Terbium
Terbium | ||||||||||||||||||||||||||||
---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
Pronunciation | /ˈtɜːrbiəm/ | |||||||||||||||||||||||||||
Appearance | silvery white | |||||||||||||||||||||||||||
Standard atomic weight Ar°(Tb) | ||||||||||||||||||||||||||||
Terbium in the periodic table | ||||||||||||||||||||||||||||
| ||||||||||||||||||||||||||||
kJ/mol | ||||||||||||||||||||||||||||
Heat of vaporization | 391 kJ/mol | |||||||||||||||||||||||||||
Molar heat capacity | 28.91 J/(mol·K) | |||||||||||||||||||||||||||
Vapor pressure
| ||||||||||||||||||||||||||||
Atomic properties | ||||||||||||||||||||||||||||
Discovery and first isolation | Carl Gustaf Mosander (1843) | |||||||||||||||||||||||||||
Isotopes of terbium | ||||||||||||||||||||||||||||
| ||||||||||||||||||||||||||||
Terbium is a
Swedish chemist Carl Gustaf Mosander discovered terbium as a chemical element in 1843. He detected it as an impurity in yttrium oxide, Y2O3. Yttrium and terbium, as well as erbium and ytterbium, are named after the village of Ytterby in Sweden. Terbium was not isolated in pure form until the advent of ion exchange techniques.
Terbium is used to
Most of the world's terbium supply is used in green
Characteristics
Physical properties
Terbium is a silvery-white
The terbium(III) cation is brilliantly
Terbium has a simple
Chemical properties
Terbium metal is an electropositive element and oxidizes in the presence of most acids (such as sulfuric acid), all of the halogens, and even water.[13]
- 2 Tb (s) + 3 H2SO4 → 2 Tb3+ + 3 SO2−4 + 3 H2↑
- 2 Tb + 3 X2 → 2 TbX3 (X = F, Cl, Br, I)
- 2 Tb (s) + 6 H2O → 2 Tb(OH)3 + 3 H2↑
Terbium also oxidizes readily in air to form a mixed terbium(III,IV) oxide:[13]
- 8 Tb + 7 O2 → 2 Tb4O7
The most common oxidation state of terbium is +3 (trivalent), such as
3. In the solid state, tetravalent terbium is also known, in compounds such as TbO2 and TbF4.[14] In solution, terbium typically forms trivalent species, but can be oxidized to the tetravalent state with ozone in highly basic aqueous conditions.[15]
The coordination and organometallic chemistry of terbium is similar to other lanthanides. In aqueous conditions, terbium can be coordinated by nine water molecules, which are arranged in a tricapped trigonal prismatic molecular geometry. Complexes of terbium with lower coordination number are also known, typically with bulky ligands like bis(trimethyl-silylamide), which forms the three-coordinate Tb[N(SiMe3)2]3 complex.
Most coordination and organometallic complexes contain terbium in the trivalent oxidation state. Divalent (Tb2+) complexes are also known, usually with bulky cyclopentadienyl-type ligands.[16][17][18] A few coordination compounds containing terbium in its tetravalent state are also known.[19][20][21]
Oxidation states
Like most
Compounds
Terbium combines with nitrogen, carbon, sulfur, phosphorus, boron, selenium, silicon and arsenic at elevated temperatures, forming various binary compounds such as TbH2, TbH3, TbB2,
Terbium(IV) fluoride is the only halide that tetravalent terbium can form, and has strong oxidizing properties. It is also a strong fluorinating agent, emitting relatively pure atomic fluorine when heated, rather than the mixture of fluoride vapors emitted from cobalt(III) fluoride or cerium(IV) fluoride.[25] It can be obtained by reacting terbium(III) chloride or terbium(III) fluoride with fluorine gas at 320 °C:[26]
- 2 TbF3 + F2 → 2 TbF4
When TbF4 and CsF is mixed in a stoichiometric ratio, in a fluorine gas atmosphere, CsTbF5 is obtained. It is an orthorhombic crystal, with space group Cmca, with a layered structure composed of [TbF8]4− and 11-coordinated Cs+.[27] The compound BaTbF6 can be prepared in a similar method. It is an orthorhombic crystal, with space group Cmma. The compound [TbF8]4− also exists.[28]
Other compounds include
Isotopes
Naturally occurring terbium is composed of its only stable
The element also has 27 nuclear isomers, with masses of 141–154, 156, and 158 (not every mass number corresponds to only one isomer). The most stable of them are terbium-156m, with a half-life of 24.4 hours, and terbium-156m2, with a half-life of 22.7 hours; this is longer than half-lives of most ground states of radioactive terbium isotopes, except those with mass numbers 155–161.[29]
Terbium-149, with a half-life of 4.1 hours, is a promising candidate in
History
Swedish chemist Carl Gustaf Mosander discovered terbium in 1843. He detected it as an impurity in yttrium oxide, Y2O3. Yttrium is named after the village of Ytterby in Sweden. Terbium was not isolated in pure form until the advent of ion exchange techniques.[32][33][34]: 701 [35][32][36][37]
Mosander first separated yttria into three fractions, all named for the ore: yttria, erbia, and terbia. "Terbia" was originally the fraction that contained the pink color, due to the element now known as erbium. "Erbia" (containing what is now known as terbium) originally was the fraction that was essentially colorless in solution. The insoluble oxide of this element was noted to be tinged brown.
