] | |||||
γ-K2HfF2(SO4)2 · 2H2O | 2:2 | [36] | |||||||||
K2HfF2(SO4)2 · 2.5H2O | 2:2 | [36] | |||||||||
Na6Pb4(SO4)6F2 | 6:2 | [64] | |||||||||
ThSO4F2.H2O | 1:2 | monoclinic | P21n | a = 6.9065 b = 6.9256 c = 10.589 β = 96.755° Z = 4 | 502.98 | colourless | [65] | ||||
potassium catena-di—fluoro-difluorotetraoxo-di—sulphato-diuranate(VI) hydrate | K2UF2O2(SO4)·H2O | 1:2 | monoclinic | P21/c | a = 9.263 b = 8.672 c = 11.019 β= 101.60° Z = 4 | 867.1 | 3.83 | greenish yellow | [66][67] | ||
(NH4)2[UO2F2(SO4)] | triclinic | P1 | a=9.73 b=10.28 c=11.37 α = 107.4°, β = 111.9°, γ =106.9 Z=2 | greenish yellow | [67] | ||||||
(NH4)6[(UO2)2F4(SO4)3] | triclinic | P1 | a=9.35 b=9.85 c=11.25 α = 109.2°, β = 113.1°, γ =102.5 Z=1 | greenish yellow | [67] | ||||||
Cs2[(UO2)2F4(SO4)] | greenish yellow | [67] | |||||||||
(NH4)[UO2F(SO4)] | triclinic | P1 | a=8.99 b=7.12 c=7.42 α = 114.5°, β = 117.4°, γ =103.2 Z=1 | 1.92 | greenish yellow | [67] | |||||
RbUO2SO4F | orthorhombic | Pca21 | a=25.353 b=6.735 c=11.496 Z=12 | [68][69] | |||||||
[N2C6H16][UO2F2(SO4)] | 520.29 | 1:2 | triclinic | P1 | a=6.9105 b=9.6605 =10.1033 α=72.6594(14) β=87.068 γ=77.9568 Z=2 | 629.62 | 2.744 | yellow | [70] | ||
[N2C6H16][UO2F(SO4)]2 | 884.37 | 2:2 | orthorhombic | Pmmn | a=6.9503 b=17.2147 c=7.0867 Z=2 | 847.90 | 3.464 | yellow | [70] | ||
[N2C3H12][UO2F(SO4)]2·H2O | 862.32 | 2:2 | orthorhombic | Pnma | a=13.5775 b=14.6180 c=8.1168 Z=4 | 1610.99 | 3.555 | yellow | [70] | ||
[N2C5H14][UO2F(H2O)(SO4)]2 | 907.38 | 2:2 | monoclinic | P121/n1 | a=8.4354 b=15.5581 c=14.8442 β =96.666 Z=4 | 1935.0 | 3.115 | yellow | [70] | ||
[N2C6H18]2[UO2F(SO4)]4·H2O | 1792.80 | 4:4 | triclinic | P1 | a=10.8832 b=10.9386 c=16.5325 α=75.6604 β=73.6101 γ=89.7726 Z=2 | 1824.73 | 3.263 | yellow | [70] | ||
[N2C3H12][UO2F(SO4)]2·H2O | 864.34 | 2:2 | monoclinic | P121/n1 | a=6.7745 b=8.1589 c=14.3661 β =94.556 Z=2 | 791.54 | 3.626 | yellow | [70] | ||
diammonium hydrazinium triuranium(IV) tetrafluoride hexasulfate | U4+3F4(SO4)6·2NH4·H3N-NH3 | 1436.6 | 6:4 | monoclinic | C2/c | a=15.2309 b=8.77998 c=18.8590 β=105.5030 Z=4 | 2432.69 | 4.392 | green | [71] |
References
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- ^ de Marignac, Jean Charles (1859). Recherches sur les formes cristallines et la composition chimique de divers sels. p. 221.
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