User:R8R/sandbox
User:R8R/Rethinking rules on spellings of elements
Lead | ||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||
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Pronunciation | /ˈlɛd/ | |||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||
Appearance | metallic gray | |||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||
Standard atomic weight Ar°(Pb) | ||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||
Lead in the periodic table | ||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||
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7000 BCE) | ||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||
Symbol | "Pb": from Latin plumbum | |||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||
Isotopes of lead | ||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||
Isotopic abundances vary greatly by sample[5] | ||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||
Lead is a
Lead is a relatively unreactive
Lead is easily extracted from its ores and was known to prehistoric people in Western Asia. A principal ore of lead, galena, often bears silver, and interest in silver helped initiate widespread lead extraction and use in ancient Rome. Lead production declined after the fall of Rome and did not reach comparable levels again until the Industrial Revolution. Nowadays, global production of lead is about ten million tonnes annually; secondary production from recycling accounts for more than half of that figure.
Lead has several properties that make it useful: high density, low melting point, ductility, and relative inertness to
Physical properties
Atomic
A lead atom has 82 electrons, arranged in an
The lighter group 14 elements form stable or metastable
Bulk
Freshly prepared lead has a bright silvery appearance with a hint of blue
Lead's close packed face-centered cubic structure and high atomic weight result in a density[15] of 11.34 g/cm3, which is greater than that of common metals such as iron (7.87 g/cm3), copper (8.93 g/cm3), and zinc (7.14 g/cm3).[16] It is the origin of the idiom to go over like a lead balloon.[17] Some rarer metals are denser: tungsten and gold are both 19.3 g/cm3, and osmium— the densest metal known—has a density of 22.59 g/cm3, almost twice that of lead.[18]
Lead is a very soft metal with a
The melting point of lead—at 327.5 °C (621.5 °F)
Isotopes
Isotopic abundances vary greatly by sample talk |
Natural lead consists of four stable isotopes with mass numbers of 204, 206, 207, and 208,[30] and traces of five short-lived radioisotopes.[31] The high number of isotopes is due to lead's atomic number of 82 being even,[e] as well as a magic number (meaning lead's protons form complete shells within its atomic nucleus).[f] With its high atomic number, lead is the heaviest element whose natural isotopes are regarded as stable. This title was formerly held by bismuth, with an atomic number of 83, but its only primordial isotope was found in 2003 to decay at an extremely gradual rate.[g] The four stable isotopes of lead could theoretically undergo alpha decay to isotopes of mercury with a release of energy, but this has not been observed for any of them;[32] their predicted half-lives range from 1035 to 10189 years.[35]
Three of the stable isotopes are found in three of the four major
Apart from the stable isotopes, which make up almost all lead that exists naturally, there are
In total, forty-three lead isotopes have been synthesized, with mass numbers 178–220.[32] Lead-205 is the most stable, with a half-life of around 1.5×107 years.[h] The second-most stable is the synthetic lead-202, which has a half-life of about 53,000 years, longer than any of the natural trace radioisotopes.[32]
Chemistry
Bulk lead exposed to moist air forms a protective layer of varying composition.
The action of water on lead has the potential to make lead plumbing dangerous.[48] An excess of dissolved carbon dioxide in the carried water may result in the formation of soluble lead bicarbonate; oxygenated water may similarly dissolve lead as lead(II) hydroxide.[49] Drinking such water, over time, has the potential to cause health problems due to the toxicity of the dissolved lead.[i]
Fluorine reacts with lead at room temperature, forming lead(II) fluoride. The reaction with chlorine is similar but requires heating as the resulting chloride layer diminishes the reactivity of the elements.[45][51] Molten lead reacts with the chalcogens to give lead(II) chalcogenides.[52]
Lead metal is not attacked by dilute
Inorganic compounds
Lead shows two main oxidation states: +4 and +2. The
There is a relatively large difference in the electronegativity of lead(II) at 1.87 and lead(IV) at 2.33. This difference marks the reversal in the trend of increasing stability of the +4 oxidation state going down group 14; tin, by comparison, has values of 1.80 in the +2 oxidation state and 1.96 in the +4 state.[54]
Lead(II)
Lead(II) compounds are characteristic of the inorganic chemistry of lead. Even strong
Lead monoxide exists in two
Lead dihalides are well-characterized; this includes the diastatide,
4]2−
, [PbCl
6]4−
, and the [Pb
2Cl
9]5n−
n chain anion.[62]
Lead(IV)
Few inorganic lead(IV) compounds are known, and these are typically strong oxidants or exist only in highly acidic solutions.