Later workers had difficulty in observing the minor colorless "erbia", but the soluble pink fraction was impossible to miss. Arguments went back and forth as to whether erbia even existed. In the confusion, the original names got reversed, and the exchange of names stuck, so that the pink fraction referred eventually to the solution containing erbium (which in solution, is pink). It is now thought that workers using double sodium or potassium sulfates to remove ceria from yttria inadvertently lost the terbium into the ceria-containing precipitate. What is now known as terbium was only about 1% of the original yttria, but that was sufficient to impart a yellowish color to the yttrium oxide. Thus, terbium was a minor component in the original fraction containing it, where it was dominated by its immediate neighbors, gadolinium and dysprosium.
Thereafter, whenever other rare earths were teased apart from this mixture, whichever fraction gave the brown oxide retained the terbium name, until at last, the brown oxide of terbium was obtained in pure form. The 19th century investigators did not have the benefit of the UV fluorescence technology to observe the brilliant yellow or green Tb(III) fluorescence that would have made terbium easier to identify in solid mixtures or solutions.[33]
Occurrence
Terbium is contained along with other rare earth elements in many minerals, including monazite ((Ce,La,Th,Nd,Y)PO4 with up to 0.03% terbium), xenotime (YPO4) and euxenite ((Y,Ca,Er,La,Ce,U,Th)(Nb,Ta,Ti)2O6 with 1% or more terbium). The crust abundance of terbium is estimated as 1.2 mg/kg.[23] No terbium-dominant mineral has yet been found.[38]
Currently, the richest commercial sources of terbium are the ion-adsorption
In 2018, a rich terbium supply was discovered off the coast of
Production
Crushed terbium-containing minerals are treated with hot concentrated sulfuric acid to produce water-soluble sulfates of rare earths. The acidic filtrates are partially neutralized with caustic soda to pH 3–4. Thorium precipitates out of solution as hydroxide and is removed. After that the solution is treated with ammonium oxalate to convert rare earths into their insoluble oxalates. The oxalates are decomposed to oxides by heating. The oxides are dissolved in nitric acid that excludes one of the main components, cerium, whose oxide is insoluble in HNO3. Terbium is separated as a double salt with ammonium nitrate by crystallization.[23]
The most efficient separation routine for terbium salt from the rare-earth salt solution is ion exchange. In this process, rare-earth ions are sorbed onto suitable ion-exchange resin by exchange with hydrogen, ammonium or cupric ions present in the resin. The rare earth ions are then selectively washed out by suitable complexing agents. As with other rare earths, terbium metal is produced by reducing the anhydrous chloride or fluoride with calcium metal. Calcium and tantalum impurities can be removed by vacuum remelting, distillation, amalgam formation or zone melting.[23]
Applications
Terbium is used as a
Terbium is also used in alloys and in the production of electronic devices. As a component of Terfenol-D, terbium is used in actuators, in naval sonar systems, sensors, in the SoundBug device (its first commercial application), and other magnetomechanical devices. Terfenol-D is a terbium alloy that expands or contracts in the presence of a magnetic field. It has the highest magnetostriction of any alloy.[40]
Terbium
Terbium is also used to detect
In 2023, terbium compounds were used to create a lattice with one iron (Fe) atom, that was then examined by synchrotron x-ray beam, to examine one atom at sub-atomic levels for the first time.[42]
Precautions
Handling of terbium, like other lanthanides, should be done with care. Terbium compounds show moderate toxicity, although there is limited data on the specific toxicity of the element. They can act as irritants to the skin and eyes upon contact. Ingestion of terbium compounds should be avoided due to their mildly toxic nature.[43][44]
In the event of exposure:
- If inhaled: Move the person to fresh air, provide artificial respiration if breathing has stopped, and seek medical advice.
