Isotopes of strontium
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The alkaline earth metal strontium (38Sr) has four stable, naturally occurring isotopes: 84Sr (0.56%), 86Sr (9.86%), 87Sr (7.0%) and 88Sr (82.58%). Its standard atomic weight is 87.62(1).
Only 87Sr is
radioactive alkali metal 87Rb, which has a half-life of 4.88 × 1010 years (i.e. more than three times longer than the current age of the universe). Thus, there are two sources of 87Sr in any material: primordial, formed during nucleosynthesis along with 84Sr, 86Sr and 88Sr; and that formed by radioactive decay of 87Rb. The ratio 87Sr/86Sr is the parameter typically reported in geologic investigations;[4] ratios in minerals and rocks have values ranging from about 0.7 to greater than 4.0 (see rubidium–strontium dating). Because strontium has an electron configuration similar to that of calcium, it readily substitutes for calcium in minerals
.
In addition to the four stable isotopes, thirty-two unstable isotopes of strontium are known to exist, ranging from 73Sr to 108Sr. Radioactive isotopes of strontium primarily decay into the neighbouring elements
beta minus decay) and rubidium (85Sr, 83Sr and lighter isotopes, via positron emission or electron capture). The longest-lived of these isotopes, and the most relevantly studied, are 90Sr with a half-life of 28.9 years, 85Sr with a half-life of 64.853 days, and 89Sr (89Sr) with a half-life
of 50.57 days. All other strontium isotopes have half-lives shorter than 50 days, most under 100 minutes.
beta particles
directly to the cancerous portions of the bone, where calcium turnover is greatest.
Strontium-90 is a by-product of beta emitter, it is used in SNAP (Systems for Nuclear Auxiliary Power) devices. These devices hold promise for use in spacecraft
, remote weather stations, navigational buoys, etc., where a lightweight, long-lived, nuclear-electric power source is required.
In 2020, researchers have found that mirror nuclides 73Sr and 73Br were found to not behave identically to each other as expected.[7]
List of isotopes
Nuclide [n 1] |
Z | N | Isotopic mass (Da) [n 2][n 3] |
Half-life [n 4] |
Daughter isotope [n 6][n 7] |
Natural abundance (mole fraction) | |||||||||||||
---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
Excitation energy | Normal proportion | Range of variation | |||||||||||||||||
73Sr | 38 | 35 | 72.96597(64)# | >25 ms | β+ (>99.9%) | 73Rb | 1/2−# | ||||||||||||
β+, p (<.1%) | 72Kr | ||||||||||||||||||
74Sr | 38 | 36 | 73.95631(54)# | 50# ms [>1.5 µs] | β+ | 74Rb | 0+ | ||||||||||||
75Sr | 38 | 37 | 74.94995(24) | 88(3) ms | β+ (93.5%) | 75Rb | (3/2−) | ||||||||||||
β+, p (6.5%) | 74Kr | ||||||||||||||||||
76Sr | 38 | 38 | 75.94177(4) | 7.89(7) s | β+ | 76Rb | 0+ | ||||||||||||
77Sr | 38 | 39 | 76.937945(10) | 9.0(2) s | β+ (99.75%) | 77Rb | 5/2+ | ||||||||||||
β+, p (.25%) | 76Kr | ||||||||||||||||||
78Sr | 38 | 40 | 77.932180(8) | 159(8) s | β+ | 78Rb | 0+ | ||||||||||||
79Sr | 38 | 41 | 78.929708(9) | 2.25(10) min | β+ | 79Rb | 3/2(−) | ||||||||||||
80Sr | 38 | 42 | 79.924521(7) | 106.3(15) min | β+ | 80Rb | 0+ | ||||||||||||
81Sr | 38 | 43 | 80.923212(7) | 22.3(4) min | β+ | 81Rb | 1/2− | ||||||||||||
82Sr | 38 | 44 | 81.918402(6) | 25.36(3) d | EC | 82Rb | 0+ | ||||||||||||
83Sr | 38 | 45 | 82.917557(11) | 32.41(3) h | β+ | 83Rb | 7/2+ | ||||||||||||
83mSr | 259.15(9) keV | 4.95(12) s | IT | 83Sr | 1/2− | ||||||||||||||
84Sr | 38 | 46 | 83.913425(3) | Observationally Stable[n 9]
|
0+ | 0.0056 | 0.0055–0.0058 | ||||||||||||
85Sr | 38 | 47 | 84.912933(3) | 64.853(8) d | EC | 85Rb | 9/2+ | ||||||||||||
85mSr | 238.66(6) keV | 67.63(4) min | IT (86.6%) | 85Sr | 1/2− | ||||||||||||||
β+ (13.4%) | 85Rb | ||||||||||||||||||
86Sr | 38 | 48 | 85.9092607309(91) | Stable | 0+ | 0.0986 | 0.0975–0.0999 | ||||||||||||
86mSr | 2955.68(21) keV | 455(7) ns | 8+ | ||||||||||||||||