Other oxidation states
Some lead compounds exist in formal oxidation states other than +4 or +2. Lead(III) may be obtained, as an intermediate between lead(II) and lead(IV), in larger organolead complexes.[69][70] This oxidation state is not stable as the both the lead(III) ion and the larger complexes containing it are radicals; the same applies for lead(I), which can be found in such species.[71]
Numerous mixed lead(II,IV) oxides are known. When PbO2 is heated in air, it becomes Pb12O19 at 293 °C, Pb12O17 at 351 °C, Pb3O4 at 374 °C, and finally PbO at 605 °C. A further sesquioxide Pb2O3 can be obtained at high pressure, along with several non-stoichiometric phrases. Many of them show defect fluorite structures in which some oxygen atoms are replaced by vacancies: for instance, PbO can be considered as having such a structure, with every alternate layer of oxygen atoms absent.[72]
Negative oxidation states can occur as
Organolead
Lead can form multiply bonded chains, a property it shares with its lighter homolog, carbon. Its capacity to do so is much less because the Pb–Pb bond energy (98 kJ/mol) is far lower than that of the C–C bond (356 kJ/mol).[52] With itself lead can build metal–metal bonds of an order up to three.[76] With carbon, lead forms organolead compounds similar to, but generally less stable than, typical organic compounds[77] (due to the Pb–C bond being rather weak).[57] This makes the organometallic chemistry of lead far less wide-ranging than that of tin.[78] It predominantly forms organolead(IV) compounds. Very few organolead(II) compounds are known: even starting with inorganic lead(II) reactants results in organolead(IV) products. The most well-characterized exceptions are the purple bis(disyl)plumbylene, Pb[CH(SiMe)3)2]2 and lead cyclopentadienide, Pb(η5-C5H5)2.[78]
The simplest
Origin and occurrence
In space
Atomic number |
Element | Relative amount |
---|---|---|
42 | Molybdenum | 0.798 |
46 | Palladium | 0.440 |
50 | Tin | 1.146 |
78 | Platinum | 0.417 |
80 | Mercury | 0.127 |
82 | Lead | 1 |
90 | Thorium | 0.011 |
92 | Uranium | 0.003 |
Lead 's per-particle abundance in the
Primordial lead—which comprises the isotopes lead-204, lead-206, lead-207, and lead-208—was mostly created as a result of repetitive neutron capture processes occurring in stars. The two main modes of capture are the s- and r-processes.[86]
In the s-process (s is for "slow"), captures are separated by years or decades, allowing less stable nuclei to beta decay. For example, a stable thallium-203 nucleus captures a neutron and becomes thallium-204; this undergoes beta decay to give stable lead-204; on capturing another neutron, it becomes lead-205, which is stable enough to generally last longer than a capture takes (its half-life is around 15 million years). Further captures result in lead-206, lead-207, and lead-208. On capturing another neutron, lead-208 becomes lead-209, which quickly decays into bismuth-209. On capturing another neutron, bismuth-209 becomes bismuth-210, and this undergoes alpha decay to thallium-206 (which beta decays to lead-206), or beta decays to polonium-210 (which alpha decays to lead-206). The cycle ends at lead-206, lead-207, lead-208, and bismuth-209.[86]
In the r-process (r is for "rapid"), captures happen faster than nuclei can decay. This occurs in environments with a high neutron density, such as a supernova or the merger of two neutron stars. The neutron flux involved may be on the order of 1022 neutrons/(cm2·second).[87] The r-process does not form as much lead as the s-process. It tends to stop once neutron-rich nuclei reach 126 neutrons. At this point, the neutrons are arranged in complete shells within the atomic nucleus, and it becomes harder to energetically accommodate more of them. When the neutron flux subsides, these nuclei beta decay into stable isotopes of osmium, iridium, and platinum.[86]
On Earth
Lead is classified as a
The main lead-bearing mineral is galena (PbS), which is mostly found with zinc ores.[88] Most other lead minerals are related to galena in some way; for example, boulangerite, Pb
5Sb
4S
11, is a mixed sulfide derived from galena; anglesite, PbSO