- In case of skin contact: Wash immediately with soap and water, then rinse thoroughly and seek medical advice.
- In case of eye contact: Rinse the eyes for several minutes under running water and consult a physician.
- If swallowed: Seek immediate medical treatment.[45]
For safe handling and storage:
- Keep terbium compounds in tightly sealed containers stored in a cool, dry place away from oxidizing agents.
- Use personal protective equipment, such as impervious gloves and safety glasses, to prevent skin and eye contact.
- Ensure adequate ventilation in the working area and avoid releasing terbium compounds into the environment without proper permits.[46]
Proper disposal of terbium compounds should be conducted in accordance with local environmental regulations.[47]
See also
- Terbium compounds
- List of elements facing shortage
References
- ^ "Standard Atomic Weights: Terbium". CIAAW. 2021.
- ISSN 1365-3075.
- ^ ISBN 978-1-62708-155-9.
- .
- PMID 34753931.
- ISBN 0-8493-0464-4.
- .
- ^ ISBN 978-0-8493-0486-6.
- ^ "Rare-Earth Metal Long Term Air Exposure Test". Retrieved 2009-05-05.
- ^ V.B. Taxak, R. Kumar, J.K. Makrandi, S.P. Khatkar Displays, 30 (2009), pp. 170–174
- .
- ^ Jackson, M. (2000). "Magnetism of Rare Earth" (PDF). The IRM Quarterly. 10 (3): 1.
- ^ a b "Chemical reactions of Terbium". Webelements. Retrieved 2009-06-06.
- .
- .
- S2CID 105379627.
- PMID 23697603.
- S2CID 199388151.
- S2CID 189814301.[permanent dead link]
- S2CID 207197096.
- S2CID 209385870.
- ISBN 978-0-08-037941-8.
- ^ ISBN 978-0-07-049439-8. Retrieved 2009-06-06.
- ISBN 978-81-265-1338-3.
- .
- ISBN 978-0-7923-1018-1.
- .
- .
- ^ .
- PMID 29564382.
- PMID 34207408.
- ^ ISBN 978-0-8412-3020-0.
- ^ ISBN 978-0-415-33340-5.
- ^ Weeks, Mary Elvira (1956). The discovery of the elements (6th ed.). Easton, PA: Journal of Chemical Education.
- .
- ^ Marshall, James L. Marshall; Marshall, Virginia R. Marshall (2015). "Rediscovery of the elements: The Rare Earths–The Beginnings" (PDF). The Hexagon: 41–45. Retrieved 30 December 2019.
- ^ Marshall, James L. Marshall; Marshall, Virginia R. Marshall (2015). "Rediscovery of the elements: The Rare Earths–The Confusing Years" (PDF). The Hexagon: 72–77. Retrieved 30 December 2019.
- ^ Hudson Institute of Mineralogy (1993–2018). "Mindat.org". www.mindat.org. Retrieved 14 January 2018.
- PMID 29636486.
- .
- .
- S2CID 258992110.
- ^ "Harmful Effects of Terbium". Vedantu. Retrieved 2023-11-07.
- ^ "Terbium". Los Alamos National Laboratory. Retrieved 2023-11-07.
- ^ "Terbium(III,IV) Oxide Safety Data Sheet". American Elements. Retrieved 2023-11-07.
- ^ Cite error: The named reference
americanelementsstorage
was invoked but never defined (see the help page). - ^ "Terbium(III) oxide - Handling and Storage". Sciencemadness Wiki. Retrieved 2023-11-07.