87Sr[n 10] | 38 | 49 | 86.9088774970(91) | Stable | 9/2+ | 0.0700 | 0.0694–0.0714 | ||||||||||||
87mSr | 388.533(3) keV | 2.815(12) h | IT (99.7%) | 87Sr | 1/2− | ||||||||||||||
EC (.3%) | 87Rb | ||||||||||||||||||
88Sr[n 11] | 38 | 50 | 87.9056122571(97) | Stable | 0+ | 0.8258 | 0.8229–0.8275 | ||||||||||||
89Sr[n 11] | 38 | 51 | 88.9074507(12) | 50.57(3) d | β− | 89Y | 5/2+ | ||||||||||||
90Sr[n 11] | 38 | 52 | 89.907738(3) | 28.90(3) y | β− | 90Y | 0+ | ||||||||||||
91Sr | 38 | 53 | 90.910203(5) | 9.63(5) h | β− | 91Y | 5/2+ | ||||||||||||
92Sr | 38 | 54 | 91.911038(4) | 2.66(4) h | β− | 92Y | 0+ | ||||||||||||
93Sr | 38 | 55 | 92.914026(8) | 7.423(24) min | β− | 93Y | 5/2+ | ||||||||||||
94Sr | 38 | 56 | 93.915361(8) | 75.3(2) s | β− | 94Y | 0+ | ||||||||||||
95Sr | 38 | 57 | 94.919359(8) | 23.90(14) s | β− | 95Y | 1/2+ | ||||||||||||
96Sr | 38 | 58 | 95.921697(29) | 1.07(1) s | β− | 96Y | 0+ | ||||||||||||
97Sr | 38 | 59 | 96.926153(21) | 429(5) ms | β− (99.95%) | 97Y | 1/2+ | ||||||||||||
β−, n (.05%) | 96Y | ||||||||||||||||||
97m1Sr | 308.13(11) keV | 170(10) ns | (7/2)+ | ||||||||||||||||
97m2Sr | 830.8(2) keV | 255(10) ns | (11/2−)# | ||||||||||||||||
98Sr | 38 | 60 | 97.928453(28) | 0.653(2) s | β− (99.75%) | 98Y | 0+ | ||||||||||||
β−, n (.25%) | 97Y | ||||||||||||||||||
99Sr | 38 | 61 | 98.93324(9) | 0.269(1) s | β− (99.9%) | 99Y | 3/2+ | ||||||||||||
β−, n (.1%) | 98Y | ||||||||||||||||||
100Sr | 38 | 62 | 99.93535(14) | 202(3) ms | β− (99.02%) | 100Y | 0+ | ||||||||||||
β−, n (.98%) | 99Y | ||||||||||||||||||
101Sr | 38 | 63 | 100.94052(13) | 118(3) ms | β− (97.63%) | 101Y | (5/2−) | ||||||||||||
β−, n (2.37%) | 100Y | ||||||||||||||||||
102Sr | 38 | 64 | 101.94302(12) | 69(6) ms | β− (94.5%) | 102Y | 0+ | ||||||||||||
β−, n (5.5%) | 101Y | ||||||||||||||||||
103Sr | 38 | 65 | 102.94895(54)# | 50# ms [>300 ns] | β− | 103Y | |||||||||||||
104Sr | 38 | 66 | 103.95233(75)# | 30# ms [>300 ns] | β− | 104Y | 0+ | ||||||||||||
105Sr | 38 | 67 | 104.95858(75)# | 20# ms [>300 ns] | |||||||||||||||
106Sr[8] | 38 | 68 | |||||||||||||||||
107Sr[8] | 38 | 69 | |||||||||||||||||
108Sr[9] | 38 | 70 | |||||||||||||||||
This table header & footer: |
- ^ mSr – Excited nuclear isomer.
- ^ ( ) – Uncertainty (1σ) is given in concise form in parentheses after the corresponding last digits.
- ^ # – Atomic mass marked #: value and uncertainty derived not from purely experimental data, but at least partly from trends from the Mass Surface (TMS).
- ^ a b # – Values marked # are not purely derived from experimental data, but at least partly from trends of neighboring nuclides (TNN).
- ^
Modes of decay:
EC: Electron capture IT: Isomeric transitionn: Neutron emission p: Proton emission - ^ Bold italics symbol as daughter – Daughter product is nearly stable.
- ^ Bold symbol as daughter – Daughter product is stable.
- ^ ( ) spin value – Indicates spin with weak assignment arguments.
- ^ Believed to decay by β+β+ to 84Kr
- ^ Used in rubidium–strontium dating
- ^ Fission product
References
- .
- ^ "Standard Atomic Weights: Strontium". CIAAW. 1969.
- ISSN 1365-3075.
- ISBN 978-1-107-09944-9.
- PMID 2419578.
- S2CID 99369165.
- ^ "Discovery by UMass Lowell-led team challenges nuclear theory". Space Daily. Retrieved 2022-06-26.
- ^ .
- S2CID 234019083.
- Isotope masses from:
- Audi, Georges; Bersillon, Olivier; Blachot, Jean;
- Isotopic compositions and standard atomic masses from:
- .
- Wieser, Michael E. (2006). "Atomic weights of the elements 2005 (IUPAC Technical Report)". .
- "News & Notices: Standard Atomic Weights Revised". International Union of Pure and Applied Chemistry. 19 October 2005.
- Half-life, spin, and isomer data selected from the following sources.
- Audi, Georges; Bersillon, Olivier; Blachot, Jean;
- National Nuclear Data Center. "NuDat 2.x database". Brookhaven National Laboratory.
- Holden, Norman E. (2004). "11. Table of the Isotopes". In Lide, David R. (ed.). ISBN 978-0-8493-0485-9.