4, is a product of galena oxidation; and cerussite or white lead ore, PbCO
3, is a decomposition product of galena. Arsenic, tin, antimony, silver, gold, and bismuth are common impurities in lead minerals.[88]
World lead resources exceed 2 billion tons.[91] Significant deposits are located in Australia, China, Ireland, Mexico, Peru, Portugal, Russia, and the United States. Global reserves—resources that are economically feasible to extract—totaled 89 million tons in 2015, of which Australia had 35 million, China 15.8 million, and Russia 9.2 million.[91]
Typical background concentrations of lead do not exceed 0.1 μg/m3 in the atmosphere; 100 mg/kg in soil; and 5 μg/L in freshwater and seawater.[92]
Etymology
The modern English word "lead" is of Germanic origin; it comes from the Middle English leed and Old English lēad (with the macron above the "e" signifying that the vowel sound of that letter is long).[93] The Old English word is derived from the hypothetical reconstructed Proto-Germanic *lauda- ("lead").[94] According to accepted linguistic theory, this word bore descendants in most Germanic languages of exactly the same meaning.
The origin of the Proto-Germanic *lauda- is not agreed within the linguistic community. One hypothesis suggests it is derived from
The name of the chemical element is not related to the verb of the same spelling, which is instead derived from (eventually) Proto-Germanic *laidijan- ("to lead").[97]
History
Prehistory and early history
Metallic lead beads
Classical era
Because silver was extensively used as a decorative material and an exchange medium, lead deposits came to be worked in Asia Minor from 3000 BC,
This metal was by far the most used material in classical antiquity, and it is appropriate to refer to the (Roman) Lead Age. Lead was to the Romans what plastic is to us.
Heinz Eschnauer and Markus Stoeppler
"Wine—An enological specimen bank", 1992[106]
Rome's territorial expansion in Europe and across the Mediterranean, and its development of mining, led to it becoming the greatest producer of lead during the classical era, with an estimated annual output peaking at 80,000 tonnes. Like their predecessors, the Romans obtained lead mostly as a by-product of silver smelting.[98][107][108] Lead mining occurred in Central Europe, Britain, the Balkans, Greece, Anatolia, and Hispania, with the latter accounting for 40% of world production.[98]
Lead was used for making
The Roman author Vitruvius reported the health dangers of lead[114] and modern writers have suggested that lead poisoning played a major role in the decline of the Roman Empire.[115][116][m] Other researchers have criticized such claims, citing errors in linking the fall of Rome to lead poisoning, and even "false evidence".[118][119] According to archaeological research, Roman lead pipes increased lead levels in tap water but such an effect was "unlikely to have been truly harmful".[120][121] When lead poisoning did occur, victims were called "saturnine" after the ghoulish father of the gods, Saturn, since they became dark and cynical. By association, lead was considered the father of all metals.[122] Its social status was low as it was readily available in Roman society[123] and cheap.[124]
Confusion with tin and antimony
During the classical era (and even up to the 17th century), tin was often not distinguished from lead: Romans called lead plumbum nigrum ("black lead"), and tin plumbum candidum ("bright lead"). The association of lead and tin can be seen in other languages: the word olovo in Czech translates to "lead", but in Russian the cognate олово (olovo) means "tin".[125] To add to the confusion, lead bore a close relation to antimony: both elements commonly occur as sulfides (galena and stibnite), often together. Pliny wrote that stibnite would give lead on heating, whereas the mineral produced on heating was antimony.[126] In countries such as Turkey and India, the originally Persian name surma came to refer to either antimony sulfide or lead sulfide,[127] and in some languages, such as Russian, gave its name to antimony (сурьма).[128]
Middle Ages and the Renaissance
Lead mining in Western Europe declined after the fall of the Western Roman Empire, with Arabian Iberia being the only region having a significant output.[130][131] The largest production of lead occurred in South and East Asia, especially China and India, where lead mining grew strongly.[131]
In Europe, lead production only began to revive in the 11th and 12th centuries, where it was again used for roofing and piping; from the 13th century, lead was used to create
Outside Europe and Asia
In the
Industrial Revolution
In the second half of the 18th century Britain, and later continental Europe and the United States, experienced the Industrial Revolution. During the period, lead mining proved important; the Industrial Revolution was the first time during which production rates exceeded those of Rome.[98] Britain was the leading producer, losing this status by the mid-19th century with the depletion of its mines and the development of lead mining in Germany, Spain, and the United States.[144] By 1900, the United States dominated global lead production,[145] and other non-European nations—Canada, Mexico, and Australia—had begun significant production.[146] A great share of the demand for lead came from plumbing and painting—lead paints were in regular use.[147] At this time, more (working class) people contacted the metal and lead poisoning cases escalated. This led to research into the effects of lead intake. Lead was proven to be more dangerous in its fume form than as a solid metal. Lead poisoning and gout were linked; British physician Alfred Baring Garrod noted a third of his gout patients were plumbers and painters. The effects of chronic ingestion of lead, including mental disorders, were also studied in the 19th century. The first laws aimed at decreasing lead poisoning in factories were enacted during the 1870s and 1880s in the United Kingdom.[147]
Modern era
Further evidence of the threat that lead posed to humans was discovered in the late 19th and early 20th centuries. Mechanisms of harm were better understood, and lead blindness was documented. Countries in Europe and the United States started efforts to reduce the amount of lead that people came into contact with. The United Kingdom first introduced mandatory factory inspections in 1878 and appointed the first Medical Inspector of Factories in 1898; as a result, a 25-fold decrease in lead poisoning incidents from 1900 to 1944 was reported.
Production
Production and consumption of lead is increasing worldwide due to its use in lead–acid batteries.[156] There are two major categories of production: primary, from mined ores; and secondary from scrap. In 2013, 4.74 million metric tons came from primary production and 5.74 million from secondary production. The top three producers of mined lead concentrate in that year were China, Australia, and the United States. The top three producers of refined lead were China, the United States, and Germany.[157] According to the International Resource Panel's Metal Stocks in Society report of 2010, the total amount of lead in use, stockpiled, discarded or dissipated into the environment, on a global per capita basis, is 8 kg. Much of this is in more developed countries (20–150 kg per capita) rather than less developed ones (1–4 kg per capita).[158]
Production processes for primary and secondary lead are similar. Some primary production plants now supplement their operations with scrap lead, and this trend is likely to increase in the future. Given adequate techniques, secondary lead is indistinguishable from primary lead. Scrap lead from the building trade is usually fairly clean and is re-melted without the need for smelting, though refining is sometimes needed. Secondary lead production is therefore cheaper, in terms of energy requirements, than is primary production, often by 50% or more.[159]
Primary
Most lead ores contain a low percentage of lead—lead-rich ores have a typical content of 3–8%—which must be concentrated for extraction.[160] During initial processing, ores typically undergo crushing, dense-medium separation, grinding, froth flotation, and drying. The resulting concentrate, which has a lead content of 30–80% by mass (regularly 50–60%),[160] is then turned into (impure) lead metal.
There are two main ways of doing this: a two-stage process involving roasting followed by blast furnace extraction, carried out in separate vessels; or a direct process in which the extraction of the concentrate occurs in a single vessel. The latter has become the most common route, though the former is still significant.[161]
Two-stage process
First, the sulfide concentrate is roasted in air to oxidize the lead sulfide:[162]
- 2 PbS + 3 O2 → 2 PbO + 2 SO2↑
Country | Output (thousand tons) |
---|---|
China | 2,300 |
Australia | 633 |
United States | 385 |
Peru | 300 |
Mexico | 240 |
India | 130 |
Russia | 90 |
Bolivia | 82 |
Sweden | 76 |
Turkey | 54 |
North Korea | 45 |
Poland | 40 |
South Africa | 40 |
Kazakhstan | 38 |
Ireland | 33 |
Other countries | 226 |
As the original concentrate was not pure lead sulfide, roasting yields lead oxide and a mixture of
- 2 PbO + C → Pb + CO2↑
Impurities are mostly arsenic, antimony, bismuth, zinc, copper, silver, and gold. The melt is treated in a reverberatory furnace with air, steam, and sulfur, which oxidizes the impurities except for silver, gold, and bismuth. Oxidized contaminants float to the top of the melt and are skimmed off.[166][167] Metallic silver and gold are removed and recovered economically by means of the Parkes process, in which zinc is added to lead. The zinc adsorbs silver and gold, both of which, being immiscible in lead, can be separated and retrieved.[168][167] De-silvered lead is freed of bismuth by the Betterton–Kroll process, treating it with metallic calcium and magnesium. The resulting bismuth dross can be skimmed off.[167]
Very pure lead can be obtained by processing smelted lead electrolytically using the
Direct process
In this process lead bullion and slag is obtained directly from lead concentrates. The lead sulfide concentrate is charged directly to a furnace, melted, and oxidized, forming lead monoxide. Carbon (coke or gas) is added to the molten charge along with fluxing agents. The lead monoxide is thereby reduced to metallic lead, in the midst of a slag rich in lead monoxide.
As much as 80% of the lead in very high-content initial concentrates can be obtained as bullion; the remaining 20% resides in a slag rich in lead monoxide. For a low-grade feed, all of the lead can be oxidized to a high-lead slag.[161] Metallic lead is further obtained from the high-lead (25–40%) slags via submerged fuel combustion or injection, reduction assisted by an electric furnace, or a combination of both.[161]
Alternatives
Research on a cleaner, less energy-intensive, lead extraction process continues; a major drawback is that the alternatives result in either a high sulfur content in the resulting lead metal, or too much lead is lost as waste. Hydrometallurgical extraction, in which anodes of impure lead are immersed into an electrolyte and pure lead is deposited onto a cathode, is technique that may have potential.[170]
Secondary
Smelting, which is an essential part of the primary production, is often skipped during secondary production. It is only performed when metallic lead had undergone significant oxidation.
Of the sources of lead for recycling, lead–acid batteries are the most important; lead pipe, sheet, and cable sheathing are also significant.[159]
Applications
Contrary to popular belief, pencil leads in wooden pencils have never been made from lead. When the pencil originated as a wrapped graphite writing tool, the particular type of
Elemental form
Lead metal has several useful mechanical properties, including high density, low melting point, ductility, and relative inertness. Many metals are superior to lead in some of these aspects but lead is more common than most of these metals, and lead-bearing minerals are easier to mine and process than those of many other metals. One disadvantage of using lead is its toxicity, which explains why it has been phased out for some uses.[174]
Lead has been used for bullets since their invention in the Middle Ages. It is inexpensive; its low melting point means small arms ammunition and shotgun pellets can be cast with minimal technical equipment; and it is denser than other common metals (which allows for better retention of velocity). In cast bullets, lead is sometimes alloyed with tin or antimony: this increases the cost and time of making the bullet, but increases its hardness (thereby making the bullet more effective against hard targets), reduces tension on the gun barrel and does not contaminate it with lead, as simple lead bullets do.[175]. Concerns have been raised that lead bullets used for hunting can damage the environment.[o]
Its high density and resistance to corrosion have been exploited in a number of related applications. It used as
The high density and atomic number of lead, combined with its relatively low cost, malleability and low melting point, helped establish lead as a radiation shielding material. A gamma ray, for example, can be absorbed by an electron, potentially knocking it out from its atom. The high density of lead means that lead atoms are densely packed and the electron density is high; the high atomic number means there are many electrons per atom.[181] In its molten form, it has been used as a coolant for lead-cooled fast reactors.[182]
Lead is added to copper alloys such as
Sheet-lead is used as a sound deadening layer in the walls, floors and ceilings of sound studios.[184][185] It is the traditional base metal of organ pipes, mixed with various amounts of tin to control the tone of each pipe.[186][187]
Lead has many uses in the construction industry; for example, lead sheets are used as architectural metals in roofing material, cladding, flashing, gutters and gutter joints, and on roof parapets.[188][189] Detailed lead moldings are used as decorative motifs to fix lead sheet. Lead is still used in statues and sculptures,[p] including for armatures.[191] In the past it was often used to balance the wheels of a car; for environmental reasons this use is being phased out in favor of other materials.[192]
The largest use of lead in the early 21st century is in
Lead is used in
Compounds
Lead compounds are used as, or in, coloring agents, oxidants, plastic, candles, glass, and semiconductors. Lead-based coloring agents are used in
Biological and environmental effects
Biological
Lead has no confirmed biological role.[204] Its prevalence in the human body—at an adult average of 120 mg[r]—is nevertheless exceeded only by zinc (2500 mg) and iron (4000 mg) of all metals.[206] Lead salts are very quickly and efficiently absorbed by the body.[207] A small amount of lead (1%) will be stored in bones; the rest will be excreted in urine and feces within a few weeks of exposure. Only about a third of lead will be excreted by a child. Continuous exposure may result in the bioaccumulation of lead.[208]
Toxicity
Lead is a highly poisonous metal (whether inhaled or swallowed), affecting almost every organ and system in the human body.
Effects
Lead can cause severe damage to the brain and kidneys in adults or children and, ultimately, death. By mimicking calcium, lead can cross the
Symptoms of lead poisoning include
Despite the toxicity of lead in significant amounts, there is some evidence that trace amounts are beneficial in pigs and rats, and that its absence causes deficiencies such as depressed growth, anemia, and disturbed iron metabolism. If this finding holds for humans it would make lead an essential element, one with a threshold of toxicity so low that lead toxicity would remain a much higher priority than lead deficiency.[220][221][222][223]
Treatment
Treatment for lead poisoning normally involves the administration of
Exposure sources
Lead exposure is a global issue as lead mining and lead smelting are common in many countries. Poisoning typically results from ingestion of food or water contaminated with lead, and less commonly after accidental ingestion of contaminated soil, dust, or lead-based paint.[226] Fruit and vegetables can be contaminated by high levels of lead in the soils they were grown in. Soil can be contaminated through particulate accumulation from lead in pipes, lead paint, and residual emissions from leaded gasoline.[227] The use of lead for water pipes is problematic in areas with soft or acidic water. Hard water forms insoluble layers in the pipes whereas soft and acidic water dissolves the lead pipes.[228]
Ingestion of lead-based paint is the major source of exposure for children. As the paint deteriorates, it peels, is pulverized into dust and then enters the body through hand-to-mouth contact or contaminated food, water, or alcohol. Ingesting certain
Dermal exposure may be significant for a narrow category of people working with organic lead compounds. The rate of skin absorption is lower for inorganic lead.[233]
Environmental
The extraction, production, use, and disposal of lead and its products have caused significant contamination of the Earth's soils and waters. Atmospheric emissions of lead were at their peak during the Industrial Revolution and the leaded gas period in the second half of the twentieth century. Elevated concentrations of lead persist in soils and sediments in post-industrial and urban areas, and industrial emissions, including those arising from coal burning,[234] continue in many parts of the world.[235]
Lead can accumulate in soils, especially those with a high organic content, where it remains for hundreds to thousands of years. It can take the place of other metals within plants and can accumulate on their surfaces, thereby retarding photosynthesis, and preventing their growth or killing them. Contamination of soils and plants then affects microorganisms and animals. Affected animals have a reduced ability to synthesize red blood cells.
Restriction and remediation
By the mid-1980s, a significant shift in lead use had taken place. In the United States, environmental regulations reduced or eliminated the use of lead in non-battery products, including gasoline, paints, solders, and water systems. Particulate control devices can be used in
In the United States, the Occupational Safety and Health Administration has set the permissible exposure limit for lead exposure in the workplace as 0.05 mg/m3 over an 8-hour workday; this applies to metallic lead, inorganic lead compounds, and lead soaps. The US National Institute for Occupational Safety and Health has set a recommended exposure limit of 0.05 mg/m3 over an 8-hour workday and recommends that workers' blood concentrations of lead stay below 0.06 mg per 100 g of blood.
Lead may still be found in harmful quantities in stoneware,
Lead waste, depending of the jurisdiction and the nature of the waste, may be treated as household waste (in order to facilitate lead abatement activities),[243] or potentially hazardous waste requiring specialized treatment or storage.[244] Research has been conducted on how to remove lead from biosystems by biological means. Fish bones are being researched for their ability to bioremediate lead in contaminated soil.[245][246] The fungus Aspergillus versicolor is effective at removing lead ions.[247] Several bacteria have been researched for their ability to reduce lead, including the sulfate-reducing bacteria Desulfovibrio and Desulfotomaculum, both of which are highly effective in aqueous solutions.[248]
See also
Notes
- relativistic effects.[8]
- ^ The allotrope was obtained by depositing lead atoms on the surface of an icosahedral silver-indium-ytterbium quasicrystal. Its electronic nature—whether it was metallic or an insulator (or something in between)—was not recorded.[12][13]
- ^ Malleability describes how easily it deforms under compression, whereas ductility means its ability to stretch.
- ^ A (wet) finger can be dipped into molten lead without risk of a burning injury.[25]
- ^ An even number of either protons or neutrons generally increases the nuclear stability of isotopes, compared to isotopes with odd numbers. No elements with odd atomic number has more than two stable isotopes; even-numbered elements have multiple stable isotopes, with tin (element 50) having the highest number of isotopes of all elements, ten.[32] See Even and odd atomic nuclei for more details.
- ^ Lead 208 is doubly magic, and especially stable against decay, as its 126 neutrons also form a complete shell.
- ^ The half-life found in the experiment was 1.9×1019 years.[33] A kilogram of natural bismuth would have an activity value of approximately 0.003 becquerels (decays per second). For comparison, the activity value of natural radiation within the human body is around 65 becquerels per kilogram of body weight (4500 becquerels on average).[34]
- ^ It decays solely via electron capture, which means when there are no electrons available and lead is fully ionized with all 82 electrons removed it cannot decay. Fully ionized thallium-205, the isotope lead-205 would decay to, becomes unstable and can decay into a bound state of lead-205.[41]
- ^ The harder the water the more calcium bicarbonate and sulfate it will contain, and the more the inside of the pipes will be coated with a protective layer of lead carbonate or lead sulfate.[50]
- ^ Abundances in the source are listed relative to silicon rather than in per-particle notation. The sum of all elements per 106 parts of silicon is 2.6682×1010 parts; lead comprises 3.258 parts.
- ^ Elemental abundance figures are estimates and their details may vary from source to source.[90]
- Gnaeus Iulius Agricolawas imperial governor (of Britain)."
- Caesar Augustus, have been attributed to lead poisoning.[117]
- ^ It is not known when mining was first performed in the region because no written records were kept, but there are 17th-century European records of trade with the Congolese, which indicate lead was being smelted by then.[143]
- ^ For instance, California banned lead bullets for hunting on that basis in April 2015.[176]
- ^ For example, a firm "...producing quality [lead] garden ornament from our studio in West London for over a century".[190]
- ^ See[193] for details on how a lead–acid battery works.
- ^ Rates vary greatly by country.[205]
- ^ An alloy of brass (copper and zinc) with lead, iron, tin, and sometimes antimony.[240]
References
- ^ "Standard Atomic Weights: Lead". CIAAW. 2020.
- ^ ISSN 1365-3075.
- PMID 15740207.
- ^ .
- ^ a b c Meija et al. 2016.
- ^ Lide 2004, p. 10-179.
- ^ a b c Polyanskiy 1986, pp. 14–15.
- ^ Pyykko 1988, pp. 563–94.
- ^ Norman 1996, p. 36.
- ^ Greenwood & Earnshaw 1998, pp. 374, 226–27.
- ^ Christensen 2002, pp. 867–68.
- ^ Sharma et al. 2013.
- ^ Sharma et al. 2014, p. 174710.
- ^ a b Polyanskiy 1986, p. 18.
- ^ Thornton, Rautiu & Brush 2001, p. 6.
- ^ Lide 2004, pp. 12-35–12-37.
- ^ Jones 2014, p. 42.
- ^ Lide 2004, pp. 4-39–4-96.
- ^ Vogel & Achilles 2013, p. 8.
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